The 1s2s 3S1 - 1s2 1S0 relativistic magnetic dipole transition in heliumlike argon, emitted by the plasma of an electron-cyclotron resonance ion source, has been measured using a double-flat crystal x-ray spectrometer. Such a spectrometer, used for the first time on a highly charged ion transition, provides absolute (reference-free) measurements in the x-ray domain. We find a transition energy of 3104.1605(77) eV (2.5 ppm accuracy). This value is the most accurate, reference-free measurement done for such a transition and is in good agreement with recent QED predictions.

TiO2 films with enhanced photosensitivity were deposited on alkali free glass substrates without intentional substrate heating by pulsed DC magnetron reactive sputtering with an average thickness of about 2 mu m. Three dyes, commercial N719 and two new organic dyes were impregnated in order to control the optical spectral selectivity of such films. The type of dye used proved to dramatically influence the device's response to radiation pulses. The practical breakthrough is the use of different dyes according to the region of the electromagnetic spectrum one wants to detect. Devices with photocurrent 6 orders of magnitude higher than the dark current (from similar to 2 x 10(-12) to 2 x 10(-6) A for a 100 V bias) were fabricated with a spectral response within the visible range of the electromagnetic spectrum. In addition, this approach is likely to allow for the fabrication of hybrid photodetectors on cheap heat sensible flexible polymeric substrates. (C) 2011 Elsevier B.V. All rights reserved.

TiO2 films with enhanced photosensitivity were deposited on alkali free glass substrates without intentional substrate heating by pulsed DC magnetron reactive sputtering with an average thickness of about 2 mu m. Three dyes, commercial N719 and two new organic dyes were impregnated in order to control the optical spectral selectivity of such films. The type of dye used proved to dramatically influence the device's response to radiation pulses. The practical breakthrough is the use of different dyes according to the region of the electromagnetic spectrum one wants to detect. Devices with photocurrent 6 orders of magnitude higher than the dark current (from similar to 2 x 10(-12) to 2 x 10(-6) A for a 100 V bias) were fabricated with a spectral response within the visible range of the electromagnetic spectrum. In addition, this approach is likely to allow for the fabrication of hybrid photodetectors on cheap heat sensible flexible polymeric substrates. (C) 2011 Elsevier B.V. All rights reserved.

This Chapter presents the optimal design of radio-frequency integrated spiral inductors. The basic idea is to generate an analytical model to characterize integrated inductors based on the double {\ensuremathπ}-model, and offer to the designer an approach to determine the inductor layout parameters. Particle Swarm Optimization technique is used to generate optimal values of parameters of the developed models. Viability of the proposed models is highlighted via comparison with ASITIC simulation results.

A gene encoding Bfr (bacterioferritin) was identified and isolated from the genome of Desulfovibrio vulgaris cells, and overexpressed in Escherichia coli. In vitro, H(2)O(2) oxidizes Fe(2+) ions at much higher reaction rates than O(2). The H(2)O(2) oxidation of two Fe(2+) ions was proven by Mossbauer spectroscopy of rapid freeze-quenched samples. On the basis of the Mossbauer parameters of the intermediate species we propose that D. vulgaris Bfr follows a mineralization mechanism similar to the one reported for vertebrate H-type ferritins subunits, in which a diferrous centre at the ferroxidase site is oxidized to diferric intermediate species, that are subsequently translocated into the inner nanocavity. D. vulgaris recombinant Bfr oxidizes and stores up to 600 iron atoms per protein. This Bfr is able to bind DNA and protect it against hydroxyl radical and DNase deleterious effects. The use of H(2)O(2) as an oxidant, combined with the DNA binding and protection activities, seems to indicate a DPS (DNA-binding protein from starved cells)-like role for D. vulgaris Bfr.

Investigation of the palaeoclimatic conditions associated with Upper Jurassic strata in Portugal and comparison with published palaeoclimate reconstructions of the Upper Jurassic Morrison Formation in western North America provide important insights into the conditions that allowed two of the richest terrestrial faunas of this period to flourish. Geochemical analyses and observations of palaeosol morphology in the informally named Upper Jurassic Lourinhã formation of western Portugal indicate warm and wet palaeoclimatic conditions with strongly seasonal precipitation patterns. Palaeosol profiles are dominated by carbonate accumulations and abundant shrink-swell (vertic) features that are both indicative of seasonal variation in moisture availability. The δ18OSMOW and δDSMOW values of phyllosilicates sampled from palaeosol profiles range from +22·4‰ to +22·7‰ and −53·0‰ to −37·3‰, respectively. These isotope values correspond to temperatures of formation between 32°C and 39°C ± 3°, with an average of 36°C, which suggest surface temperatures between 27°C and 34°C (average 31°C). On average, these surface temperature estimates are 1°C higher than the highest summer temperatures modelled for Late Jurassic Iberia using general circulation models. Elemental analysis of matrix material from palaeosol B-horizons provides proxy (chemical index of alteration minus potassium) estimates of mean annual precipitation ranging from 766 to 1394 mm/year, with an average of approximately 1100 mm/year. Palaeoclimatic conditions during deposition of the Lourinhã formation are broadly similar to those inferred for the Morrison Formation, except somewhat wetter. Seasonal variation in moisture availability does not seem to have negatively impacted the ability of these environments to support rich and relatively abundant faunas. The similar climate between these two Late Jurassic terrestrial ecosystems is probably one of the factors which explains the similarity of their vertebrate faunas.

A indústria do betão pré fabricado é, por tradição, inovadora, precursora de novas tecnologias e de novos materiais.O processo produtivo de estruturas com elementos pré-fabricados difere significativamente do das estruturas betonadas em obra pelo facto de uma parte, ou a totalidade, dos elementos da estrutura serem produzidos em fábrica, em condições de produção melhoradas em relação às condições da obra, e serem posteriormente transportados para a obra, onde são, finalmente ligados entre si. A produção em fábrica é efectuada em ambiente protegido do Sol e da chuva, com operários fixos e com formação profissional para desenvolverem tarefas com procedimentos normalizados. Consequentemente, os elementos executados em fábrica possuem melhor qualidade, sob vários aspectos, do que as estruturas executadas em obra.Este livro divide-se em duas grandes áreas, numa primeira abordam-se algumas aplicações de estruturas pré-moldadas no mundo e numa segunda parte descreve-se o seu comportamento estrutural face a diferentes acções. Nos primeiros capítulos relata-se a experiência da pré-fabricação em três países de diferentes continentes: o Brasil, Portugal e a Austrália e revelam-se novas oportunidades que poderão surgir para a indústria da pré-fabricação. Nos capítulos seguintes dá-se um especial enfoque à investigação do comportamento das ligações (rígidas e semi-rígidas). Aborda-se o projecto de estruturas de betão pré-fabricado às acções acidentais. E por fim, dedicam-se os últimos capítulos ao comportamento das estruturas pré-fabricadas face às acções sísmicas. Nesta área, o bom desempenho das estruturas e grande parte do conhecimento e da tecnologia actual advém da resposta dada pelos engenheiros, investigadores e construtores aos fenómenos naturais que afectam as nossas construções, como comprova o desempenho das ligações dúcteis resistentes a momentos em edifícios pré fabricados de betão no verdadeiro teste sísmico que foram os sismos de Christchurch de 2010 e 2011.

Differently shaped polymeric matrices were efficiently coated with stimuli-responsive hydrogels for a wide range of applications using a new methodology. By combining plasma surface activation and polymerization in supercritical media at mild conditions, we report the direct smart coating of microcarriers and membranes in gram-scale quantities with a scalable, green, and low-cost approach.

In this paper we present a method for estimating soil pCO2 in ancient environments using the measured carbon-isotope values of pedogenic carbonates and plant-derived organic matter. The validity of soil pCO2 estimates proves to be highly dependent on the organic δ13C values used in the calculations. Organic matter should be sourced from the same paleosol profiles as sampled carbonates to yield the most reliable estimates of soil pCO2. In order to demonstrate the potential use of soil pCO2 estimates in paleoecological and paleoenvironmental studies, we compare samples from three Upper Jurassic localities. Soil pCO2 estimates, interpreted as a qualitative indicator of primary paleoproductivity, are used to rank the Late Jurassic terrestrial environments represented by the Morrison Formation in western North America, the informally named Lourinhã formation in Western Europe, and the Stanleyville Group in Central Africa. Because modern terrestrial environments show a positive correlation between primary productivity and faunal richness, a similar relationship is expected in ancient ecosystems. When the relative paleoproductivity levels inferred for each study area are compared with estimates of dinosaur generic richness, a positive correlation emerges. Both the Morrison and Lourinhã formations have high inferred productivity levels and high estimated faunal richness. In contrast, the Stanleyville Group appears to have had low primary productivity and low faunal richness. Paleoclimatic data available for each study area indicate that both productivity and faunal richness are positively linked to water availability, as observed in modern terrestrial ecosystems.

Over the last decades, several indices based on ash chemistry and ash fusibility have been used to predict the ash behaviour during coal combustion, namely, its tendency for slagging and fouling. However, due to the physical–chemical differences between coals and biomass, in this work only the applicability of an ash fusibility index (AFI) to the combustion and co-combustion of three types of biomass (straw pellets, olive cake and wood pellets) with coals was evaluated. The AFI values were compared with the behaviour of ash during combustion in a pilot fluidized bed and a close agreement was observed between them. For a better understanding of the mechanisms associated with bed ash sintering, they were evaluated by SEM/EDS and the elements present on the melted ash were identified. Evidences of different sintering mechanisms were found out for the fruit biomass and herbaceous biomass tested, depending on the relative proportions of problematic elements. The particles deposited on a fouling probe inserted in the FBC were analyzed by XRD and the differences between the compounds identified allowed concluding that the studied biomasses present different tendencies for fouling. Identification of KCl and K2SO4 in the deposits confirmed the higher tendency for fouling of fruit biomass tested rather than wood pellets.

Clavicles and interclavicles are plesiomorphically present in Reptilia. However, several groups show reduction or even loss of these elements. Crocodylimorpha, e.g., lost the clavicles, whereas dinosaurs are generally interpreted to only preserve the clavicles, the theropod furcula representing an unique case of fused clavicles. In sauropods, reports of clavicles are relatively frequent in non-titanosauriforms. These elements are elongated, curved, and rather stout bones with a spatulate and a bifurcate end. However, they were always found as single bones, and differ from the relatively short and unbifurcated clavicles found articulated with the scapulae of basal sauropodomorphs.
Elements from the Howe Quarry (Late Jurassic; Wyoming, USA) shed new light on these interpretations. Besides the elongated, curved bones (herein named morphotype A), also pairs of symmetric, L-shaped bones were recovered (morphotype B), associated with diplodocid dorsal and cervical vertebrae. Elements resembling morphotype B - articulated between the scapulae - have recently been reported from a diplodocid found near Tensleep, Wyoming. Taphonomic evidence, as well as the fact that they were preserved in symmetrical pairs, therefore implies that morphotype B represents the true sauropod clavicles.
Contrary to earlier reports, morphotype A elements from the Howe Quarry, as well as of previously reported specimens show a symmetry plane following the long axis of the elements. It is thus possible that the morphotype A elements were single bones from the body midline. The only such element present in the pectoral girdle of tetrapods are the interclavicle and the furcula. Comparison with crocodilian and lacertiform interclavicles indicates that the bifurcate end of the sauropod elements might represent the reduced transverse processes of the anterior end, and the spatulate end would have covered the coracoids or sternal plates ventrally.
The presence of both clavicles and interclavicles in the pectoral girdle stiffens the anterior trunk, and enhances considerably its stability. Such an enforcement might have been needed in diplodocids due to the strong lateral forces induced to the fore-limbs by the posteriorly placed center of mass (due to shorter fore- than hind-limbs), as well as lateral movements of the enormously elongated necks and tails. The absence of clavicles and interclavicles in titanosauriforms coincides with the development of wide-gauge locomotion style.
The presence of interclavicles in sauropods supports the recently proposed homology of the furcula with the interclavicle, instead of representing fused clavicles. Interclavicles were thus not lost, but may have remained cartilaginous or have yet to be found in basal dinosauriforms.

Since the 1980’s, several buildings throughout the world have been subject to gas explosions, impact by cars or airplanes, or car bomb attacks. In many cases the effect of the impact or explosion has been the failure of a critical structural member at the perimeter of the building. After the failure, the load supported by that member could not be redistributed and part or all of the structure has collapsed in a progressive manner. The phenomenon that occurs when local failure is not confined to the area of initial distress, and spreads horizontally and/or vertically through the structure, is termed progressive collapse.

Progressive collapse is a relatively rare event, as it requires both an accidental action to cause local damage and a structure that lacks adequate continuity, ductility, and redundancy to prevent the spread of damage. It is technically very difficult and economically prohibitive to design buildings for absolute safety. However it is possible to construct precast concrete buildings that afford an acceptable degree of safety with regard to accidental actions.

A structure is normally designed to respond properly, without damage, under normal load conditions, but local and/or global damages cannot be avoided under the effect of an unexpected, but moderate degree of accidental overload. Properly designed and constructed structures usually possess reasonable probability not to collapse catastrophically under such loads, depending on different factors, for example: the type of loading; the degree and the location of accidental loading in regard to the structure and its structural members; the type of structural system, the construction technology, and the spans between structural vertical members, etc.

No structure can be expected to be totally resistant to actions arising from an unexpected and extreme cause, but it should not be damaged to an extent that is disproportionate to the original cause.

The aim of fib Bulletin 63 is to summarize the present knowledge on the subject and to provide guidance for the design of precast structures against progressive collapse. This is addressed in terms of (a) the classification of the actions, (b) their effect on the structural types, (c) the strategies to cope with such actions, (d) the design methods and (e) some typical detailing, all supplemented with illustrations from around the world, and some model calculations.

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