In this study, amorphous indium-tungsten oxide (IWO) semiconductor thin films were prepared by an eco-friendly spin-coating process using ethanol and water as solvents. The electrical properties of IWO thin-film transistors (TFTs), together with the structural and morphological characteristics of IWO thin films, were systematically investigated as functions of tungsten concentration and annealing temperature. The optimized IWO channel layer was then integrated on an aqueous aluminum oxide (AlOx) gate dielectric. It is observed that the solution-processed IWO/AlOx TFT presents high stability and improved characteristics, such as an on/off current ratio of 5 × 107, a field-effect mobility of 15.3 cm2 V-1 s-1, a small subthreshold slope of 68 mV dec-1, and a threshold voltage shift of 0.15 V under bias stress for 2 h. The IWO/AlOx TFT could be operated at a low voltage of 2 V, which was 15 times lower than that of conventional SiO2-based devices. The solution-processed IWO thin films synthesized in a green route would be promising candidates for large-area and high-performance low-cost devices. © The Royal Society of Chemistry 2016.

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Software refactoring is a well-known technique that provides transformations on software artifacts with the aim of improving their overall quality.

In the past, we have proposed a catalog of refactoring for spreadsheet models expressed in the ClassSheets modeling language, which allows us to specify the business logic of a spreadsheet in an object-oriented fashion.

Reasoning about spreadsheets at the model level enhances a model-driven spreadsheet environment where a ClassSheet model and its conforming instance (the spreadsheet data) automatically co-evolves after a refactoring is applied at the model level. Our motivation for such research was to improve the model and its conforming instance: the spreadsheet data.

In this paper we define such refactorings using previously proposed evolution steps for models and instances.

We also present an empirical study we designed and conducted in order to confirm our original intuition that these refactorings have a positive impact on end-user productivity, both in terms of effectiveness and efficiency.

The results are presented not only in terms of productivity changes between refactored and non-refactored scenarios, but also in terms of overall user satisfaction, relevance, and experience.

In almost all cases the refactorings indeed improved end-users productivity. Moreover, in most cases users were more engaged with the refactored version of the spreadsheets they worked with.

This study presents an analysis of Carbon Fiber Reinforced Polymers (CFRP)-to-parent material interfaces based on 40 single-lap shear tests intended to highlight the strength of the interfaces under fracture mode II. Three different substrates are analyzed: timber;concrete and steel, using the same CFRP laminates and adhesive agent. The Externally Bonded Reinforcement (EBR) technique was used throughout the study. The results show that the CFRP-to-timber interfaces had the highest strength but also showed that these interfaces need a longer bonded length in order to reach maximum strength, i.e., CFRP-to-timber interfaces had the longest effective bond length. The local non-linear bond-slip curve of CFRP-to-concrete can be approximated to exponential curves, whereas the CFRP-to-timber or steel interfaces showed tri-linear and bi-linear bond-slip relations, respectively. Also, the CFRP-to-timber interfaces revealed the highest fracture energy.

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A set of three old suspended timber floors were flexurally-strengthened with Carbon Fiber Reinforced Polymers (CFRP) strips in order to investigate the effectiveness of externally bonding FRP to their soffits. The specimens were from an old building and 740 mm-wide bands were transferred to the laboratory in order to be tested in a 4-point bending test. One specimen was tested with no strengthening system and the results obtained were used as reference values for comparison with the specimens those were externally bonded and reinforced (EBR) with CFRP strips. Two similar EBR systems were studied: (i) keeping both ends of the CFRP strips free of any restriction (traditional technique); and (ii) embedding both ends of the CFRP strips into the timber, thus providing a bonding anchorage of the strips (new technique). The installation of the new strengthening system comprises the opening of holes in the timber and the creation of a transition curve between the holes and the timber surface. This transition curve allows a smooth transition of the CFRP laminate between the hole and the timber surface, thus avoiding stress concentrations in this area. After the opening of the holes, the resin is applied inside the hole and on the beam surface, and then the CFRP laminate is mounted. The load-carrying capacity of the specimens, the rupture modes, the strains and bond stress distributions within the CFRP-to-timber interface are presented. A nonlinear numerical simulation of the specimens based on the mid-span cross-sectional equilibrium is also presented. The results showed that the use of the new strengthening system enhances the performance of the specimens when compared with the traditional strengthening system.

© 2016 Elsevier B.V. All rights reserved.Different glasses based on the ZnO-B2O3-SiO2 system, with a ZnO content ≥ 60 mol{%} and a fixed SiO2 content (20 mol{%}), were synthesised using a melt-quenching method. Glass samples with zinc oxide concentrations as high as 65 mol{%} were prepared successfully without deteriorating the glass-forming ability. The glass samples were submitted to controlled heat-treatments, and the effect of the ZnO/B2O3 molar ratio on the formation of crystalline phases within the glass matrix was investigated by means of differential thermal analysis (DTA), X-ray diffraction (XRD) and scanning electron microscopy (SEM). DTA results indicated that the glass transition and the onset crystallization temperatures of the studied glasses tended to increase with the increment on the ZnO/B2O3 ratio. XRD data showed that the zinc binary crystalline phases, willemite (Zn2SiO4), a zinc orthosilicate, and zinc borate (Zn3B2O6) could be present in the crystallized glasses, depending on the heat-treatment conditions. The formation of willemite was promoted by an increasing ZnO/B2O3 ratio. Microstructural observations performed by SEM indicated that under controlled experimental parameters (glass composition, heat-treatment temperature and time) the precipitation of nanocrystals within the glass matrix can be achieved, resulting in transparent and translucent willemite glass-ceramics.

We compute the generalized Cauchy index of some semi-almost periodic functions, which are important
in the study of the Fredholm index of singular integral operators with shifts and slowly oscillating data.

Although there are a few research studies on solution-processed p-channel oxide thin-film transistors (TFTs), the strict fabrication conditions and the poor electrical properties have limited their applications in low-power complementary metal oxide semiconductor (CMOS) electronics. Here, the application of the polyol reduction method for processing p-type CuxO and NiOx channel layers and their implementation in TFT devices are reported. The optimized CuxO and NiOx TFTs were achieved at low annealing temperatures (∼300 °C) and exhibited decent electrical properties. Encouraged by the inspiring results obtained on SiO2/Si substrates, the TFT performance was further optimized by device engineering, employing high-k AlOx as the gate dielectric. The fully solution-processed NiOx/AlOx TFT could be operated at a low voltage of 3.5 V and exhibits a high hole mobility of around 25 cm2 V-1 s-1. Our work demonstrates the ability to grow high-quality p-type oxide films and devices via the polyol reduction method over large area substrates while at the same time it provides guidelines for further p-type oxide material and device improvements. © The Royal Society of Chemistry 2016.

A importância do papel do Arquiteto-urbanista na caracterização dos conceitos e no planejamento das Smart Cities é um tema com muito por estudar e desenvolver. Este artigo faz uma aproximação a esta questão através de análise crítica com a seguinte abordagem: 1 - é feita uma descrição mais detalhada do porquê deste trabalho de investigação; 2 – apresenta-se uma contextualização da transição dos cenários; 3 - é levantada a problematização e a identificação de alguns motivos do “desenquadramento” da atuação do arquiteto-urbanista na cena; 4 – são discutidos aspectos e elencadas algumas características para “(re)enquadramento” dentro do cenário ideal, 5 – são analisados alguns casos de estudo; 6 - são tecidas conclusões. Este artigo mostra, portanto, o resultado deste estudo comparativo entre panorama atual e desejado, considerando este último como o cenário conceitual. É inicialmente caracterizada a situação atual através de levantamento da crítica especializada, depois é descrita a situação desejada tendo como base a análise de quatro casos de estudo; sendo dois de Smart Cities construídas a partir do zero e dois de cidade existentes que estão sendo transformadas em Smart Cities. Por fim, são identificados elementos que contribuem, na opinião dos autores, para o reassumir do papel do arquiteto-urbanista. Com este trabalho, foi possível, de uma forma sistematizada, estudar e suscitar ações deficitárias na atuação dos arquitetos-urbanistas, como também descortinar potenciais ações que podem induzir e reverter a transformação do cenário atual. Ficou claro que as necessidades intrínsecas ao novo modelo de cidade exigem ainda mais proposições criativas. O delinear das futuras cenas seria então ideal se os arquitetos-urbanistas retomassem posicionamento crítico propositivo e o utilizassem na solução que imagina novas e condizentes maneiras de habitar o espaço. O prelúdio já delineado convida então, os protagonistas na produção do espaço a alforriar-se da inércia, saindo da condição de espectadores e passando a condição de entendedores antecipados do cenário.