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1996
Carvalho, C., JMM De Nijs, I. Ferreira, E. Fortunato, and R. Martins. "Improvement of the ITO-p Interface In a-SI: H Solar Cells Using a Thin SiO Intermediate Layer." MRS Proceedings. 426.1 (1996). Abstract
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Nunes de Carvalho, C., JMM De Nijs, I. Ferreira, E. Fortunato, and R. Martins. "Improvement of the ITO-p Interface in a-Si: H solar cells using a thin SiO Intermediate Layer." MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS. 426 (1996): 25-30. Abstract
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Nijs, JMM De, I. Ferreira, E. Fortunato, and R. Martins. "Improvement of the ITO-P Interface in a-Si: H Solar Cells Using a Thin SiO Intermediate Layer." MRS Proceedings. 420.1 (1996). Abstract
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Fortunato, E., Soares Lavareda Martins F. G. R. "A linear array thin film position sensitive detector for 3D measurements." Journal of Non-Crystalline Solids. 198-200 (1996): 1212-1216. AbstractWebsite

A novel compact linear thin film position sensitive detector with 128 elements, based on p-i-n a-Si:H devices was developed. The proper incorporation of this sensor into an optical inspection camera makes possible the acquisition of three dimension information of an object, using laser triangulation methods. The main advantages of this system, when compared with the conventional charge-coupled devices, are the low complexity of hardware and software used and that the information can be continuously processed (analogue detection).

Godinho, M. H., AF Martins, and J. L. Figueirinhas. "Novel PDLC type display based on cellulose derivatives." Liquid Crystals. 20.3 (1996): 373-376. Abstract
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Fortunato, E., Lavareda Scares Martins G. F. R. "Performances presented by large-area thin film position-sensitive detectors based on amorphous silicon." Thin Solid Films. 272 (1996): 148-156. AbstractWebsite

This paper presents a low-cost technology for the realisation of large-area thin film position-sensitive detectors using the a-Si:H technology. The obtained results are quite promising regarding the application of these sensors to a wide variety of optical inspection systems, such as: machine tool alignment and control; angle measuring; rotation monitoring; surface profiling; medical instrumentation; targeting; remote optical alignment; guidance systems; etc., to which automated inspection control is needed.

Fortunato, E., Martins R. "Role of the collecting resistive layer on the static characteristics of a 1D a-Si:H thin film position sensitive detector." Review of Scientific Instruments. 67 (1996): 2702-2707. AbstractWebsite

The aim of this work is to present an analytical model able to interpret the role of the thin collecting resistive layer on the static performances exhibited by 1D amorphous silicon hydrogenated p-i-n thin film position sensitive detectors. The data obtained show that the devices present a linearity and a spatial resolution, of respectively, better than 99% and 20 μm for a spatial detection limit of about 80 mm, highly dependent on the characteristics exhibited by the collecting resistive layer that should have sheet resistivities in the range of 10 to 103 Ω/sq, as predicted by the model proposed. © 1996 American Institute of Physics.

Martins, Rodrigo, Manuela Vieira, Isabel Ferreira, and Elvira Fortunato. "Transport properties of doped silicon oxycarbide microcrystalline films produced by spatial separation techniques." Solar energy materials and solar cells. 41 (1996): 493-517. Abstract
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Fantoni, A.a, Vieira Cruz Schwarz Martins M. a J. a. "A two-dimensional numerical simulation of a non-uniformly illuminated amorphous silicon solar cell." Journal of Physics D: Applied Physics. 29 (1996): 3154-3159. AbstractWebsite

We present here a two-dimensional numerical simulation of a hydrogenated amorphous silicon p-i-n solar cell non-uniformly illuminated through the p-layer. This simulation is used to show the effect of the presence of dark regions in the illuminated surface on the electrical behaviour of the device. The continuity equations for holes and electrons together with Poisson's equation, implemented with a recombination mechanism reflecting the amorphous structure of the material, are solved using standard numerical techniques over a rectangular domain. The results obtained reveal the appearance of a lateral component of the electric field and current density vectors inside the structure. The effect of such components is a lateral carrier flow of electrons inside the intrinsic layer and of holes inside the p-layer, resulting in leakage of the transverse current collected at the contacts and an increase in the series resistance.

1995
Leal, C. R., M. H. Godinho, AF Martins, and F. Fried. "Aging effects on the rheology of LC solutions of hydroxypropylcellulose." Molecular Crystals and Liquid Crystals. 261.1 (1995): 87-93. Abstract
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Cerdeira, J. O., I. Faria, and P. Bárcia. "Establishing determinantal inequalities for positive-definite matrices." Discrete Applied Mathematics. 63 (1995): 13-24. Abstract
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Fortunato, Elvira, Lavareda Guilherme Martins Rodrigo Soares Fernando Fernandes Luis. "High-detection resolution presented by large-area thin-film position-sensitive detectors." Proceedings of SPIE - The International Society for Optical Engineering. Vol. 2397. 1995. 259-270. Abstract

The aim of this work is to present the main optoelectronic characteristics of large area 1D position sensitive detectors based on amorphous silicon p-i-n diodes. From that, the device resolution, response time and detectivity are derived and discussed concerning the field of applications of the 1D thin film position sensitive detectors.

Fortunato, E.a, Lavareda Martins Soares Fernandes G. a R. a. "Large-area 1D thin-film position-sensitive detector with high detection resolution." Sensors and Actuators: A. Physical. 51 (1995): 135-142. AbstractWebsite

The aim of this work is to present the main optoelectronic characteristics of large-area one-dimensional position-sensitive detectors (1D TFPSDs) based on amorphous silicon (a-Si) p-i-n diodes. From that, the device resolution, response time and detectivity (defined as being the reciprocal of the noise equivalent power pattern) are derived and discussed concerning the field of applications of the 1D TFPSDs. © 1996.

Fortunato, E., Soares Lavareda Martins F. G. R. "New linear array thin film position sensitive detector (LTFPSD) for 3D measurements." Materials Research Society Symposium - Proceedings. Vol. 377. 1995. 797-802. Abstract

A Linear array Thin Film Position Sensitive Detector (LTFPSD) based on hydrogenated amorphous silicon (a-Si:H) is proposed for the first time, taking advantage of the optical properties presented by a-Si:H devices we have developed a LTFPSD with 128 integrated elements able to be used in 3D inspections/measurements. Each element consists on an one-dimensional TFPSD, based on a p.i.n. diode produced in a conventional PECVD system, where the doped layers are coated with thin resistive layers to establish the required device equipotentials. By proper incorporation of the LTFPSD into an optical inspection camera it will be possible to acquire information about an object/surface, through the optical cross-section method. The main advantages of this system, when compared with the conventional CCDs, are the low complexity of hardware and software used and that the information can be continuously processed (analogue detection).

Martins, R., M. Vieira, I. Ferreira, and E. Fortunato. "Role of oxygen partial pressure on the properties of doped silicon oxycarbide microcrystalline layers produced by spatial separation techniques." Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. 13.4 (1995): 2199-2209. Abstract
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Fantoni, Alessandro, Vieira Manuela Martins Rodrigo. "Spatial microscopic/macroscopic control and modeling of the p.i.n devices stability." Proceedings of SPIE - The International Society for Optical Engineering. Vol. 2397. 1995. 695-702. Abstract

The introduction into a traditional p.i.n. structure of two defective buffer layers near the p/i and i/n interfaces can improve the device stability and efficiency through an enhancement of the electric field profile at the interfaces and a reduction of the available recombination bulk centers. The defectous layer (`i-layer'), grown at a higher power density, present a high density of the defects and acts as `gettering centers' able to tailor light induced defects under degradation conditions. If the i-layer density of states remains below 1016 eV-1 cm-3 and assuming a Gaussian distribution of defect states, the gettering center distribution will not affect significantly the carrier population but only its spatial distribution. We report here about a device numerical simulation that allows us to analyze the influence of the `i- layer' position, thickness and density of states on the a-Si:H solar cells performances. Results of some systematic simulation rom the ASCA program (Amorphous Solar Cell Analysis), and for different configurations will be presented.

Lanca, M. C., J. Domingues, and I. Franco Study of fractal properties in Lichtenberg figures., 1995. AbstractWebsite
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Lanca, M. C., J. Domingues, and I. Franco Study of fractal properties in Lichtenberg figures., 1995. AbstractWebsite
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Martins, R., I. Ferreira, and E. Fortunato. "Wide Band Gap Microcrystalline Silicon Thin Films." DIFFUSION AND DEFECT DATA PART B SOLID STATE PHENOMENA (1995): 299. Abstract
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Ferreira, Isabel, Rodrigo Martins, and Elvira Fortunato. "Wide Band Gap Microcrystalline Silicon Thin Films." Solid State Phenomena. 44 (1995): 299-346. Abstract
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1994
Fortunato, E.a, Lavareda Vieira Martins Ferreira G. a M. a. "Application of thin film technology to optical sensors." Vacuum. 45 (1994): 1151-1154. AbstractWebsite

In this paper we present results of PIN single and dual axis Thin Film Position Sensitive Detectors (TFPSD) based on hydrogenated amorphous silicon (a-Si:H) technology, with a wide detection area (up to 80 × 80 mm). These sensors provide an alternative to Charge Coupled Devices (CCDs) when large inspection areas are needed, under a requirement to use simpler technology. In this paper we analyse the forward and reverse I-V characteristics in the dark and under illumination, as well as the device linearity of TFPSD. © 1994.

Fortunato, Elvira, Carvalho Carlos Bicho Ana Martins Rodrigo N. "Effect of different TCO interfaces on the performances presented by hydrogenated amorphous silicon p-i-n solar cells." Conference Record of the IEEE Photovoltaic Specialists Conference. Vol. 1. 1994. 646-649. Abstract

In this paper we report results concerning the effect of the TCO interface on hydrogenated amorphous silicon (a-Si:H) p-i-n homojunction solar cells. Its correlation with dark current density-voltage (J-V) characteristics and spectral response, before and after while light-soaking degradation, is analysed. From this study, we conclude that the properties and stability of these devices are not only influenced by the a-Si:H film properties, but also by the properties of the transparent conductive electrode and its interface with the a-Si:H layer.

Martins, R., and I. Ferreira. "Engineering of the energy coupling in PECVD systems used to produce large area a-Si: H coatings." Vacuum. 45.10 (1994): 1107-1108. Abstract
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Fried, F., C. R. Leal, M. H. Godinho, and AF Martins. "The first normal stress difference and viscosity in shear of liquid crystalline solutions of hydroxypropylcellulose: new experimental data and theory." Polymers for Advanced Technologies. 5.9 (1994): 596-599. Abstract
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Ferreira, GC, R. Franco, S. G. Lloyd, AS Pereira, I. Moura, JJG Moura, and BH HUYNH. "MAMMALIAN FERROCHELATASE, A NEW ADDITION TO THE METALLOENZYME FAMILY." Journal of Biological Chemistry. 269 (1994): 7062-7065. AbstractWebsite

A [2Fe-2S] cluster has been detected in mammalian ferrochelatase, the terminal enzyme of the heme biosynthetic pathway. Natural ferrochelatase, purified from mouse livers, and recombinant ferrochelatase, purified from an overproducing strain of Escherichia coli, were investigated by electron paramagnetic resonance (EPR) and Mossbauer spectroscopy. In their reduced forms, both the natural and recombinant ferrochelatases exhibited an identical EPR signal with g values (g = 2.00, 1.93, and 1.90) and relaxation properties typical of [2Fe-2S](+) cluster. Mossbauer spectra of the recombinant ferrochelatase, purified from a strain of E. coli cells transformed with a plasmid encoding murine liver ferrochelatase and grown in Fe-57-enriched medium, demonstrated unambiguously that the cluster is a [2Fe-2S] cluster. No change in the cluster oxidation state was observed during catalysis, The putative protein binding site for the Fe-S cluster in mammalian ferrochelatases is absent from the sequences of the bacterial and yeast enzymes, suggesting a possible role of the [2Fe-2S] center in regulation of mammalian ferrochelatases.