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This paper presents a comparative evaluation of efficiencies of different accelerated ageing tests (freezethaw, thermal shock, salt crystallization, dissolution and wetting-drying) and fuzzy inference system in predicting weathering degrees of some monument stones from three historical sites (Anahita Temple, Anobanini reliefs and Eshkaft-e Salman reliefs, Iran). The combined effects of natural weathering processes (heating and cooling, wetting and drying, and freezing and thawing) and climatic information were used for assessing the natural weathering degrees. Finally, the natural weathering degrees were multiplied by time effect coefficients to obtain more realistic natural weathering degrees of the monuments. The predicted natural weathering degrees for Anahita Temple, Anobanini reliefs and Eshkaft-e Salman reliefs are 56%, 61%, and 47%, respectively. These predicted values reasonably support the weathering degrees defined by progressive decay indices (calculated equal to 2.77, 3.42 and 2.66 for Anahita Temple, Anobanini reliefs and Eshkaft-e Salman reliefs, respectively), which means the fuzzy model potentially could accurately predict the weathering of stones.

Carbon Fiber Reinforced Polymer (CFRP) composites have a large potential for strengthening and retrofitting steel parts but due to their premature debonding from steel, further data and research are still required for wider application in such situations. In the present paper, the bond characteristics of CFRP-to-steel joints in pull-pull loaded conditions were studied. Monotonic loading of the double strap joints with different bond lengths was applied and the failure modes and interfacial bond-slip curves were obtained. A tri-linear bondslip model is proposed and it was derived from the experimental data. A closed-form solution approach is also proposed based on the tri-linear bond-slip model. The strength of the CFRP-to-steel interface, the distribution of the relative displacements between bonded materials, the strains developed in the CFRP laminate and the bond stresses along the interface are reported and the closed-form solution is compared with the experimental results. Two cases are selected for presentation: (i) one with the bond length greater than the effective bond length; and, inversely, (ii) one with bond length which is shorter than the effective bond length. The results predicted by the closed-form solutions are shown to be accurate enough when compared to the experiments.

Nitrous oxide reductase is the enzyme that catalyses the last step of the denitrification pathway, reducing nitrous oxide to dinitrogen gas. This enzyme is a functional homodimer with two copper centres, CuA and a "CuZ centre", located in different domains. The CuA centre is the electron transferring centre, while the catalytic centre is the "CuZ centre", a unique metal centre in biology - a tetranuclear copper centre with a μ4-bridging sulphide. The enzyme has been isolated with the "CuZ centre" in two different forms, CuZ(4Cu2S) and CuZ∗(4Cu1S), with the first presenting an additional μ2-sulphur atom as a bridging ligand between CuI and CuIV of the "CuZ centre", whereas the second form was identified as a water-derived molecule. Spectroscopic analysis of CuZ∗(4Cu1S), together with computational studies, indicated that there is a hydroxide bound to CuI. Genomic analysis has identified the presence of two different types of nitrous oxide reductase, the typical and "atypical", with a single member of the last group having been isolated to date, from Wolinella succinogenes. Thus, here the structure of the "typical" nitrous oxide reductase with either CuZ(4Cu2S) or CuZ∗(4Cu1S), as well as its spectroscopic and catalytic properties, will be discussed. © The Royal Society of Chemistry 2017.

The main goal of the present research work is to characterise a unidirectional fibre reinforced grout (UFRG), developed as an alternative material to strengthen RC structures using small thickness jacketing. A high performance cementitious grout reinforced with continuous and unidirectional non-woven steel fibre mat has been developed for this purpose. It was expected that the optimization of the percentage and alignment of the steel fibres would yield a more efficient fibre grout. In fact, the composite should attain higher tensile strength with continuous fibres since the fibre embedment length is enough to prevent fibre pull-out. An experimental programme was carried out to characterise the UFRG’s mechanical properties. Compressive tests were conducted on small thickness tubular specimens to enable the determination of the compressive strength and the static modulus of elasticity. The tensile strength was obtained from splitting tests performed on cubic specimens (DIN 1048-5). Semi-empirical equations, based on the experimental results, are proposed to estimate UFRG’s modulus of elasticity, compressive strength and tensile strength. Two strengthening solutions for RC structures using small thickness CFRP jacketing are presented.

Abstract Ancient structures are part of the inheritance our elders left us. These historical inheritance needs to be preserved, so the historic structures need to be rehabilitated and restored, protecting the cultural patrimony and attending to the comfort and habitability required nowadays. In order to accomplish a good and economic rehabilitation is essential to study the behaviour of traditional structures elements (masonry and wood) in order to develop adequate assessment measures and techniques. In this context it was carried out an experimental campaign to characterize the tensile mechanical behavior of the woods from the �sequeiro� wood structure, integral part of the �Quinta de Lobeira de Cima� farm. This building from the 20th century is located in Minho, Portugal. Tensile Tests were carried out for two different species of wood, chestnut and oak. The tensile tests were performed to obtain the tensile strength parallel to the fibers, using the digital image correlation (DIC) for the extension measurement.

Abstract This paper proposes an experimental study aiming to evaluate stress intensity factors (SIFs) for fatigue cracks propagating under pure mode I and mixed-mode I+II for a S235 structural steel. Compact tension (CT) specimens with a side hole were manufactured in order to generate a stress field, ahead of the crack tip, resulting in mixed-mode fatigue crack propagation. Specimens with distinct side hole locations were submitted to fatigue tests under stress controlled conditions for a stress rati

Weathering imposes vital effects on stony monuments. Mostly, the degree of weathering is determined by simple test results, ignoring simultaneous effects of various weathering factors. Hence, the main purpose of this study is to develop prediction models with fuzzy inference systems to determine the weathering degree of the Persepolis stone, using various accelerated ageing tests in laboratory condition and to extrapolate the results to the natural condition, considering climatic information. The results suggest reliable conformity between the prediction of the weathering degree of the stone and the weathering degree observed in the Persepolis complex in natural condition.

The effect of ply thickness on the onset of intralaminar and interlaminar damage is extremely important for the structural response of laminated composite structures. This subject has gained particular interest in recent years due to the introduction in the market of spread-tow, ultra-thin carbon-fibre reinforcements with different configurations. In the present paper, an experimental test campaign was carried out to study the structural response of aerospace-grade plain weave spread-tow fabrics (STFs) of different areal weights. The results showed that, in spite of an apparent superior longitudinal tensile strength of the thick STF, the multidirectional thin-STF laminate exhibited an improved tensile unnotched strength over the thick-STF laminate, attributed to its damage suppression capability. However, damage suppression was also responsible for similar tensile notched strengths. In compression, the thin-STF laminate performed substantially better than the thick-STF laminate in both unnotched and notched configurations. Finally, a similar bearing response was obtained in both STF laminates, in spite of a slightly higher resistance of the thin-STF laminate to the propagation of subcritical damage mechanisms.

The bonding between two different materials or between same materials is a quite popular method. Unlike fastener joints, it avoids undesirable stress concentrations and doesn't demand an intrusive application to ensure the good performance of the joint. However, depending on the configuration of the adhesively bonded joint, its performance responds differently and the choice (if possible to make) on the best configuration, i.e. the configuration that originates the highest strength and/or stiffness, may be hard to make. Within this context, several configurationsof aluminium-to-aluminium bonded joints unstrengthened and strengthened with fiber reinforced polymers (FRP) were modelled using a commercial finite element code. The linearity and nonlinearity of the FRP composite and the aluminium were considered, respectively, and the adhesively bonded joints were subjected to a regular displacement that intended to simulate a tensioning load. Also, the nonlinearities of the interfaces were considered in the form of nonlinear cohesive adhesive laws. The fracture Modes I and II were defined trough a bond-slip relation with abi-linear shape and the Mohr-Coulomb failure criterion is used for the coupling of the cohesive adhesive laws of the interface when the debonding process of the bonded joint configuration implies the interaction between both fracture modes, i.e. the joint is under a mixed-mode (Mode I+II) situation. The results are presented and discussed and the configurations of the bonded joints are all compared through bond stress distributions and load-slip responses. The study herein presented is, therefore, a contribution to the analysis of the structural integrity of bonded joints between FRP composites and aluminium substrates, helping also on the choice of the most adequatebonded joint configuration and corresponding reinforcement to be used and applied in practice.

A set of three old suspended timber floors were flexurally strengthened with carbon fiber–reinforced polymer (CFRP) strips in order to investigate the effectiveness of externally bonding FRP to their soffits. The specimens were from an old building and 740-mm-wide bands were transferred to the laboratory in order to be tested in a four-point bending test. One specimen was tested with no strengthening system and the results obtained were used as reference values for comparison with the specimens that were externally bonded and reinforced (EBR) with CFRP strips. Two similar EBR systems were studied: (1) keeping both ends of the CFRP strips free of any restriction (traditional technique), and (2) embedding both ends of the CFRP strips into the timber, thus providing a bonding anchorage of the strips (new technique). The installation of the new strengthening system comprises the opening of holes in the timber and the creation of a transition curve between the holes and the timber surface. This transition curve allows a smooth transition of the CFRP laminate between the hole and the timber surface, thus avoiding stress concentrations in this area. After the opening of the holes, the resin is applied inside the hole and on the beam surface, and then the CFRP laminate is mounted. The load-carrying capacity of the specimens, the rupture modes, and the strains and bond stress distributions within the CFRP-to-timber interface are presented. A nonlinear numerical simulation of the specimens based on the midspan cross-sectional equilibrium is also presented. The results showed that the use of the new strengthening system enhances the performance of the specimens when compared with the traditional strengthening system.