Publications

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1999
Fantoni, A.a, Vieira Martins M. b R. a. "Transport properties in microcrystalline silicon solar cells under AM1.5 illumination analyzed by two-dimensional numerical simulation." Solid-State Electronics. 43 (1999): 1709-1714. AbstractWebsite

Microcrystalline silicon is a two-phase material. Its composition can be interpreted as a series of grains of crystalline silicon imbedded in an amorphous silicon tissue, with a high concentration of dangling bonds in the transition regions. In this paper, results for the transport properties of a μc-Si:H p-i-n junction obtained by means of two-dimensional numerical simulation are reported. The role played by the boundary regions between the crystalline grains and the amorphous matrix is taken into account and these regions are treated similar to a heterojunction interface. The device is analyzed under AM1.5 illumination and the paper outlines the influence of the local electric field at the grain boundary transition regions on the internal electric configuration of the device and on the transport mechanism within the μc-Si:H intrinsic layer.

Fantoni, A.a, Vieira Martins M. b R. a. "Transport properties of μc-Si:H analyzed by means of numerical simulation." Thin Solid Films. 337 (1999): 109-112. AbstractWebsite

Microcrystalline silicon is a two-phase material. Its composition can be interpreted as grains of crystalline silicon imbedded in an amorphous silicon tissue, with a high concentration of danglind bonds in the transition regions. In this paper, results obtained by means of numerical simulations about the transport properties of a μc-Si:H p-i-n junction are reported. The role played by the boundary regions between the crystalline grains and the amorphous matrix is taken in account, and these regions are treated similarly to a heterojunction interface. The influence of the local electric field at the grains boundary transition regions on the internal electric configuration of the device is outlined under illumination and applied external bias. © 1999 Elsevier Science S.A. All rights reserved.

1998
Fortunato, E., Soares Lavareda Martins F. G. R. "Thin films applied to integrated optical position-sensitive detectors." Thin Solid Films. 317 (1998): 421-424. AbstractWebsite

We have developed a linear thin film position-sensitive detector with 128 elements, based on p.i.n. a-Si:H devices. The incorporation of this sensor into an optical inspection camera makes possible the acquisition of three-dimensional information of an object, using laser triangulation methods. The main advantages of this system, when compared with the conventional charge-coupled devices, are the low complexity of hardware and software used, and that the information can be continuously processed (analogic detection). In this paper, we present the most significant characteristics of the singular one-dimensional thin film position-sensitive detectors that form part of the linear array with 128 sensors. © 1998 Elsevier Science S.A.

Fortunato, E., Malik Martins A. R. "Thin oxide interface layers in a-Si:H MIS structures." Journal of Non-Crystalline Solids. 227-230 (1998): 1230-1234. AbstractWebsite

Pd-metal/insulator/semiconductor based on hydrogenated amorphous silicon were produced by plasma enhanced chemical vapour deposition with two different oxidised surfaces: thermal in ambient air and chemical with hydrogen peroxide. The diode characteristics have been investigated using dark and light current as f(v) measurements in the temperature range from 300 K to 380 K, from which it was possible to infer the electron barrier height. The data obtained show that the incorporation of a thin insulator layer between the semiconductor and the metal improves the performances of the devices by preventing the formation of suicides at the interface. Apart from that we also show that the MIS structures with the thermal oxide presents 'better' performances than the ones with the chemical oxide due to the type of interface states and of the oxide charges associated with the interface between the insulator and the semiconductor. © 1998 Elsevier Science B.V. All rights reserved.

1996
Martins, R.a, Vieira Ferreira Fortunato Guimarães M. b I. a. "Transport properties of doped silicon oxycarbide microcrystalline films produced by spatial separation techniques." Solar Energy Materials and Solar Cells. 41-42 (1996): 493-517. AbstractWebsite

This paper presents results of the role of the oxygen partial pressure used during the deposition process on the transport properties exhibited by doped microcrystalline silicon oxycarbide films produced by a Two Consecutive Decomposition and Deposition Chamber system, where a spatial separation between the plasma and the growth regions is achieved. This paper also presents the interpretative models of the optoelectronic behaviour observed in these films (highly conductive and transparent with suitable properties for optoelectronic applications) as well as the interpretation of the growth process that leads to film's microcrystallization.

Fantoni, A.a, Vieira Cruz Schwarz Martins M. a J. a. "A two-dimensional numerical simulation of a non-uniformly illuminated amorphous silicon solar cell." Journal of Physics D: Applied Physics. 29 (1996): 3154-3159. AbstractWebsite

We present here a two-dimensional numerical simulation of a hydrogenated amorphous silicon p-i-n solar cell non-uniformly illuminated through the p-layer. This simulation is used to show the effect of the presence of dark regions in the illuminated surface on the electrical behaviour of the device. The continuity equations for holes and electrons together with Poisson's equation, implemented with a recombination mechanism reflecting the amorphous structure of the material, are solved using standard numerical techniques over a rectangular domain. The results obtained reveal the appearance of a lateral component of the electric field and current density vectors inside the structure. The effect of such components is a lateral carrier flow of electrons inside the intrinsic layer and of holes inside the p-layer, resulting in leakage of the transverse current collected at the contacts and an increase in the series resistance.

1994
Fortunato, E., Lavareda Vieira Martins G. M. R. "Thin film position sensitive detector based on amorphous silicon p-i-n diode." Review of Scientific Instruments. 65 (1994): 3784-3786. AbstractWebsite

The application of hydrogenated amorphous silicon (a-Si:H) to optoelectronic devices are now well established as a viable low cost technology and is presently receiving much interest. Taking advantage of the properties of a-Si:H based devices, single and dual axis large area (up to 80×80 mm 2) thin film position sensitive detectors (TFPSD) based on a-Si:H p-i-n diodes have been developed, produced by plasma enhanced chemical vapor deposition. In this study, the main optoelectronic properties presented by the TFPSD as well as their behavior under operation conditions, concerning its linearity and signal to noise ratio, are reported. © 1994 American Institute of Physics.

Martins, Rodrigo, Vieira Manuela Ferreira Isabel Fortunato Elvira Guimaraes L. "Transport properties of doped silicon oxycarbide microcrystalline films produced by spatial separation techniques." Conference Record of the IEEE Photovoltaic Specialists Conference. Vol. 1. 1994. 508-511. Abstract

This paper presents results of the role of the oxygen partial pressure (pO2) used on the properties exhibited by doped μc silicon oxycarbide films produced by a Two Consecutive Decomposition and Deposition Chamber (TCDDC) system [1], where a spatial separation between the plasma and the growth regions is achieved. The films produced are highly conductive and transparent with suitable properties for optoelectronic applications.

1993
Martins, R., Fantoni Vieira A. M. "Tailoring defects on amorphous silicon pin devices." Journal of Non-Crystalline Solids. 164-166 (1993): 671-674. AbstractWebsite

This paper deals with a new model and structure able to tailor defects in pin devices. The model assumes the usual density of states profile, including donor and acceptor like states inside the mobility gap and has the capability to simulate the transient and steady state device behavior. The new structure is based in two interfacial defectous layers, located at the junctions, acting as "gettering" centers to tailor the defects. The role of the interlayer and its thickness on device performances will be also discussed. © 1993.

1991
de Nijs, J.M.M.a, Carvalho Santos Martins C. b M. b. "A thin SiO layer as a remedy for the indium reduction at the In2O3/μc-Si:C:H interface." Applied Surface Science. 52 (1991): 339-342. AbstractWebsite

The reduction of the In2O3 caused by the deposition of μc-Si:C:H by means of plasma-enhanced CVD, is considerably diminished if a thin (50 Å) silicon monoxide layer is applied as a diffusion barrier. The amount of reduced indium diminishes by a factor three while the amount of silicon oxide is also less, although SiO was added on purpose. First results on an amorphous silicon In2O3/pi junction show that the SiO layer benefits the opto-electrical characteristics. © 1991.

1989
Martins, R.a, Willeke Fortunato Ferreira Vieira Santos Maçarico Guimarães G. b E. a. "Transport in μc-Six:Cy:Oz:H films prepared by a TCDDC system." Journal of Non-Crystalline Solids. 114 (1989): 486-488. AbstractWebsite

N- and p-type weakly absorbing and highly conductive microcrystalline thin μc-Six:Cy:Oz:H films, have been produced by a TCDDC (Two Consecutive Decomposition and Deposition Chamber) system1. The optoelectronic and structural results show that we are in the presence of a mixed phase of Si microcrystals (c-islands) embedded in a-Six:Cy:Oz:H (a-tissue). Based on that, we propose a model where transport mechanisms are explained by the potential fluctuations related to films heterogeneities. Thus, conduction is due to carriers that by tunneling or percolation "pass" or "go" trough the barriers and/or percolate randomly by the formed channels. © 1989.

Fortunato, E., Martins Ferreira Santos Maçarico Guimarães R. I. M. "Tunneling in vertical μcSi/aSixCyOz:H/μcSi heterostructures." Journal of Non-Crystalline Solids. 115 (1989): 120-122. AbstractWebsite

In this paper we report by the first time tunneling tranport on vertical μcSi/aSixCyOz:H/μcSi (μcaμc) heterostructures produced in a Two consecutive Decomposition and Deposition Chamber system where a Negative Differential Conductance is observed even at room temperature. Giant bias anomalies are observed, that decrease with temperature. Tunneling spectroscopy data are also reported for samples measured at low temperatures. A qualitative information of the recorded data is obtained and related with main features of the heterostructure. Nevertheless in this stage is hard to take quantitative information. © 1989.