Fortunato, E., Barquinha Pereira Gonçalves Martins P. L. G. "
Multicomponent wide band gap oxide semiconductors for thin film transistors."
Proceedings of International Meeting on Information Display. Vol. 2006. 2006. 605-608.
AbstractThe recent application of wide band gap oxide semiconductors to transparent thin film transistors (TTFTs) is making a fast and growing (r)evolution on the contemporary solid-state electronics. In this paper we present some of the recent results we have obtained using wide band gap oxide semiconductors, like indium zinc oxide, produced by rf sputtering at room temperature. The devices work in the enhancement mode and exhibit excellent saturation drain currents. On-off ratios above 106 are achieved. The optical transmittance data in the visible range reveals average transmittance higher than 80%, including the glass substrate. Channel mobilities are also quite respectable, with some devices presenting values around 25 cm2/Vs, even without any annealing or other post deposition improvement processes. The high performances presented by these TTFTs associated to a high electron mobility, at least two orders of magnitude higher than that of conventional amorphous silicon TFTs and a low threshold voltage, opens new doors for applications in flexible, wearable, disposable portable electronics as well as battery-powered applications.
Fantoni, A., Vieira Martins M. R. "
Modelling heteroface of P.I.N solar cells for improving stability."
Materials Research Society Symposium Proceedings. Vol. 336. 1994. 711-716.
AbstractThe introduction into a traditional p.i.n structure of two defective buffer layers near the p/i and i/n interfaces can improve the device stability and efficiency through an enhancement of the electric field profile at the interfaces and a reduction of the available recombination bulk centers. The defectous layer ("i′-layer"), grown at a higher power density, present a high density of defects and acts as "gettering centers" able to tailor light induced defects under degradation conditions. If the i-layer density of states remains below 1016 eV-1 cm-3 and assuming a Gaussian distribution of defect states, the gettering center distribution will not affect significantly the carrier population but only its spatial distribution. We report here about a device numerical simulation that allows us to analyse the influence of the "i′-layer" position, thickness and density of states on the a-Si: H solar cells performances. Results of some systematic simulation from the ASCA program (Amorphous Solar Cell Analysis), and for different configurations will be presented. © 1994 Materials Research Society.
Fernandes, M.a, Vieira Martins M. a R. b. "
Modeling the laser scanned photodiode S-shaped J-V characteristic."
Materials Research Society Symposium Proceedings. Vol. 989. 2007. 469-474.
AbstractThe devices analyzed in this work present an S-shape J-V characteristic when illuminated. By changing the light flux a non linear dependence of the photocurrent with illumination is observed. Thus a low intensity light beam can be used to probe the local illumination conditions, since a relationship exists between the probe beam photocurrent and the steady state illumination. Numerical simulation studies showed that the origin of this S-shape lies in a reduced electric field across the intrinsic region, which causes an increase in the recombination losses. Based on this, we present a model for the device consisting of a modulated barrier recombination junction in addition to the p-i-n junction. The simulated results are in good agreement with the experimental data. Using the presented model a good estimative of the LSP signal under different illumination conditions can be obtained, thus simplifying the development of applications using the LSP as an image sensor, with advantages over the existing imaging systems in the large area sensor fields with the low cost associated to the amorphous silicon technology. © 2007 Materials Research Society.
Wojcik, P.J., Cruz Santos Pereira Martins Fortunato A. S. L. "
Microstructure control of dual-phase inkjet-printed a-WO 3/TiO 2/WO X films for high-performance electrochromic applications."
Journal of Materials Chemistry. 22 (2012): 13268-13278.
AbstractThe microstructural aspects related to crystalline or amorphous structure of as-deposited and annealed films of sol-gel-derived WO 3 are shown in the literature to be critical for electrochromic (EC) performance. In consideration of ion insertion materials, there is a need for developing light and at the same time nanocrystalline structures to improve both coloration efficiency and switching kinetics. By controlling microstructure and morphology, one could design a material with optimal EC performance. This report compares the microstructural and morphological characteristics of standard WO 3 wet deposition techniques versus inkjet printing technology (IPT), correlating these features with their optical and electrochemical performances, emphasizing the importance of the dual-phase a-WO 3/TiO 2/WO X film composition proposed in this work for high-performance EC applications. The effect of the type and content of metal oxide nanoparticles in the precursor sols formulated in various peroxopolytungstic acid (PTA) and oxalic acid (OAD) proportions on film properties is comprehensively studied using multi-factorial design of experiment (DOE). To the authors' knowledge, no other report on sol-gel deposition of inorganic EC materials via the inkjet printing technique exists, in which furthermore the film crystallinity can be controlled under low-temperature process conditions. The proposed method enables development of EC films which irrespective of their composition (a-WO 3, a-WO 3/TiO 2 or a-WO 3/TiO 2/WO X) outperform their amorphous or nanocrystalline analogues presented as the state-of-the-art due to their superior chemical and physical properties. © 2012 The Royal Society of Chemistry.
Alendouro, M.S.J.G.a, Monteiro Figueiredo Martins Silva Ferro Fernandas R. C. C. a. "
Microstructural characterization and properties of a glass and a glassceramic made from municipal incinerator bottom ash."
Materials Science Forum. 455-456 (2004): 827-830.
AbstractA glass was made using bottom ash produced by a Portuguese municipal solid waste (MSW) incinerator. The bottom ash was the single batch material used in the formation of the glass, which was obtained through a conventional melt-quenching method. The glass was then converted to glass-ceramic for further recycling to construction materials. After submitting the glass samples to several heat treatments, between 820 and 1050°C and during different times, it was verified that the optimum heat treatment schedule for the ceramization of the glass was at 1000°C for 10h, as confirmed by microstructural observation and by X-ray diffraction. The major crystalline phases precipitated in the glass-ceramic were wollastonite (CaSiO3) and diopside (Ca(Mg,Al)(Si,Al)2O6). Microstructural analysis of the glass-ceramic revealed that the crystalline phases were present as dendrites and fiber-like structures that were homogeneously distributed in the material. The glassceramic showed good mechanical properties with a hardness of 5.6 MPa and a bending strength of 101 MPa. This material had a density of 2.8 gcm-3 and a thermal expansion coefficient of 9.10-6°C-1. The glass and the glass-ceramic showed an excellent chemical stability against leaching in acidic solution and in alkaline solution. In summary, both the glass and the glass-ceramic have good chemical and mechanical properties and can, therefore, be applied as construction materials.
Malik, A.a, Sêco Fortunato Martins A. c E. b. "
Microcrystalline thin metal oxide films for optoelectronic applications."
Journal of Non-Crystalline Solids. 227-230 (1998): 1092-1095.
AbstractWe report the properties and optoelectronic applications of transparent and conductive indium and tin oxide films prepared by the spray pyrolysis method and doped with Sn or F, respectively. The film properties have been measured using X-ray diffraction, optical and electrical absorption. As examples of applications we produced a set of selective optical detectors for different spectral regions, covering the wavelength range from 0.25 to 1.1 μm, based on metal oxide-semiconductor heterostructures and using different substrates such as: GaP, GaSe, AlxGa1-xAs, GaAs and Si. The fabricated devices exhibit several features such as: production simplicity, high quantum efficiency, uniform sensitivity over the entire active area and a high response speed. Finally, we present a high quantum efficiency and solar blind monocrystalline zinc sulphide optical sensor fabricated by spray deposition as an alternative to the ultraviolet-enhanced SiC and GaN photodetectors and the performances of a solar cell. © 1998 Elsevier Science B.V. All rights reserved.
Kholkin, A.L.b, Martins Águas Ferreira Silva Smirnova Costa Vilarinho Fortunato Baptista R. a H. a. "
Metal-ferroelectric thin film devices."
Journal of Non-Crystalline Solids. 299-302 (2002): 1311-1315.
AbstractFerroelectric and high dielectric permittivity films are currently being investigated in view of their use as gate dielectrics in MIS structures. Along with the suppression of tunnelling currents at small gate thickness, they provide a memory function to MIS structures, which can be used in non-volatile memory applications. In this work we report fabrication and characterization of novel metal-ferroelectric-amorphous silicon structures. The structures consist of glass/ITO substrates coated with PZT 20/80 films (sol-gel) followed by an active layer (i-a-SiC:H, deposited by plasma enhanced chemical vapor deposition (PECVD)). A strong capacitance hysteresis is observed in C-V curves in electron accumulation region (VG > 0), accompanied with a large increase in the capacitance of ferroelectric-semiconductor structures at low frequencies. Threshold voltage for electron accumulation is about 10 V being dependent on the ferroelectric polarization switching. © 2002 Elsevier Science B.V. All rights reserved.
Malik, A., Martins R. "
Metal oxide/silicon heterostructures: New solutions for different optoelectronic applications."
Materials Research Society Symposium - Proceedings. Vol. 487. 1998. 375-380.
AbstractIn this paper we report the success in fabricating FTO/Si surface-barrier photodiodes produced by spray pyrolysis deposition technique, under ambient conditions. Three types of photodetectors for low-voltage-bias operation were developed based on high-resistivity silicon: 1. X-Ray detectors with energy resolution of 16.5% at 661.5 keV (137Cs source), consisting of surface-barrier PIN photodiode with an active area of 50 mm2 operating at 5 V reverse bias, scintillator based on monocrystalline Bi4Ge3O12 and preamplifier (noise of 250 e- RMS.); 2. Fast-response surface-barrier FTO/n–n+ silicon epitaxial photodiodes, operating at 10 V bias with rise times of 2 ns at λ = 0.85 μm; 3. Radiation-resistant drift epitaxial surface-barrier PIN photodiodes for unbiased operating conditions, with an exponential impurity distribution in a 8 μm thick epitaxial layer. A built-in electrical field due to the carrier concentration distribution in the epitaxial layer provides a considerable improvement in the `critical fluence' value (3×1014 cm-2) for neutron irradiation.
Wojcik, P.J., Pereira Martins Fortunato L. R. E. Metal oxide nanoparticle engineering for printed electrochemical applications. Handbook of Nanoelectrochemistry: Electrochemical Synthesis Methods, Properties, and Characterization Techniques., 2016.
AbstractEngineering procedures governing the selection or development of printable nanostructured metal oxide nanoparticles for chromic, photovoltaic, photocatalytic, sensing, electrolyte-gated TFTs, and power storage applications are established in this chapter. The main focus is given on how to perform the material selection and formulation of printable dispersion in order to develop functional films for electrochemical applications. This chapter is divided into four main parts. Firstly, a brief introduction on electrochemically active nanocrystalline metal oxide films developed via printing techniques is given. This is followed by the description of the film morphology, structure, and required functionality. A theoretical approach to understand the impact of size and shape of nanoparticles on an ink formulation and electrochemical performance being the subject of the third section provides a greater control over the material selection. We attempt to describe these properties and show that for a given material, geometry and size of the nanoparticles have a major influence on the electrochemical reactivity and response time. This gives the ability to tune the performance of the film simply by varying the morphology of incorporated nanostructures. This section is completed by the recommendations on each major step of an ink formulation, together with imposed critical constraints concerning the fluid control. Finally, the performance of the ink-jetprinted dual-phase electrochromic films is discussed as a case study. By providing such a rather systematic survey, we aim to stress the importance of proper design strategy that would result in both improved physicochemical properties of nanoparticle-loaded inks and enhanced electrochemical performance of printed functional films. © Springer International Publishing Switzerland 2016.