The optical properties of localized surface plasmon resonances (LSPR) sustained by self-assembled silver nanoparticles are of great interest for enhancing light trapping in thin film photovoltaics. First, we report on a systematic investigation of the structural and the optical properties of silver nanostructures fabricated by a solid-state dewetting process on various substrates. Our study allows to identify fabrication conditions in which circular, uniformly spaced nanoparticles are obtainable. The optimized NPs are then integrated into plasmonic back reflector (PBR) structures. Second, we demonstrate a novel procedure, involving a combination of opto-electronic spectroscopic techniques, allowing for the quantification of useful and parasitic absorption in thin photovoltaic absorber deposited on top of the PBR. We achieve a significant broadband useful absorption enhancement of 90{%} for 0.9 µm thick $μ$c-Si:H film and demonstrate that optical losses due to plasmonic scattering are insignificant below 730 nm. Finally, we present a successful implementation of a plasmonic light trapping scheme in a thin film a-Si:H solar cell. The quantum efficiency spectra of the devices show a pronounced broadband enhancement resulting in remarkably high short circuit current densities (Jsc).

Combined perovskite/crystalline-silicon four-terminal tandem solar cells promise {\textgreater}30{%} efficiencies. Here we propose all-thin-film double-junction architectures where high-bandgap perovskite top cells are coupled to ultrathin c-Si bottom cells enhanced with light trapping. A complete optoelectronic model of the devices was developed and applied to determine the optimal intermediate layers, which are paramount to maximize the cells' photocurrent. It was ascertained that by replacing the transparent conductive oxides by grid-based metallic contacts in the intermediate positions, the parasitic absorption is lowered by 30{%}. Overall, a 29.2{%} efficiency is determined for ∼2 um thick tandems composed of the optimized interlayers and improved with Lambertian light trapping.

ZnSnO3 semiconductor nanostructures have several applications as photocatalysis, gas sensors, and energy harvesting. However, due to its multicomponent nature, the synthesis is far more complex than its binary counter parts. The complexity increases even more when aiming for low-cost and low-temperature processes as in hydrothermal methods. Knowing in detail the influence of all the parameters involved in these processes is imperative, in order to properly control the synthesis to achieve the desired final product. Thus, this paper presents a study of the influence of the physical parameters involved in the hydrothermal synthesis of ZnSnO3 nanowires, namely volume, reaction time, and process temperature. Based on this study a growth mechanism for the complex Zn:Sn:O system is proposed. Two zinc precursors, zinc chloride and zinc acetate, were studied, showing that although the growth mechanism is inherent to the material itself, the chemical reactions for different conditions need to be considered.

Green and lean are manufacturing management paradigms that identify new opportunities to improve the business to be more competitive. The purpose of this research is to contribute for the understanding of how to address green–lean approaches in a supply chain. The objective is to provide basic mechanisms to implement an organization’s supplychain based on an integrated green and lean approach. To attain this objective, some relevant initiatives for a green and lean transformation were considered first. Second, a multiple case study was conducted in the automotive industry to test qualitatively the several integrated green and lean initiatives and see how they are being implemented in the real world. Based on the literature review and the case study, an oriented-tool is suggested, which involves a roadmap to achieve a green–lean supply-chain transformation. The proposed roadmap can serve as the basis for further research in green and lean supply chain management, providing insights into the implementation of a green–lean approach.

The human natural killer-1 (HNK-1) epitope is a unique sulfated trisaccharide sequence presented on O- and N-glycans of various glycoproteins and on glycolipids. It is overexpressed in the nervous system and plays crucial roles in nerve regeneration, synaptic plasticity, and neuronal diseases. However, the investigation of functional roles of HNK-1 in a more complex glycan context at the molecular level remains a big challenge due to lack of access to related structurally well-defined complex glycans. Herein, we describe a highly efficient chemoenzymatic approach for the first collective synthesis of HNK-1-bearing O-mannose glycans with different branching patterns, and for their nonsulfated counterparts. The successful strategy relies on both chemical glycosylation of a trisaccharide lactone donor for the introduction of sulfated HNK-1 branch and substrate promiscuities of bacterial glycosyltransferases that can tolerate sulfated substrates for enzymatic diversification. Glycan microarray analysis with the resulting complex synthetic glycans demonstrated their recognition by two HNK-1-specific antibodies including anti-HNK-1/N-CAM (CD57) and Cat-315, which provided further evidence for the recognition epitopes of these antibodies and the essential roles of the sulfate group for HNK-1 glycan-antibody recognition.

CO2 capture and utilization (CCU) technologies are being immensely researched as means to close the anthropogenic carbon cycle. One approach known as artificial photosynthesis uses solar energy from photovoltaics (PV), carbon dioxide and water to generate hydrocarbon fuels, being methane (CH4) a preferential target due to the already in place infrastructures for its storage, distribution and consumption. Here, a model is developed to simulate a direct (1-step) solar methane production approach, which is studied in two scenarios: first, we compare it against a more conventional 2-step methane production route, and second, we apply it to address the energetic needs of concept buildings with usual space and domestic hot water heating requirements. The analysed 2-step process consists in the PV-powered synthesis of an intermediate fuel – syngas – followed by its conversion to CH4 via a Fischer–Tropsch (methanation) process. It was found that the 1-step route could be adequate to a domestic, small scale use, potentially providing energy for a single-family house, whilst the 2-step can be used in both small and large scale applications, from domestic to industrial uses. In terms of overall solar-to-CH4 energy efficiency, the 2-step method reaches 13.26{%} against the 9.18{%} reached by the 1-step method. Next, the application of the direct solar methane technology is analysed for domestic buildings, in different European locations, equipped with a combination of solar thermal collectors (STCs) and PV panels, in which the heating needs that cannot be fulfilled by the STCs are satisfied by the combustion of methane synthesized by the PV-powered electrolyzers. Various combinations of situations for a whole year were studied and it was found that this auxiliary system can produce, per m2 of PV area, in the worst case scenario 23.6 g/day (0.328 kWh/day) of methane in Stockholm, and in the best case scenario 47.4 g/day (0.658 kWh/day) in Lisbon.

One of the most promising approaches to produce industrial-compatible Transparent Conducting Materials (TCMs) with excellent characteristics is the fabrication of TCO/metal/TCO multilayers. In this article, we report on the electro-optical properties of a novel high-performing TCO/metal/TCO structure in which the intra-layer is a micro-structured metallic grid instead of a continuous thin film. The grid is obtained by evaporation of Ag through a mask of polystyrene colloidal micro-spheres deposited by the Langmuir-Blodgett method and partially dry-etched in plasma. IZO/Ag grid/IZO structures with different thicknesses and mesh dimensions have been fabricated, exhibiting excellent electrical characteristics (sheet resistance below 10 $Ømega$/□) and particularly high optical transmittance in the near-infrared spectral region as compared to planar (unstructured) TCM multilayers. Numerical simulations were also used to highlight the role of the Ag mesh parameters on the electrical properties.

Due to the ongoing technical advancements in robotics, new organizational and occupational impacts are expected in different sectors. The contribution of António Moniz and Bettina-Johanna Krings focuses on the social conditions under which technology is embedded into production processes. Thus, social distribution processes, demographic change, sustainability becomes more and more important when reflecting about "technology futures".
In particular they will ask:
How does automation change work & working conditions?
Which expectations on technology are strengthen-ing the concepts of work?
Which regulations and ethics principles must be considered (safety, autonomy, control)?
Which new competences and qualification dimen-sions will be raised for non-routine tasks in auto-mated environments?
Which new types of human-machine interaction can be developed with increased cyber-physical system application at the shopfloor?

Deterioration of adhesively bonded CFRP/steel systems in salt fog environment, i.e., deicing salts and ocean environments, has to be taken into account in the design of steel strengthened structures. In the present work, monotonic and quasi-static cyclic loading were applied to CFRP-to-steel double strap joints for two kinds of CFRP laminates after being aged for a period of 5000 h to evaluate the bond behavior. The bonded joints exposed to salt fog had a different failure mode than that observed in the control specimens (0 h of exposure). The severe reduction of the maximum bond stress resulted from damage initiation that occurred in the corrosion region of the steel substrate, associated with final partial rupture on the corroded steel substrate around the edge of the bonded area: it was also correlated with reduced load carrying capacity. Results of pseudo-cyclic tests showed that the relationship between a local damage parameter (D) and normalized local dissipated energy (Wd/Gf) and the normalized slip increment (ΔS/ΔSult) exhibited almost the same trend in the un-aged and aged bonded joints. The normalized slip increment can be seen as a direct indicator for the local and global damage for the un-aged and aged bonded joints. However, monotonic and quasi-static cyclic tests results revealed that the stress concentration due to local corrosion of steel substrate could lead to brittle rupture or accelerated cumulative damage once the aged bonded interface had become weaker. The bonded joints have exhibited also a smaller relative deformation capacity between CFRP and steel.

This paper evaluates and compares the statistics of compressive strength data from three Portuguese ready-mixed concrete plants. A hierarchical model showed that different groups of concrete strength records are not statistically equivalent, even if they were produced in the same plant and using the same concrete composition. This finding is related to autocorrelation. For the same specified strength class, compositions produced less often result in higher average compressive strength and variability. The statistics of one of the plants were quite different from those of the others, even though the concrete of this plant also complied with the specifications. It was found that the average compressive strength of a mix may be quite dependent on the plant that produced it, even if the compressive strength complies with quality control specifications. Conformity with the target slump and strength class was checked following the conformity criteria of EN 206-1 for continuous production. Nonconformity with slump is more frequent than failure to comply with the strength class. A bias factor for reliability analyses was proposed.

The bias factor of the Eurocode 2 [CEN (European Committee for Standardization) (2008). Eurocode 2: Design of ConcreteStructures–Part 1-1: General Rules and Rules for Buildings] and ACI 318 [ACI (American Concrete Institute) (2014). Building CodeRequirements for Structural Concrete and Commentary] flexural resistance models of reinforced concrete beams are compared withemphasis on the effect of the incorporation of coarse recycled aggregates sourced from concrete waste. The bias factor of the yielding momentcalculations according to both codes is also investigated, and the bias in the cracking moment when Eurocode 2 material clauses are used. Thedatabase was composed of 174 beams, and the criteria that led to its development are discussed. The effect of recycled aggregate incorporationon the statistical descriptors of the bias factor is evaluated and probabilistic modeling using lognormal distributions is argued for. Preliminarypartial safety factors for the bias factor of recycled aggregate concrete beams are proposed. No significant differences in the bias of theultimate moment were found between the two comparison vectors: Eurocode 2 versus ACI 318 specifications and recycled versus naturalcoarse aggregate. The bias of the cracking moment increased when coarse recycled aggregates were incorporated, most probably due to thehigher heterogeneity of recycled aggregates.