{Two new bis(aryl-imino)-acenaphthene, Ar-BIAN (Ar = 2

Journal of Analytical Atomic Spectrometry (2020), 35, 2920-2927, doi:10.1039/D0JA00307G

This paper reports on-chip rail-to-rail timing signals generation thin-film circuits for the first time. These circuits, based on a-IGZO thin-film transistors (TFTs) with a simple staggered bottom gate structure, allow row and column selection of a sensor matrix embedded in a flexible radiation sensing system. They include on-chip clock generator (ring oscillator), column selector (shift register) and row-selector (a frequency divider and a shift register). They are realised with rail-to-rail logic gates with level-shifting ability that can perform inversion and NAND logic operations. These logic gates are capable of providing full output swing between supply rails, $V_{DD}$ and $V_{SS}$ , by introducing a single additional switch for each input in bootstrapping logic gates. These circuits were characterised under normal ambient atmosphere and show an improved performance compared to the conventional logic gates with diode connected load and pseudo CMOS counterparts. By using these high-performance logic gates, a complete rail-to-rail frequency divider is presented from measurements using D-Flip Flop. In order to realize a complete compact system, an on-chip ring oscillator (output clock frequency around 1 kHz) and a shift register are also presented from simulations, where these circuits show a power consumption of 1.5 mW and 0.82 mW at a supply voltage of 8 V, respectively. While the circuit concepts described here were designed for an X-ray sensing system, they can be readily expanded to other domains where flexible on-chip timing signal generation is required, such as, smart packaging, biomedical wearable devices and RFIDs.

Abstract Photonic front-coatings with self-cleaning properties are presented as means to enhance the efficiency and outdoor performance of thin-film solar cells, via optical enhancement while simultaneously minimizing soiling-related losses. This is achieved by structuring parylene-C transparent encapsulants using a low-cost and highly-scalable colloidal-lithography methodology. As a result, superhydrophobic surfaces with broadband light-trapping properties are developed. The optimized parylene coatings show remarkably high water contact angles of up to 165.6° and extremely low adhesion, allowing effective surface self-cleaning. The controlled nano/micro-structuring of the surface features also generates strong anti-reflection and light scattering effects, corroborated by numeric electromagnetic modeling, which lead to pronounced photocurrent enhancement along the UV?vis?IR range. The impact of these photonic-structured encapsulants is demonstrated on nanocrystalline silicon solar cells, that show short-circuit current density gains of up to 23.6%, relative to planar reference cells. Furthermore, the improvement of the devices' angular response enables an enhancement of up to 35.2% in the average daily power generation.

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Zinc K-shell radiative and radiationless transition rates are calculated using the multiconfiguration Dirac–Fock method. Correlation up to the 4p orbital is included in almost all transition rate cal...

The relevance of microalgae biotechnology for producing high-value compounds with biomedical application, such as polysaccharides, has been increasing. Despite this, the knowledge about the composition and structure of microalgae polysaccharides is still scarce. In this work, water-soluble polysaccharides from Nannochloropsis oculata were extracted, fractionated, structurally analysed, and subsequently tested in terms of immunostimulatory activity. A combination of sugar and methylation analysis with interaction data of carbohydrate-binding proteins using carbohydrate microarrays disclosed the complex structural features of the different polysaccharides. These analyses showed that the water-soluble polysaccharides fractions from N. oculata were rich in ($\beta$1→3, $\beta$1→4)-glucans, ($\alpha$1→3)-, ($\alpha$1→4)-mannans, and anionic sulphated heterorhamnans. The immunostimulatory assay highlighted that these fractions could also stimulate murine B-lymphocytes. Thus, the N. oculata water-soluble polysaccharides show potential to be further explored for immune-mediated biomedical applications.

The aim of the present paper is to evaluate the gravity loads effect in the behaviour of reinforced concrete beams critical zones subjected to cyclic loads. A numerical study to assess the influence of gravity load on RC beam critical zones subjected to cyclic loading is presented, assuming the level of gravity load as a variable parameter. For this purpose, the non-linear model was previously validated with an experimental campaign carried out on RC beam connection subject to cyclic loading with and without gravity loads. The consideration of the gravity load effects led to an accumulation of negative (hogging) deformation and the formation of an unidirectional plastic hinge. In order to validate this behaviour in an overall structural response, a non-linear numerical analysis of a RC frame system under cyclic loads, subject to different levels of gravity load, is also presented. The numerical results are analysed in terms of global hysterical response, accumulated energy dissipation and equivalent viscous damping ratio. In this numerical study was observed that the hysteretic response depends on the load path. In the presence of higher gravity loads levels, the structure hysteretic behaviour exhibits higher damage levels and the failure mechanism is prone to the formation of four plastic hinges. This phenomenon is analysed and discuss in the present paper. © Federation Internationale du Beton (fib) - International Federation for Structural Concrete, 2019.

An analysis on the effect of the incorporation of coarse recycled concrete aggregates on the bond strength between concrete and embedded steel reinforcement is presented. The model’s uncertainty of the Level I provision of the anchorage length of fib Bulletin 72 on ribbed steel/recycled aggregate concrete bond is quantified. Afterwards, reliability analyses on the bond strength are made and a partial safety factor for the anchorage length of recycled concrete elements is proposed. The model’s uncertainty is evaluated through data from pullout tests, the only type of bond test that has been so far performed extensively on recycled aggregate concrete specimens. The limitations of this test in reproducing the bond of actual structural elements is discussed, and the model’s uncertainty is converted to that of lap splice tests. The bond strength of recycled aggregate concrete design was found to be less reliable than that of natural aggregate concrete, especially in the absence of confining reinforcement. For concrete with full recycled aggregate incorporation, a 25% increase in the anchorage length is proposed. Additional testing on the bond strength of lapped splices or beam-end specimens is recommended.

This paper analyses the studies made so far on the variability and reliability of recycled aggregate concrete. Since recycled aggregate concrete is seen by different agents of the construction industry as a variable material and no structural code has specifically been calibrated to its use, its role as a structural material is limited. Such calibration is hindered since specific research on the statistical and probabilistic data of recycled aggregate concrete properties is lacking.Investigations on the probabilistic knowledge of recycled aggregates and recycled aggregate concrete properties are discussed, and the studies made so far on the reliability of recycled aggregate concrete elements are summarised. Final remarks regarding the future prospects towards the consensual acceptance of recycled aggregate concrete structures are provided.

An investigation on the scatter of code-type constitutive models that relate compressive strength (fc) with tensile strength (fct) and Young’s modulus (Ec) of standard concrete specimens is presented. The influence of the mix design on the accuracy of the fc vs. fct and fc vs. Ecrelationships is discussed, with emphasis on the lithological type and morphology of the coarse aggregates. The uncertainty of the constitutive models is analysed in probabilistic terms and random variables that model the uncertainty of the fc vs. fct and fc vs. Ec relationships are proposed for reliability analyses of serviceability limit states. The suitability of the models proposed is assessed through preliminary conservative estimates of their design values.