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A classical theorem of Coifman, Rochberg, and Weiss on commutators of singular integrals is extended to the case of generalized Lp spaces with variable exponent.

Given a complete rewriting system R on X and a subset X0 of X+ satisfying certain conditions, we present a complete rewriting system for the submonoid of M(X;R) generated by X0. The obtained result will be applied to the group of units of a monoid satisfying H1 = D1. On the other hand we prove that all maximal subgroups of a monoid defined by a special rewriting system are isomorphic.

This thesis deals with the analysis of the behaviour of retrofitting reinforced concrete circular columns with FRP materials which were subjected either to axial cyclic compression or axial compression and alternated cyclic horizontal loads. The choice of this topic derived from the need to investigate the behaviour of the strengthening of reinforced concrete columns to seismic actions, especially with new materials such as carbon and glass fibres or polymeric mortars. Another reason for such choice is linked to the strong seismicity of the Portuguese territory.
It has been verified that confined concrete columns with FRP jackets have their resistance and ductility highly increased as these considerably reduce the columns transversal deformation, thus preventing the buckling of longitudinal reinforcement. There has been an increasing use of FRP composites in the strengthening of structures, mainly with GFRP (Glass Fibre Reinforced Plastics) or CFRP (Carbon Fibre Reinforced Plastics). This is due to their attractive characteristics such as high resistance to corrosion, lowratio for weight/strength, moldability, easy application and the fact that there is no need of support structures.
Forty-five experimental tests were carried out, dealing with retrofitting reinforced concrete columns with axial monotonic or cyclic compression reinforced with FRP composites. The column height of 750 mm was maintained in order to evaluate the influence of several parameters in its behaviour: the column geometry (change in its diameter), the type of column (plain or reinforced concrete), transversal reinforcement ratio of concrete columns, the type of external confinement with FRP (C or GFRP), the number of FRP layers and the type of axial loading (monotonic or cyclic).
Twelve additional experimental tests were conducted in order to analyse the behaviour of reinforced concrete columns jacketed with FRP composites and subjected to axial cyclic compression and alternated cyclic horizontal loads. The columns’ dimension was maintained (1500 mm height by 250 mm diameter) and the models were subjected to a series of cyclic and alternated loadings. This enabled the study of the various parameters’ influence in their behaviour such as the type of FRP confinement, the number of FRP layers, the level of axial loading, the jacket’s height or the strengthening of the plastic hinge by replacing the cover concrete with polymeric mortar.
Based on the numerical models presented and experimental analysis carried out, models were proposed and developed to simulate the behaviour of columns jacketed with FRP composites.

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A series of hydrogenated amorphous silicon carbide (a-Si 1- xC x:H) films were prepared by plasma-enhanced chemical vapour deposition (PECVD) using a gas mixture of silane, methane, and hydrogen as the reactive source. The previous results show that a high excitation frequency, together with a high hydrogen dilution ratio of the reactive gases, allow an easier incorporation of the carbon atoms into the silicon-rich a-Si 1-xC x:H film, widen the valence controllability. The data show that films with optical gaps ranging from about 1.9 to 3.6 eV could be produced. In this work the influence of the hydrogen dilution ratio of the reactive gases on the a-Si 1-xC x:H film properties was investigated. The microstuctural and photoelectronic properties of the silicon carbide films were characterized by Rutherford backscattering spectrometry (RBS), elastic recoil detection analysis (ERDA), and FT-IR spectrometry. The results show that a higher hydrogen dilution ratio enhances the incorporation of silicon atoms in the amorphous carbon matrix for carbon-rich a-Si 1-xC x:H films. One pin structure was prepared by using the a-Si 1-xC x:H film as the intrinsic layer. The light spectral response shows that this structure fits the requirement for the top junction of colour sensor. © 2004 Elsevier B.V. All rights reserved.

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An understanding of space charge build-up in the polymeric insulation of power cables is important in determining how aging occurs and progresses and, also in predicting cable lifetime. In this investigation electric-field induced space charge in peelings from XLPE (cross-linked polyethylene) cables was measured using two different methods: the pulsed electro-acoustic technique (PEA) and the combined procedure of isothermal and non-isothermal charging/discharging currents (FTSDC). These two methods allow the study of space charge in highly insulating materials. Also, since electric fields of different orders of magnitude are applied to the sample in the two methods, it is possible to analyze different characteristics of the space charge traps. Prior to the measurements the samples were subjected to conditioning to remove volatiles. Cable peelings from various brands aged under different conditions (including field aged and thermally aged samples) were studied as received from the manufacturers. Some of the samples have undergone further ageing in AC electric field (50Hz) for 1000h to see the influence of further ageing on space charge build-up. The results for the different types of samples are compared in an attempt to correlate different ageing parameters.

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The thermal decompositions of methyl azidoformate (N3COOMe), ethyl azidoformate (N3COOEt) and 2-azido-N,N-dimethylacetamide (N3CH2CONMe2) have been studied by matrix isolation infrared spectroscopy and real-time ultraviolet photoelectron spectroscopy. N2 appears as an initial pyrolysis product in all systems, and the principal interest lies in the fate of the accompanying organic fragment. For methyl azidoformate, four accompanying products were observed: HNCO, H2CO, CH2NH and CO2, and these are believed to arise as a result of two competing decomposition routes of a four-membered cyclic intermediate. Ethyl azidoformate pyrolysis yields four corresponding products: HNCO, MeCHO, MeCHNH and CO2, together with the five-membered-ring compound 2-oxazolidone. In contrast, the initial pyrolysis of 2-azido-N,N-dimethyl acetamide, yields the novel imine intermediate Me2NCOCHNH, which subsequently decomposes into dimethyl formamide (HCONMe2), CO, Me2NH and HCN. This intermediate was detected by matrix isolation IR spectroscopy, and its identity confirmed both by a molecular orbital calculation of its IR spectrum, and by the temperature dependence and distribution of products in the PES and IR studies. Mechanisms are proposed for the formation and decomposition of all the products observed in these three systems, based on the experimental evidence and the results of supporting molecular orbital calculations.