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The Thermally Stimulated Discharge Current (TSDC) method is a very sensitive technique to analyze the movement of dipoles and of space charge (SC). To increase the selectivity of the method we have proposed a variant of the TSDC method, namely the final thermally stimulated discharge current (FTSDC) technique. The experimental conditions can be selected so that the FTSDC is mainly determined by SC de-trapping. The aim of this paper is to analyze if the elementary peaks obtained by using the two methods can be assumed as elementary Debye peaks and to determine the best experimental conditions to obtain a narrow experimental peak which means to increase the selectivity of the method.

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The recent developments in virtualization change completely the panorama of the Hardware/OS deployment. New bottlenecks arise in the deployment of application stacks, where IT industry will spend most of the time to assure automation. VIRTU tool aims at managing, configuring and testing distributed ground applications of space systems on a virtualized environment, based on open tools and cross virtualization support. This tool is a spin-off of previous activities performed by the European Space Operations Center (ESOC) and thus it covers the original needs from the ground data systems infrastructure division of the European Space Agency. VIRTU is a testing oriented solution. Its ability to group several virtual machines in an assembly provides the means to easily deploy a full testing infrastructure, including the client/server relationships. The possibility of making on-demand request of the testing infrastructure will provide some infrastructure optimizations, specially having in mind that ESA maintains Ground Control software of various missions, and each mission cam potentially have a different set of System baselines and last up to 15 years. The matrix array of supported system combinations is therefore enormous and any improvement on the process provides substantial benefits to ESA, by reducing the effort and schedule of each maintenance activity. The ESOC’s case study focuses on the development and validation activities of infrastructure or mission Ground Systems solutions. The Ground Systems solutions are typically composed of distributed systems that could take advantage of virtualized environments for testing purposes. Virtualization is used as way to optimize maintenance for tasks such as testing new releases and patches, test different system’s configurations and replicate tests. The main benefits identified are related to deployment test environment and the possibility to have on-demand infrastructure.

There are new business paradigms as lean and green to develop improvements on the supply chain performance. The performance evaluation has become an important subject getting competitive advantages in organizations and their supply chains. To get a balanced performance measurement system a balanced scorecard (BSC) may be develop. This study is motivated by the lack of evidence on the supply chain performance measurement; it pretends to explore the effect of lean and green supply chain through a BSC framework. To achieve this purpose a four perspectives BSC was developed based on cause-and-effect relationships. To identify how to develop the BSC for incorporating lean and green supply chain performance, a brief literature review is presented. This paper proposes a conceptual model to explore how lean and green supply chain performance may be studied, using a BSC perspective.

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The effect of kefir grains on the proteolysis of major milk proteins in milk kefir and in a culture of kefir grains in pasteurized cheese whey was followed by reverse phase-HPLC analysis. The reduction of kappa-, alpha-, and beta-caseins (CN), alpha-lactalbumin (alpha-LA), and beta-lactoglobulin (beta-LG) contents during 48 and 90 h of incubation of pasteurized milk (100 mL) and respective cheese whey with kefir grains (6 and 12 g) at 20 degrees C was monitored. Significant proteolysis of alpha-LA and kappa-, alpha-, and beta-caseins was observed. The effect of kefir amount (6 and 12 g/100 mL) was significant for alpha-LA and alpha- and beta-CN. alpha-Lactalbumin and beta-CN were more easily hydrolyzed than alpha-CN. No significant reduction was observed with respect to beta-LG concentration for 6 and 12 g of kefir in 100 mL of milk over 48 h, indicating that no significant proteolysis was carried out. Similar results were observed when the experiment was conducted over 90 h. Regarding the cheese whey kefir samples, similar behavior was observed for the proteolysis of alpha-LA and beta-LG: alpha-LA was hydrolyzed between 60 and 90% after 12 h (for 6 and 12 g of kefir) and no significant beta-LG proteolysis occurred. The proteolytic activity of lactic acid bacteria and yeasts in kefir community was evaluated. Kefir milk prepared under normal conditions contained peptides from proteolysis of alpha-LA and kappa-, alpha-, and beta-caseins. Hydrolysis is dependent on the kefir: milk ratio and incubation time. beta-Lactoglobulin is not hydrolyzed even when higher hydrolysis time is used. Kefir grains are not appropriate as adjunct cultures to increase beta-LG digestibility in whey-based or whey-containing foods.

SmART (Smart Application Reconfiguration Tool) is a framework for the automatic configuration of systems and applications. The tool implements an application configuration workflow that resorts to the similarities between configuration files (i.e., patterns such as parameters, comments and blocks) to allow a syntax independent manipulation and transformation of system and application configuration files.Without compromising its generality, SmART targets virtualized IT infrastructures, configuring virtual appliances and its applications. SmART reduces the time required to (re)configure a set of applications by automating time-consuming steps of the process, independently of the nature of the application to be configured. Industrial experimentation and utilization of SmART show that the framework is able to correctly transform a large amount of configuration files into a generic syntax and back to their original syntax. They also show that the elapsed time in that process is adequate to what would be expected of an interactive tool. SmART is currently being integrated into the VIRTU bundle, whose trial version is available for download from the project’s web page.

This study deals with SiO2-P2O5 powders obtained by sol-gel process, starting from tetraethoxysilane (TEOS) as precursor for SiO2 and either triethylphosphate (TEP) or phosphoric acid (H3PO4) as precursors for P2O5. In the case of samples prepared with H3PO4, TG-DTA data showed an accentuated weight loss associated to an endothermic effect up to about 140 °C, specific for the evaporation of water and ethylic alcohol from structural pores, and also due to alkyl-amines evaporation. Sol-gel samples prepared with TEP exhibited different thermal effects, depending on the type of atmosphere used in the experiments, i.e. argon or air. XRD analysis revealed that annealed sol-gel samples prepared with H3PO4 showed specific peaks for silicophosphate compounds such as Si3(PO4)4, Si2P2O9, and SiP2O7. XRD results for annealed sol-gel samples prepared with TEP indicated mainly the presence of a vitreous (amorphous) phase, which could be correlated with SEM images. The presence of SiO2 in the sample might be expected. Thus, we have searched for any SiO2 polymorph possible to crystallize. Only potential peaks of cristobalite were identified but some of them are overlapping with peaks of other crystalline phosphates. SEM analysis indicated a decrease of the amount of crystalline phases with the increase in the annealing temperature. © 2009 Elsevier B.V. All rights reserved.

Cobalt oxide doped silica films were synthesized by a dip-coating technique. Initial compounds were cobalt acetate Co(CH3COO)2-4H 2O and tetraethoxysilane Si(OC2H5)4. The chemical composition was studied by X-ray diffraction and UV-Vis spectroscopy. The morphology analyses were carried out by means of atomic force microscopy. The average diameter of cobalt oxide dispersed particles increases with the molar ratio Co:Si and with the aging time of the initial colloidal solution. © 2009 American Institute of Physics.

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Benzyl azide and the three methylbenzyl azides were synthesized and characterized by mass spectrometry (MS) and ultraviolet photoelectron spectroscopy (UVPES). The electron ionization fragmentation mechanisms for benzyl azide and their methyl derivatives were studied by accurate mass measurements and linked scans at constant B/E. For benzyl azide, in order to clarify the fragmentation mechanism, labelling experiments were performed. From the mass analysis of methylbenzyl azides isomers it was possible to differentiate the isomers ortho, meta and para. The abundance and nature of the ions resulting from the molecular ion fragmentation, for the three distinct isomers of substituted benzyl azides, were rationalized in terms of the electronic properties of the substituent. Concerning the para-isomer, IRC calculations were performed at UHF/6-31G(d) level. The photoionization study of benzyl azide, with He(I) radiation, revealed five bands in the 8-21 eV ionization energies region. From every photoelectron spectrum of methylbenzyl azides isomers it has been identified seven bands, on the same range as the benzyl azide. Interpretation of the photoelectron spectra was accomplished applying Koopmans' theorem to the SCF orbital energies obtained at HF/6-311++G(d, p) level.

Benzyl azide and the three methylbenzyl azides were synthesized and characterized by mass spectrometry (MS) and ultraviolet photoelectron spectroscopy (UVPES). The electron ionization fragmentation mechanisms for benzyl azide and their methyl derivatives were studied by accurate mass measurements and linked scans at constant B/E. For benzyl azide, in order to clarify the fragmentation mechanism, labelling experiments were performed. From the mass analysis of methylbenzyl azides isomers it was possible to differentiate the isomers ortho, meta and para. The abundance and nature of the ions resulting from the molecular ion fragmentation, for the three distinct isomers of substituted benzyl azides, were rationalized in terms of the electronic properties of the substituent. Concerning the para-isomer, IRC calculations were performed at UHF/6-31G(d) level. The photoionization study of benzyl azide, with He(I) radiation, revealed five bands in the 8-21 eV ionization energies region. From every photoelectron spectrum of methylbenzyl azides isomers it has been identified seven bands, on the same range as the benzyl azide. Interpretation of the photoelectron spectra was accomplished applying Koopmans' theorem to the SCF orbital energies obtained at HF/6-311++G(d, p) level.

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The electrical methods used to study the molecular movements are based on the movement of the dipoles under DC or AC electric field. We have proposed recently a combined measuring protocol to analyze charge injection/extraction, transport, trapping and de-trapping in polar or non-polar dielectric materials. The method is used here to analyze the molecular movements in polyimide in the temperature range from 293 to 572 K. A strong relaxation was observed around 402 K and a very weak relaxation around 345 K. This is the beta relaxation which is quite complex. As concern the behavior at high temperatures, above the beta relaxation, a high peak was observed that shifts continuously to higher temperatures as the charging temperature and/or the charging field increase. The maximum current of the peak increases and the temperature corresponding to the maximum current increases as the charging temperature and/or the charging field increase, given a direct observation of the so called cross-over effect related to current decay for sample charged at high fields and/or high temperatures.

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