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2004
Fernandes, M.a, Vieira Martins M. a R. b. "Dynamic characterization of large area image sensing structures based on a-SiC:H." Materials Science Forum. 455-456 (2004): 86-90. AbstractWebsite

The working principle of silicon p-i-n structures with low conductivity (σd) doped layers as single element image sensors is based on the modulation, by the local illumination conditions of the photocurrent generated by a light beam scanning the active area of the device. A higher sensitivity is achieved using a wide band gap a-Si:C alloy in the doped layers, improving the light penetration into the intrinsic semiconductor and reducing the lateral currents in the structure, which are responsible by an image smearing effect observed in sensors with high σd doped layers. This work focuses on the transient response of such sensor and on the role of the carbon (C) content of the doped layers. A set of devices with different percentage of C incorporation in the doped layers is analyzed by measuring the scanner-induced photocurrent under different bias conditions, (ranging from -1.5V to 1V) in order to evaluate the response time.

Aguas, H., L. Pereira, I. Ferreira, A. R. Ramos, A. S. Viana, J. Andreu, P. Vilarinho, E. Fortunato, and R. Martins. "Effect of an interfacial oxide layer in the annealing behaviour of Au/a-Si: H MIS photodiodes." Journal of non-crystalline solids. 338 (2004): 810-813. Abstract
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Aguas, H., L. Pereira, I. Ferreira, A. R. Ramos, A. S. Viana, J. Andreu, P. Vilarinho, E. Fortunato, and R. Martins. "Effect of an interfacial oxide layer in the annealing behaviour of Au/a-Si: H MIS photodiodes." Journal of non-crystalline solids. 338 (2004): 810-813. Abstract
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Pereira, LuÍs, Isabel Ferreira, Rodrigo Martins, Paula M. Vilarinho, Hugo Águas, Elvira Fortunato, A. R. Ramos, A. S. Viana, and J. Andreu. "Effect of annealing on gold rectifying contacts in amorphous silicon." Materials Science Forum. 455 (2004): 96-99. Abstract
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Águas, Hugo, Lu{\'ıs Pereira, Isabel Ferreira, A. R. Ramos, A. S. Viana, J. Andreu, Paula M. Vilarinho, Elvira Fortunato, and Rodrigo Martins. "Effect of annealing on gold rectifying contacts in amorphous silicon." Materials Science Forum. Vol. 455. Trans Tech Publications, 2004. 96-99. Abstract
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Águas, H., L. Raniero, L. Pereira, E. Fortunato, and R. Martins. "Effect of the discharge frequency and impedance on the structural properties of polymorphous silicon." Thin solid films. 451 (2004): 264-268. Abstract
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Águas, H., L. Perreira, R. J. C. Silva, E. Fortunato, and R. Martins. "Effect of the tunnelling oxide growth by H 2 O 2 oxidation on the performance of a-Si: H MIS photodiodes." Materials Science and Engineering: B. 109 (2004): 256-259. Abstract
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Aguas, H., A. Goullet, L. Pereira, E. Fortunato, and R. Martins. "Effect of the tunnelling oxide thickness and density on the performance of MIS photodiodes." Thin solid films. 451 (2004): 361-365. Abstract
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Muşat, V. a, B. b Teixeira, E. b Fortunato, R. C. C. b Monteiro, and P. c Vilarinho. "Effect of thermal treatment on the properties of sol-gel derived Al-doped ZnO thin films." Materials Science Forum. 455-456 (2004): 16-19. AbstractWebsite

This paper presents preliminary results on Al doped ZnO thin films prepared by the solgel method. The thin films were produced by a dip-coater technique on glass substrate, using zinc acetate dihydrate, aluminium chloride hexahydrate, 2-methoxyethanol and monoethanolamine as raw materials. The ZnO thin films were analysed by XRD, Hall effect and SEM measurements. In order to determine the influence of the thermal treatments on the film properties, a set of four different heat treatments (atmosphere and temperature) were studied. All the films are polycrystalline presenting a crystallographic c-axis orientation (002) perpendicular to the substrate. The best results were obtained for films pre-heated at 400°C and post-heated for 1 hour in air at 600°C, after annealing under a reduced atmosphere of forming gas, where a resistivity of 3.9×10-3 Ωcm, a Hall mobility of 34.1 cm2/Vs, a carrier concentration of 4.7×1019 cm-3 and an optical transmittance of 90% were achieved.

Ferro, M. C. a, M. H. V. a Fernandas, C. F. M. L. b Figueiredo, M. S. J. G. b Alendouro, and R. C. C. b Monteiro. "Effect of TiO2 on the crystallization of fly-ash based glass-ceramics." Materials Science Forum. 455-456 (2004): 831-834. AbstractWebsite

A batch of coal fly-ash, soda and lime was melted, quenched to a glass and then devitrified, by one-step heating cycles, forming coarse fibrous microstructures with pores and cracks, resulting in low strength materials. The crystallization behaviour of the based glass was further studied by adding a nucleating agent, TiC2. The resulting structural and microstrutural changes were investigated by differential thermal analysis, scanning electron microscopy, x-ray diffraction, dilatometry and density measurements. The results indicated that the addition of TiO2 could provide a finer grained microstructure, suitable for the production of structural materials.

Neagu, E. R., R. M. Neagu, J. N. Marat-Mendes, R. Martins, E. Fortunato, I. Ferreira, and C. Dias. "Electrical charge injection/ejection and transport at moderate fields in low-density polyethylene." Advanced Materials Forum Ii. Vol. 455-456. 2004. 442-445. Abstract
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Figueirinhas, J. L., PL Almeida, and M. H. Godinho. "Electro-optical Properties of Cellulose Derivative Composites." Polysaccharides: Structural Diversity and Functional Versatility, Second Edition. CRC Press, 2004. Abstract
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Martins, R., H. Aguas, I. Ferreira, E. Fortunato, L. Raniero, and P. Roca Cabarrocas. "Electronic, Optoelectronic, Spintronic and Ferroelectric Materials-Composition, Structure and Optical Characteristics of Polymorphous Silicon Films Deposited by PECVD at 27.12 MHz." Materials Science Forum. 455 (2004): 100-103. Abstract
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Martins, R., H. Aguas, I. Ferreira, E. Fortunato, L. Raniero, and P. Roca Cabarrocas. "Electronic, Optoelectronic, Spintronic and Ferroelectric Materials-Composition, Structure and Optical Characteristics of Polymorphous Silicon Films Deposited by PECVD at 27.12 MHz." Materials Science Forum. Vol. 455. Aedermannsdorf, Switzerland: Trans Tech Publications, 1984-, 2004. 100-103. Abstract
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Aguas, H., L. Pereira, L. Raniero, E. Fortunato, and R. Martins. "Electronic, Optoelectronic, Spintronic and Ferroelectric Materials-MIS Photodiodes of Polymorphous Silicon Deposited at Higher Growth Rates by 27.12 MHz PECVD Discharge." Materials Science Forum. Vol. 455. Aedermannsdorf, Switzerland: Trans Tech Publications, 1984-, 2004. 73-76. Abstract
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Pereira, L., H. Aguas, L. Raniero, R. M. S. Martins, E. Fortunato, and R. Martins. "Electronic, Optoelectronic, Spintronic and Ferroelectric Materials-Role of Substrate on the Growth Process of Polycrystalline Silicon Thin Films by Low-Pressure Chemical Vapour Deposition." Materials Science Forum. Vol. 455. Aedermannsdorf, Switzerland: Trans Tech Publications, 1984-, 2004. 112-115. Abstract
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Pereira, L., H. Aguas, R. Igreja, R. M. S. Martins, N. Nedev, L. Raniero, E. Fortunato, and R. Martins. "Electronic, Optoelectronic, Spintronic and Ferroelectric Materials-Sputtering Preparation of Silicon Nitride Thin Films for Gate Dielectric Applications." Materials Science Forum. Vol. 455. Aedermannsdorf, Switzerland: Trans Tech Publications, 1984-, 2004. 69-72. Abstract
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Fortunato, E., V. Assuncao, A. Marques, A. Goncalves, H. Aguas, L. Pereira, I. Ferreira, FMB Fernandes, R. J. C. Silva, and R. Martins. "Electronic, Optoelectronic, Spintronic and Ferroelectric Materials-ZnO: Ga Thin Films Produced by RF Sputtering at Room Temperature: Effect of the Power Density." Materials Science Forum. 455 (2004): 12-15. Abstract
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Fortunato, E., V. Assuncao, A. Marques, A. Goncalves, H. Aguas, L. Pereira, I. Ferreira, FMB Fernandes, R. J. C. Silva, and R. Martins. "Electronic, Optoelectronic, Spintronic and Ferroelectric Materials-ZnO: Ga Thin Films Produced by RF Sputtering at Room Temperature: Effect of the Power Density." Materials Science Forum. Vol. 455. Aedermannsdorf, Switzerland: Trans Tech Publications, 1984-, 2004. 12-15. Abstract
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Fortunate, E., Gonçalves De Carvalho Pimentel Lavareda Marques Martins A. C. N. "Enhancement of the electrical properties of ITO deposited on polymeric substrates by using a ZnO buffer layer." Materials Research Society Symposium Proceedings. Vol. 814. 2004. 231-236. Abstract

In this paper we present the effect of the insertion of a non-doped nanocrystalline zinc oxide/buffer layer on the electrical, optical and structural properties of indium tin oxide produced at room temperature by radio frequency plasma enhanced reactive thermal evaporation on polymeric substrates. The electrical resistivity of the ITO films is reduced by more than two orders of magnitude (4.5×10-1 to 2.9×10-3 Ωcm). From the Hall effect measurements it is observed that the large decrease associated to the electrical resistivity, is due to the increase associated to the Hall mobility. Concerning the optical properties no effect was observed, being the transmittance in the visible and near the infra red region always higher than 80%.

Caldeira, Jorge, João Luis Figueirinhas, Celina Santos, and Maria Helena Godinho. "EPR spectroscopy of protein microcrystals oriented in a liquid crystalline polymer medium." Journal of Magnetic Resonance. 170.2 (2004): 213-219. Abstract
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Ferreira, Isabel, Elvira Fortunato, and Rodrigo Martins. "Ethanol vapour detector based in porous a-Si: H films produced by HW-CVD technique." Sensors and Actuators B: Chemical. 100.1 (2004): 236-239. Abstract
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Ferreira, I., Fortunato Martins E. R. "Ethanol vapour detector based in porous a-Si:H films produced by HW-CVD technique." Sensors and Actuators, B: Chemical. 100 (2004): 236-239. AbstractWebsite

In this work, we show the possibility to use undoped porous silicon (PS) thin films produced by hot wire chemical vapour deposition technique (HW-CVD) as ethanol detector. Silicon thins films produced by HW-CVD technique, under certain deposition conditions, have a porous structure [Vacuum 52 (1999) 147]. Therefore, in the presence of an alcohol, the OH group is adsorbed by the uncompensated bonds behaving as donor-like carriers leading to an increase in the current flowing through the material. This current enhancement is bias dependent in glass/ITO/i-a-Si:H/Al sensor and increases as the ethanol vapour pressure increases from 10-1mbar to atmospheric pressure. The response time of the current of the sensor and its recovery time are in the range of 10-50s at room temperature. Ethanol quantities above 50ppm can be detected. © Published by Elsevier B.V.

Oliveira, L. B., I. M. Filanovsky, and CJM Verhoveven. "Exact calculation of amplitudes and frequency of RC-oscillator with quadrature outputs." Circuits and Systems, 2004. MWSCAS'04. The 2004 47th Midwest Symposium on. Vol. 1. IEEE, 2004. I–413. Abstract
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Carvalho, AL, A. Goyal, JAM Prates, DN Bolam, HJ Gilbert, VMR Pires, LMA Ferreira, A. Planas, MJ Romao, and CMGA Fontes. "The family 11 carbohydrate-binding module of Clostridium thermocellum Lic26A-Cel5E accommodates beta-1,4- and beta-1,3-1,4-mixed linked glucans at a single binding site." Journal of Biological Chemistry. 279 (2004): 34785-34793. Abstract
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