The strengthening of reinforced concrete structures with laminates of fibre reinforced polymeric (FRP) matrix has received considerable attention, although there still is lack of information on the more adequate modelling of the interface between FRP composites and concrete. An experimental programme is described and was designed to: (i) characterise glass FRP-to-concrete interface by shear tests; (ii) analyse reinforced concrete T-beams with external GFRP plates. Double shear tests were carried out based on 15 cm cubes with GFRP bonded to two opposite faces. The concrete T-beams were 3.0 m long and 0.28 m high and were loaded till rupture in 4-point bending tests. The external reinforcement system showed great strength increment in relation to the non retrofitted T-beam, confirming to be an effective approach to the flexural strengthening of RC beams. The computational analysis was based on a three dimensional smeared crack model. In total, 22 computational analyses were made. Models with and without interface FE associated with Mohr–Coulomb failure criterion for the FRP-to-concrete interface were defined and different strength types of concrete were considered. The rigid interface does not predict the rupture of the T-beam with precision; however, the results obtained for low concrete strengths revealed that rigid interfaces can be assumed when conjugated with the fixed crack approach. Consequently, a slightly stiffer response of the beam is obtained. The maximum bond stresses obtained from Finite Element Analysis (FEA) revealed that the models with rigid interfaces developed lower bond stresses due to the lack of relative displacements between both materials. The effects of assuming either fixed or rotated crack approaches were also compared. The rotated crack conjugated to a fine mesh in the vicinity of the GFRP-to-concrete stress led to a very good estimation of the bond stresses along the interface. The prediction of the T-beam rupture was also estimated with better results when the rotated crack was used in the model. In general, the FEA predicted with very good results the de-bonding of the GFRP-to-concrete interface of T-beams externally bonded with GFRP composites.

The strengthening of reinforced concrete structures by means of externally bonded fibre reinforced polymers (FRPs) is now routinely considered and applied in the retrofit or strengthening of structures. FRP composites have received a considerable attention from civil engineers in recent years due to the high strength-weight and stiffness/weight ratios when compared to other materials. However, when FRP composites are bonded to a concrete surface, there is a persistent potential problem that the FRP plates may debond prematurely from the concrete. This is a very important issue for the engineers who have to focus on the computational modelling of this phenomenon. Some studies can be found in literature on computational modelling. However, there is very little information about the best modelling of the interface between FRP composites and concrete and this work is intended to help bridge this gap. The computational analysis presented here is based on three-dimensional software which assumes the smeared crack model, and the interface finite elements (FEs) used have a rupture criteria based on the Mohr-Coulomb criterion with tension cut-off. The definition of these FEs was based on double shear tests that were performed specifically for this purpose and they have shown that the debonding phenomenon can be predicted with some accuracy. In total, 10 double shear models were studied and the results were compared with the 21 experimental tests performed. The double shear tests consisted of applying loads to 2 layered GFRP laminates bonded to a 150 mm concrete cube with a bonded area of 150 × 80 mm (length × width). Double shear models with and without a gap interface were considered in order to emphasize the importance of modelling the GFRP-to-concrete interface with interface finite elements. The effect of the concrete strength on the interface performance was also considered. An externally bonded reinforcement (EBR) concrete T-beam strengthened with 2 GFRP layers is presented to illustrate the application of the method. The wet lay-up technique was used for the external reinforcement of a reinforced concrete T-beam and then tested under a four point bending test until rupture. The results are reported and differences between the numerical and the experimental results are discussed.

Forty partial fossil skulls belonging to beaked whales (Cetacea, Odontoceti, Ziphiidae) were collected by trawling and long-line fishing on Neogene (probably Late Early to Middle Miocene) layers of the Atlantic floor off the coasts of Portugal and Spain (Asturias and Galicia). e systematic study of the most diagnostic Iberian specimens, those preserving the rostrum and the dorsal part of the cranium, led to the recognition of two new genera (Globicetus n. gen. and Imocetus n. gen.) and four new species (Choneziphius leidyi n. sp., G. hiberus n. gen., n. sp., I. piscatus n. gen., n. sp., and Tusciziphius atlanticus n. sp.).
Based on the matrix of a previous work, the phylogenetic analysis places all the new taxa in the subfamily Ziphiinae Gray, 1850. More fragmentary specimens are tentatively referred to the genera Caviziphius Bianucci & Post, 2005 and Ziphirostrum du Bus, 1868. Among these new ziphiids, extremely bizarre skull morphologies are observed. In G. hiberus n. gen., n. sp. the proximal portion of the rostrum bears a voluminous premaxillary spheroid. In T. atlanticus n. sp. a medial premaxillary bulge is present on the rostrum; together with asymmetric
rostral maxillary eminences at the rostrum base, this bulge displays various degrees of elevation in different specimens, which may be interpreted as sexual dimorphism. Specimens of I. piscatus n. gen., n. sp. bear two sets of even crests: spur-like rostral maxillary crests and longitudinal maxillary crests laterally bordering a wide and long facial basin. A preliminary macroscopic observation of these elements indicates very dense bones, with a compactness comparable with that of cetacean ear bones. Questioning their function, the high medial rostral elements (the premaxillary spheroid of G. hiberus n. gen., n. sp. and the medial bulge of T. atlanticus n. sp.) remind the huge rostral maxillary crests of adult males of the extant Hyperoodon ampullatus (Forster, 1770). In the latter, the crests are very likely related to head-butting. However, they are made of much more spongy bone than in the fossil taxa studied here, and therefore possibly better mechanically suited for facing impacts. Other interpretations of these unusual bone specializations, related to deep-diving (ballast) and echolocation (sound reflection), fail to explain the diversity of shapes and the hypothetical sexual dimorphism observed in at least part of the taxa. e spur-like rostral maxillary crests and long maxillary crests limiting the large facial basin in I. piscatus n. gen., n. sp. and the excrescences on the maxilla at the rostrum base in Choneziphius spp. are instead interpreted as areas of origin for rostral and facial muscles, acting on the nasal passages, blowhole, and melon. From a palaeobiogeographic point of view, the newly described taxa further emphasize the differences in the North Atlantic (including Iberian Peninsula) and South African Neogene ziphiid faunal lists. Even if the stratigraphic context is poorly understood, leaving open the question of the geological age for most of the dredged specimens, these differences in the composition of cold to temperate northern and southern hemisphere fossil ziphiid faunas may be explained by a warm-water equatorial barrier.

The main aim of this work was to study the chemical and ecotoxicological properties of ashes produced in a biomass boiler of a pulp and paper industry and evaluate possible differences depending on the particle size of bottom and fly ashes. This industry produces electricity by burning eucalyptus and pine bark in a bubbling fluidized bed combustor. Bottom and fly ashes and their size fractions, obtained by sieving, were analysed for a set of metals and leaching behaviour. The eluates were also submitted to ecotoxicological characterization, using five indicators. The highest concentrations of metals and metalloids were found in the lower particle size fractions of bottom and fly ashes. However, generally, it could not be observed any specific releasing pattern of metals depending on the particle size, except for fly ashes in which the releasing rate of some earth and alkali-earth metals seemed to increase for lower particle size fractions. No specific pattern of the ecotoxicity levels could be associated to the different particle size fractions of ashes. The fractions of bottom ashes with 4,000–10,000 μm and > 10,000 μm have presented the lowest ecotoxicity levels. All the samples were classified as ecotoxic, except the fraction of bottom ashes > 10,000 μm.

This paper deals with the coupled effect of temperature and silica fume addition on rheological, mechanical behaviour and porosity of grouts based on CEMI 42.5R, proportioned with a polycarboxylate-based high range water reducer. Preliminary tests were conducted to focus on the grout best able to fill a fibrous network since the goal of this study was to develop an optimized grout able to be injected in a mat of steel fibers for concrete strengthening. The grout composition was developed based on criteria for fresh state and hardened state properties. For a CEMI 42.5R based grout different high range water reducer dosages (0, 0.2%, 0.4%, 0.5%, 0.7%) and silica fume (SF) dosages (0, 2%, 4%) were tested (as replacement of cement by mass). Rheological measurements were used to investigate the effect of polycarboxylates (PCE) and SF dosage on grout properties, particularly its workability loss, as the mix was to be injected in a matrix of steel fibers for concrete jacketing. The workability behaviour was characterized by the rheological parameters yield stress and plastic viscosity (for different grout temperatures and resting times), as well as the procedures of mini slump cone and funnel flow time. Then, further development focused only on the best grout compositions. The cement substitution by 2% of SF exhibited the best overall behaviour and was considered as the most promising compared to the others compositions tested. Concerning the fresh state analysis, a significant workability loss was detected if grout temperature increased above 35°C. Below this temperature the grout presented a self-levelling behaviour and a life time equal to 45 minutes. In the hardened state, silica fumes increased not only the grout’s porosity but also the grout’s compressive strength at later ages, since the pozzolanic contribution to the compressive strength does not occur until 28 days and beyond.

Reinforced concrete (RC) beams externally strengthened with glass fiber-reinforced polymer (GFRP) strips bonded to the soffit may see their load-carrying capacity reduced due to environmental conditions—especially due to the deterioration of bond between the adhesively bonded laminates and concrete, causing premature failure.
More research has been published on the detachment of the laminate progressing from the anchorage zone than on failure induced by the formation of flexural or shear-flexural cracks in the midspan followed by fiber-reinforced polymer (FRP) separation and failure designated as intermediate crack (IC) debonding. An experimental program to study degradation of the GFRP laminate beam specimens after accelerated temperature cycles, namely: 1) freezing-and-thawing type; and 2) cycles of the same amplitude (40°C [104°F]) and an upper limit approximately 70% of the glass vitreous transition temperature of the resin, Tg, is described.
Effects on the bond stress and ultimate capacity are reported. Substantial differences between shear and bending-induced failure and a decrease of bond stresses and engagement of the laminates on the structural response are analyzed.

The paper analyses different analytical and numerical solutions for the debonding process of the FRP-to-concrete interface on shear tests with the FRP plate submitted to a tensile load in one of its ends. From the point of view of the state of the art, two different ways of finding the bond-slip curve from experiments are discussed and analysed. Essentially, three different linear bond-slip models, one exponential model and another power based function are employed in the numerical process. The results are analysed and compared. The differences found in the stress field along the interface, maximum load, maximum slip, ultimate slip, fracture energy and effective bond length are reported. The load-slip behaviour is also presented for the linear and non-linear models herein studied and the influence of the local bond-slip model on the debonding process is discussed. The numerical integration process used on the present study proved to be coherent with the analytical expressions determined for the linear bond-slip models and allowed to verify that maximum load transmittable to the FRP plate is influenced by the square root of the FRP stiffness and fracture energy even when nonlinear bond-slip models are assumed.

The paper analyses numerical solutions for the process leading to debonding failure of fiber reinforced polymers (FRP)-to-concrete interfaces in shear tests with the FRP plate subjected to a tensile load at one end. Any realistic local nonlinear bond-slip law can be used in the numerical analysis proposed in the present study. However, only a Popovics’ type expression is employed in the numerical process due to its use in different studies found in the literature. Effective bond length (Leff) is discussed and an expression depending on the Popovics’ constant (nP) is proposed to calculate it. Assuming a fracture in pure Mode II, the debonding process is analyzed in detail and distributions of bond stresses and strains in the FRP plate along the interface are presented. The load-displacement behaviour is also presented and the influence of the local bond-slip law on the debonding process is discussed.

Titanosauriforms represent a diverse and globally distributed clade of neosauropod dinosaurs, but their inter-relationships remain poorly understood. Here we redescribe Lusotitan atalaiensis from the Late Jurassic Lourinhã Formation of Portugal, a taxon previously referred to Brachiosaurus. The lectotype includes cervical, dorsal, and caudal vertebrae, and elements from the forelimb, hindlimb, and pelvic girdle. Lusotitan is a valid taxon and can be diagnosed by six autapomorphies, including the presence of elongate postzygapophyses that project well beyond the posterior margin of the neural arch in anterior-to-middle caudal vertebrae. A new phylogenetic analysis, focused on elucidating the evolutionary relationships of basal titanosauriforms, is presented, comprising 63 taxa scored for 279 characters. Many of these characters are heavily revised or novel to our study, and a number of ingroup taxa have never previously been incorporated into a phylogenetic analysis. We treated quantitative characters as discrete and continuous data in two parallel analyses, and explored the effect of implied weighting. Although we recovered monophyletic brachiosaurid and somphospondylan sister clades within Titanosauriformes, their compositions were affected by alternative treatments of quantitative data and, especially, by the weighting of such data. This suggests that the treatment of quantitative data is important and the wrong decisions might lead to incorrect tree topologies. In particular, the diversity of Titanosauria was greatly increased by the use of implied weights. Our results support the generic separation of the contemporaneous taxa Brachiosaurus, Giraffatitan, and Lusotitan, with the latter recovered as either a brachiosaurid or the sister taxon to Titanosauriformes. Although Janenschia was recovered as a basal macronarian, outside Titanosauria, the sympatric Australodocus provides body fossil evidence for the pre-Cretaceous origin of titanosaurs. We recovered evidence for a sauropod with close affinities to the Chinese taxon Mamenchisaurus in the Late Jurassic Tendaguru beds of Africa, and present new information demonstrating the wider distribution of caudal pneumaticity within Titanosauria. The earliest known titanosauriform body fossils are from the late Oxfordian (Late Jurassic), although trackway evidence indicates a Middle Jurassic origin. Diversity increased throughout the Late Jurassic, and titanosauriforms did not undergo a severe extinction across the Jurassic/Cretaceous boundary, in contrast to diplodocids and non-neosauropods. Titanosauriform diversity increased in the Barremian and Aptian–Albian as a result of radiations of derived somphospondylans and lithostrotians, respectively, but there was a severe drop (up to 40%) in species numbers at, or near, the Albian/Cenomanian boundary, representing a faunal turnover whereby basal titanosauriforms were replaced by derived titanosaurs, although this transition occurred in a spatiotemporally staggered fashion.

This research has been motivated by a real-life problem of a waste cooking oil collection system characterized by the existence of multiple depots with an outsourced vehicle fleet, where the collection routes have to be plan. The routing problem addressed allows open routes between depots, i.e., all routes start at one depot but can end at the same or at a different one, depending on what minimizes the objective function considered. Such problem is referred as a Multi-Depot Vehicle Routing Problem with Mixed Closed and Open Inter-Depot Routes and is, in this paper, modeled through a Mixed Integer Linear Programming (MILP) formulation where capacity and duration constraints are taken into account. The model developed is applied to the real case study providing, as final results, the vehicle routes planning where a decrease of 13% on mileage and 11% on fleet hiring cost are achieved, when comparing with the current company solution.

This paper presents a tool, named QUERYSHEET, to query spreadsheets. We defined a language to write the queries, which resembles SQL, the language to query databases. This allows to write queries which are more related to the spreadsheet content than with current approaches.

The use of agar-based biomaterials for the development of emerging areas, such as tissue engineering or ‘smart materials’ production has recently gained great interest. Understanding how these gel-forming polysaccharides self-organise in aqueous media and how these associations can be tuned to meet the specific needs of each application is thus of great relevance. As an extension of previous pioneering research concerning the application of the microwave-assisted extraction (MAE) technique in the recovery of native (NA) and alkali-modified (AA) agars, this article focuses on the different molecular assemblies assumed by these novel NA and AA when using different MAE routes. The molecular architectures in dilute (5, 10, 50 and 100 mg mL
1) and concentrated (1.5% (w/w)) aqueous media were imaged by AFM and cryoSEM, respectively. Relevant structural and physicochemical properties were investigated to support the microscopic data. Different extraction routes led to polysaccharides with unique properties, which in turn resulted in different molecular assemblies. Even at 5 mg mL
1, AFM images included individual fibers, cyclic segments, aggregates and local networks. At higher polymer concentrations, the structures further aggregated forming multilayer polymeric networks for AA. The more compact and denser 3D networks of AA, imaged by cryoSEM, and their higher resistance to large deformations matched the 2D-shapes observed by AFM. Depending on the nature of the AA chains, homogeneous or heterogeneous growth of assemblies was seen during network formation. The obtained results support well the view of double helix formation followed by intensive double helix association proposed for agar gelation.

In this work we propose a stochastic model for the design and planning of closed-loop supply chains.
Uncertainties in demand and return volumes are modelled together with uncertain transportation
costs. A two-stage stochastic programming is developed and a sensitivity analysis to the worst-case
probability is performed in order to test the solution robustness. Finally, in order to prove the
goodness of the stochastic approach, the value of the stochastic solution and the value of perfect
information are computed. An example based on a real case shows the model applicability.