Larrinaga, Pello, Carlos Chastre, Hugo C. Biscaia, and José T. San-José. "
Experimental and Numerical Modelling of Basalt Textile Reinforced Mortar Behavior Under Uniaxial Tensile Stress."
Materials & Design. 55.March (2014): 66-74.
AbstractDuring the last years several projects and studies have improved the knowledge about Textile Reinforced Mortar (TRM) technology. TRM has already been used in strengthening masonry and reinforced concrete structural elements such as walls, arches, columns and beams. This material is presented as a real alternative to the use of fibre-reinforced polymers (FRP) in situations where these composites have presented some drawbacks or their use is banned. Textile Reinforced Mortar show a complex mechanical behaviour derived from the heterogeneity of the constituent materials. This paper aims to deepen the knowledge of this composite material in terms of tensile behaviour. Following this scope, this paper presents an experimental campaign focused on thirty one TRM specimens reinforced with four different reinforcing ratios. The results are analysed and contrasted with two distinct models. i) the Aveston-Cooper-Kelly theory (ACK) which is based on a tri-linear analytical approach; and ii) a nonlinear numerical simulation with a 3D Finite Element code. The Finite Element Analysis (FEA) of the TRM tensile tests also showed no significant dependence on the basalt-to-mortar interface, i.e., the choice of a bond-slip curve in order to reproduce the bond stresses and slippages along the interface is irrelevant and it can be simply considered as rigid interface.
Carvalho, T., V. Augusto, A. Rocha, N. M. T. Lourenco, N. T. Correia, S. Barreiros, P. Vidinha, E. J. Cabrita, and M. Dionisio. "
Ion Jelly Conductive Properties Using Dicyanamide-Based Ionic Liquids."
Journal of Physical Chemistry B. 118.31 (2014): 9445-59.
AbstractThe thermal behavior and transport properties of several ion jellys (IJs), a composite that results from the combination of gelatin with an ionic liquid (IL), were investigated by dielectric relaxation spectroscopy (DRS), differential scanning calorimetry (DSC), and pulsed field gradient nuclear magnetic resonance spectroscopy (PFG NMR). Four different ILs containing the dicyanamide anion were used: 1-butyl-3-methylimidazolium dicyanamide (BMIMDCA), 1-ethyl-3-methylimidazolium dicyanamide (EMIMDCA), 1-butyl-1-methylpyrrolidinium dicyanamide (BMPyrDCA), and 1-butylpyridinium dicyanamide (BPyDCA); the bulk ILs were also investigated for comparison. A glass transition was detected by DSC for all materials, ILs and IJs, allowing them to be classified as glass formers. Additionally, an increase in the glass transition temperature upon dehydration was observed with a greater extent for IJs, attributed to a greater hindrance imposed by the gelatin matrix after water removal, rendering the IL less mobile. While crystallization is observed for some ILs with negligible water content, it was never detected for any IJ upon thermal cycling, which persist always as fully amorphous materials. From DRS measurements, conductivity and diffusion coefficients for both cations (D+) and anions (D–) were extracted. D+ values obtained by DRS reveal excellent agreement with those obtained from PFG NMR direct measurements, obeying the same VFTH equation over a large temperature range (ΔT ≈ 150 K) within which D+ varies around 10 decades. At temperatures close to room temperature, the IJs exhibit D values comparable to the most hydrated (9%) ILs. The IJ derived from EMIMDCA possesses the highest conductivity and diffusion coefficient, respectively, 10–2 S·cm–1 and 10–10 m2·s–1. For BMPyrDCA the relaxational behavior was analyzed through the complex permittivity and modulus formalism allowing the assignment of the detected secondary relaxation to a Johari–Goldstein process. Besides the relevant information on the more fundamental nature providing physicochemical details on ILs behavior, new doorways are opened for practical applications by using IJ as a strategy to produce novel and stable electrolytes for different electrochemical devices.
Maiti, Biplab K., Luisa B. Maia, Kuntal Pal, Bholanath Pakhira, Teresa Aviles, Isabel Moura, Sofia R. Pauleta, Jose L. Nunez, Alberto C. Rizzi, Carlos D. Brondino, Sabyasachi Sarkar, and Jose J. G. Moura. "
One electron reduced square planar bis(benzene-1,2-dithiolato) copper dianionic complex and redox switch by O2/HO-."
Inorganic Chemistry. 53 (2014): 12799-12808.
Abstract
Abreu, Rui, Tiago Alves, Orlando Belo, José C. Campos, Jácome Cunha, João Paulo Fernandes, Pedro Martins, Jorge Mendes, Hugo Pacheco, Christophe Peixoto, Rui Pereira, Alexandre Perez, Hugo Ribeiro, André Riboira, João Saraiva, André Silva, João Carlos Silva, and Joost Visser SSaaPP: SpreadSheets as a Programming Paradigm – Project's Final Report. HASLab - High-Assurance Software Laboratory & Universidade do Minho, 2014.
AbstractThis technical report describes the research goals and results of the SpreadSheet as a Programming Paradigm research project. This was a project funded by Funda{\c c}ão para a Ciencia e Tecnologia – FCT: the Portuguese research foundation, under reference FCOMP-01-0124-FEDER-010048, that ran from May 2010 till July 2013. This report includes the complete document reporting the results achieved during the project execution, which was submitted to FCT for evaluation on October 2013. It describes the goals of the project, and the different research tasks presenting the deliver- ables of each of them. It also presents the management and result dissemination work performed during the project's execution. The document includes also a self assess- ment of the achieved results, and a complete list of scientific publications describing the contributions of the project. Finally, this document includes the FCT evaluation report.
Huisman, G., Bruijnes, M., Kolkmeier, J., Jung, M., Frederiks, A.D., and Rybarczyk Y. "
Touching virtual agents: embodiment and mind."
Innovative and Creative Developments in Multimodal Interaction Systems . Eds. Y. Rybarczyk, T. Cardoso, J. Rosas, and L. Camarinha-Matos. Heidelberg: Springer, 2014. 114-138.
Gomes, Isabel, Jorge Santos, Luís Cavique, Nelson C. Martins, Manuel Vieira, Paula Amaral, Raquel Barreira, and Vitor H. Fernandes AMT (airline maintenance technicians) timetabling optimization- ESGI101 - Relatório Final- TAP-AMT. ESGI 101, FCT, UNL, 2014, 2014.
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