n/a

The Late Triassic (ca. 237-201.5 million years ago) was a transitional interval in the evolution of terrestrial ecosystems, during which ‘modern’ clades such as archosaurs and mammals were radiating while ‘archaic’ groups such as temnospondyl amphibians and basal synapsids remained abundant. Little is known about the Triassic terrestrial (nonmarine) vertebrates of the Iberian Peninsula. The Algarve Basin of southern Portugal is an extensional rift basin formed during the breakup of Pangaea, which is filled with terrestrial, lacustrine, and marginal marine siliciclastics of the Grés de Silves Formation, interbedded with CAMP basalts that mark the end-Triassic extinction (radioisotopically dated to ~198-201.5 Ma). Since 2009, our field project in the Algarve has discovered numerous vertebrate specimens within the Grés de Silves, including a monodominant bonebed containing hundreds of specimens of metoposaurids, a peculiar group of temnospondyls that filled crocodile-like predatory niches in lacustrine and fluvial environments. These specimens appear to belong to a new species of Metoposaurus, similar to M. diagnosticus and M. krasiejowensis from central Europe but possessing several putative autapomorphies of the braincase and lower jaw. We also discovered a mandible of a phytosaur, the first specimen of these long-snouted, semi-aquatic archosauriforms from the Iberian Peninsula. These discoveries of characteristic Carnian Norian taxa indicate that the fossil-bearing portion of the Grés de Silves is Late Triassic in age, and provide further evidence that metoposaurids and phytosaurs commonly occurred together in low palaeolatitudes during this time.

This work presents a multi-objective optimization methodology that accounts for economic, environmental and social concerns in a supply chain with reverse flows. Environmental impact assessment is considered through the use of Recipe 2008. A social benefit indicator is developed where the creation of employment in less developed regions is preferred. The multi-objective approach is used to reach a solution of compromise between the three sustainability pillars. The model is applied to a case study developed in collaboration with a Portuguese company, leader in battery production.

Natural polymers have been studied during the last years for the transport and separation of liquid and gas mixtures, in terms of solubility and permeability data, and their structure and mechanical properties have been characterised. However, no transport models have been reported, relating transport with the material morphology. Cork is a natural cellular material containing three structural polymers (suberin, lignin and polysaccharides). Cork is considered a natural polymer, with economic relevance due to its sealing, non-toxic, stable and low-density properties. Corkwas characterised in this work in terms of its solubility and permeability data in relation to various gases with different molecular mass: He, O2,N2,CO2 and 1,1,1,2-tetrafluoroethane (R134a). A morphological analysis of the structure of the cork sample chosen in this work was also performed using SEM (scanning electron microscopy) and TEM (transmission electron microscope) image analysis, which took into account the variation of each relevant structural parameter. A transport model was developed supported on the morphology of cork characterised in this work. The transport model developed considers that gas permeation occurs through the plasmodesmata, which are channels with approximately 100 nm of diameter that cross the cell walls of the cork cells. It was found that gas transport follows a Knudsen mechanism, as proved by the gas permeability behaviour with increasing gasmolecularmass, with a negligible contribution of viscous transport to the total flux. &

{New cationic Ag(I) complexes were prepared by reaction of AgBF4 with two thioether-functionalized bis-(diphenylphosphino) amine ligands, Ph2PN(p-ArSMe)PPh2 (L1) and Ph2PN(n-PrSMe)PPh2 (L2), and compared with those obtained from the unfunctionalized ligands Ph2PN(Ph)PPh2 (L3) and Ph2PN(n-Bu)PPh2 (L4), respectively. The complex {[}Ag-3(mu(3)-Cl)(2)(mu(2)-L1-P, P)(3)](BF4) (1 center dot BF4) contains a triangular array of Ag centres supported by three bridging L1 ligands and two triply-bridging chlorides. In contrast, ligand L2 led to the coordination polymer {[}\{Ag-2(mu(3)-L2,-P,P,S)(2)(MeCN)(2)\}\{Ag-2(mu(2)-L2-P,P)(2)(MeCN)(2) \}(BF4)(4)](n) (2) in which the tethered thioether group connects intermolecularly a Ag2 unit to the diphosphine bridging the other Ag2 unit. With L3 and L4, two similar complexes were obtained, {[}Ag-2(mu(2)-L3)(BF4)(2)] (3) and {[}Ag-2(mu(2)-L4)(BF4)(2)] (4), respectively, with bridging diphosphine ligands and a BF4 anion completing the coordination sphere of the metal. Complexes 1 center dot BF4 center dot CH2Cl2, 2 center dot THF, 3 center dot 3CH(2)Cl(2) and 4 have been fully characterized, including by single crystal X-ray diffraction.}

Transport properties of natural (noncompressed) cork were evaluated for water and ethanol in both vapor and liquid phases. The permeability for these permeants has been measured, as well as the sorption and diffusion coefficients. This paper focuses on the differences between the transport of gases' relevant vapors and their liquids (water and ethanol) through cork. A transport mechanism of vapors and liquids is proposed. Experimental evidence shows that both vapors and liquids permeate not only through the small channels across the cells (plasmodesmata), as in the permeation of gases, but also through the walls of cork cells by sorption and diffusion as in dense membranes. The present study also shows that cork permeability for gases was irreversibly and drastically decreased after cork samples were exposed to ethanol or water in liquid phase.

We have projected and fabricated a microfluidic platform for DNA sensing that makes use of an optical colorimetric detection method based on gold nanoparticles. The platform was fabricated using replica moulding technology in PDMS patterned by high-aspect-ratio SU-8 moulds. Biochips of various geometries were tested and evaluated in order to find out the most efficient architecture, and the rational for design, microfabrication and detection performance is presented. The best biochip configuration has been successfully applied to the DNA detection of Mycobacterium tuberculosis using only 3. l on DNA solution (i.e. 90. ng of target DNA), therefore a 20-fold reduction of reagents volume is obtained when compared with the actual state of the art. © 2013 Elsevier B.V.

Phosphogypsum (PG) is a pollutant residue resulting from the production of phosphoric acid in the phosphated fertilizers industry. About 180 millions of tons of PG are generated worldwide per year, which originates storage problems because of the environmental restrictions and the high costs of storage spaces. Taking into account the mineralizer properties of PG it has been studied a way to valorize this residue as an alternative material in the production of Portland cement clinker. The PG and the raw-materials (limestone, marl, sand and iron oxide) were chemical, mineralogical and thermally characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD) and differential thermal analysis and termogravimetric analysis (DTA/TGA). After milling, the phosphogypsum was mixed with the raw-materials in different amounts up to 10% weight. The raw mixtures were submitted to two types of firing schedules, heating up to 1500°C without any holding time or heating up to 1350°C and holding for 20 minutes. After firing, the clinkers were analyzed by optical microscopy, milled and characterized in terms of chemical and mineralogical compositions. The clinkers were used to produce cement mortar according to NP EN 196-1 standard. The resultant test specimens were mechanically tested at 2 and 28 days according to the same standard. The obtained results show a reduction of about 140°C in the clinkerization temperature, when a raw mixture with 5% phosphogypsum was used. Standard clinkers, without phosphogypsum addition, which were fired at 1500°C, originated test specimens with a compressive strength of 48.1MPa at 28 days. Test specimens produced with clinker containing 5% phosphogypsum present higher compressive strength values at 28 days, being 55.1MPa for clinkers produced at 1500°C, and 49.4 MPa for clinkers produced at 1350°C. © (2013) Trans Tech Publications, Switzerland.