Os dispositivos móveis em proximidade geográfica representam um conjunto de recursos inexplorados, tanto em termos de capacidade de processamento como de rmazenamento, o que abre caminho para novas aplicações com oportunidades e desafios únicos. Os sistemas atuais de partilha de dados (e. g., fotos, música, vídeos) para dispositivos móveis exigem que exista conectividade com a Internet para funcionarem. No entanto, em ambientes onde a conectividade com a Internet não é constante ou de boa qualidade (e. g., eventos desportivos e concertos), ou em locais remotos onde as infraestruturas de rede não existem, é difícil (ou mesmo impossível) partilhar dados entre vários dispositivos móveis. Para resolver este problema, os dispositivos móveis podem formar uma rede ad hoc para compartilhar os seus dados e recursos. Neste artigo propomos um sistema de armazenamento distribuído para partilha de dados entre dispositivos móveis de uso diário, e. g., smartphones e tablets, usando um mecanismo de melhor esforço para garantir persistência e disponibilidade de dados suportando churn (entrada e saída inesperada de dispositivos).

Spectroscopic and computational methods have been used to determine the protonation state of the edge sulfur ligand in the Cu4S2 CuZ form of the active site of nitrous oxide reductase (N2OR) in its 3CuICuII (1-hole) and 2CuI2CuII (2-hole) redox states. The EPR, absorption, and MCD spectra of 1-hole CuZ indicate that the unpaired spin in this site is evenly delocalized over CuI, CuII, and CuIV. 1-hole CuZ is shown to have a mu2-thiolate edge ligand from the observation of S-H bending modes in the resonance Raman spectrum at 450 and 492 cm-1 that have significant deuterium isotope shifts (-137 cm-1) and are not perturbed up to pH 10. 2-hole CuZ is characterized with absorption and resonance Raman spectroscopies as having two Cu-S stretching vibrations that profile differently. DFT models of the 1-hole and 2-hole CuZ sites are correlated to these spectroscopic features to determine that 2-hole CuZ has a mu2-sulfide edge ligand at neutral pH. The slow two electron (+1 proton) reduction of N2O by 1-hole CuZ is discussed and the possibility of a reaction between 2-hole CuZ and O2 is considered.

Journal of Physics B: Atomic, Molecular and Optical Physics, 48(2015) 144027. doi:10.1088/0953-4075/48/14/144027

Power Quality is a generic term focusing on several issues, going from reliability to the quality of service provided by the energy supplier. It addresses limiting aspects such as harmonic distortion, flicker, sags, swells and transients... It is important for the students to understand the differences between the large amounts of events that fit into poor power quality category. Moreover it is important for them to analyze real time non-laboratory events. To provide this experience to the students this paper presents a remote m-learning experimental system where several types of poor power quality events can be tested. The developed system is based on a power quality analysis distributed network and can be remotely accessed from a remote computer or smart phones.

Journal of Physics B: Atomic, Molecular and Optical Physics, 48(2015) 144027. doi:10.1088/0953-4075/48/14/144027

The integration of high temperature superconductors (HTS) in electrical machines potentially allows reduction in devices dimensions or performance improvement for the same active volume, when compared with their conventional ones. The use of polycrystalline HTS samples allows big bulk samples. An axial disc motor with HTS material or conventional aluminium in the rotor and conventional armature has been designed and developed. This paper describes simulations and laboratory experiments performed at liquid nitrogen temperature (77 K) in order to analyze the motor's behaviour and its electromechanical characteristics and to define an electric equivalent circuit that allows describing its operation. In order to evaluate the superconducting quality of the bulks and flux pinning phenomena, Hall probe mapping system was performed in order to define the field profiles at 77 K for different polar configurations. The analysis of the obtained results allows confirm the flux pinning phenomena, being the entire rotor magnetized and conclude that the motor with the HTS rotor behaves as a conventional hysteresis motor even though with a different nature, while the motor with aluminium rotor behaves as a conventional induction motor. In asynchronous regime, the HTS motor exhibits a constant torque, higher than the conventional aluminium one. For both cases, the developed torque is proportional to the poles pairs.

Sand pile and Bean models have already been applied to describe single grain HTS bulks. An extension to that approach was used to model multiseed bulks, needed for several practical applications as electric motors or flywheels with superconducting bearings. The use of genetic algorithms was then proposed to determine intra- and intergrain current densities, and application to two and three seeds samples using trapped flux experimental measurements was exemplified. However, this model assumed some simplifications, as equal properties in grain boundaries between neighboring grains. In this paper an extension to this methodology is proposed and evaluated by analyzing measurements performed in plans at different distances from surfaces of samples with three seeds. Discussion of its influence on a practical application is also explored.

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In this study, we report solution-processed amorphous zinc tin oxide transistors exhibiting high operational stability under positive gate bias stress, translated by a recoverable threshold voltage shift of about 20{%} of total applied stress voltage. Under vacuum condition, the threshold voltage shift saturates showing that the gate-bias stress is limited by trap exhaustion or balance between trap filling and emptying mechanism. In ambient atmosphere, the threshold voltage shift no longer saturates, stability is degraded and the recovering process is impeded. We suggest that the trapping time during the stress and detrapping time in recovering are affected by oxygen adsorption/desorption processes. The time constants extracted from stretched exponential fitting curves are ≈106 s and 105 s in vacuum and air, respectively.

Molybdenum is found in the active site of enzymes usually coordinated by one or two pyranopterin molecules. Here, we mimic an enzyme with a mononuclear molybdenum-bis pyranopterin center by incorporating molybdenum in rubredoxin. In the molybdenum-substituted rubredoxin, the metal ion is coordinated by four sulfurs from conserved cysteine residues of the apo-rubredoxin and two other exogenous ligands, oxygen and thiol, forming a Mo((VI))-(S-Cys)4(O)(X) complex, where X represents -OH or -SR. The rubredoxin molybdenum center is stabilized in a Mo(VI) oxidation state, but can be reduced to Mo(IV) via Mo(V) by dithionite, being a suitable model for the spectroscopic properties of resting and reduced forms of molybdenum-bis pyranopterin-containing enzymes. Preliminary experiments indicate that the molybdenum site built in rubredoxin can promote oxo transfer reactions, as exemplified with the oxidation of arsenite to arsenate.