This paper presents an experimental study of four flat slab specimens subjected to combined vertical and horizontal cyclic loading. Steel fibre-reinforced concrete (SFRC) was used only in the local region of the slab–column connection, while the rest of the slabs were cast using normal concrete. The specimens measured 4·15 m × 1·85 m × 0·15 m and were connected to two steel half columns by 0·25 m × 0·25 m rigid steel plates, prestressed against the slab using steel bolts, to ensure monolithic behaviour. The specimens were tested using an innovative test setup system that accounted for important factors, such as the ability of bending moment redistribution, line of inflection mobility and assured equal vertical displacements at the opposite slab borders, and symmetrical shear forces. Results show that the presence of SFRC in the slab–column connection region is effective in increasing the deformation capacity of slab–column connections, allowing the increase of horizontal drift ratios.

This chapter provides an overview of the alpha paleobiodiversity of Angola based on the available fossil record that is limited to the sedimentary rocks, ranging in age from Precambrian to the present. The geological period with the highest paleobiodiversity in the Angolan fossil record is the Cretaceous, with more than 80{%} of the total known fossil taxa, especially marine molluscs, including ammonites as a majority among them. The vertebrates represent about 15{%} of the known fauna and about one tenth of them are species firstly described based on specimens from Angola.

We combined different experimental techniques with a theoretical approach to determine a consistent set of diagram lines energies and binding energies. We propose an original approach consisting in determining the mass attenuation coefficients in an energy range covering the L-, M- and N- absorption edges, including a detailed evaluation of the associated uncertainties, to derive precisely the binding energies. We investigated the Lα, Lβ and M spectra of Gd with an independantly calibrated high-resolution anti-parallel double-crystal x-ray spectrometer. All the lines were identified and found in excellent agreement with the binding energies previously derived. Morever, we identified for the first time M5−O2, M4−O2,3 and M4−N2,3 diagram lines.

Este projeto é delineado no contexto do Observatório de Literacia Oceânica – espaço de investigação transdisciplinar e transcultural. O seu objeto de estudo são diferentes comunidades costeiras urbanas, localizadas na área entre a Costa da Caparica e a Fonte da Telha. As comunidades piscatórias, situadas nessas áreas costeiras urbanas são social, económica, cultural e intelectualmente invisíveis. Numa perspetiva de educação intercultural e de inovação educativa, em ambientes tecnologicamente enriquecidos, que possibilitem a comunicação em rede, pretende-se desenvolver a co-construção de um museu virtual sobre as Artes da Pesca locais, sustentada em conceitos e conteúdos da disciplina de História. Pretende-se compreender de que forma se realizam as interações entre saber formal e informal, utilizando instrumentos e ambientes digitais, e como se poderá melhorar o desempenho das comunidades estudantis piscatórias. Os participantes neste projeto pertencem às comunidades piscatórias da área acima descrita e são estudantes de escolas da região da Caparica. Fazendo uso da etnografia crítica, num ambiente educacional formal e tecnologicamente enriquecido, pretende-se fomentar interações entre saberes formais e informais. A construção da plataforma digital e a construção e aplicação de instrumentos, resultando num museu virtual, servir-se-ão da metodologia Design-based Research.

ZnSnO3 semiconductor nanostructures have several applications as photocatalysis, gas sensors, and energy harvesting. However, due to its multicomponent nature, the synthesis is far more complex than its binary counter parts. The complexity increases even more when aiming for low-cost and low-temperature processes as in hydrothermal methods. Knowing in detail the influence of all the parameters involved in these processes is imperative, in order to properly control the synthesis to achieve the desired final product. Thus, this paper presents a study of the influence of the physical parameters involved in the hydrothermal synthesis of ZnSnO3 nanowires, namely volume, reaction time, and process temperature. Based on this study a growth mechanism for the complex Zn:Sn:O system is proposed. Two zinc precursors, zinc chloride and zinc acetate, were studied, showing that although the growth mechanism is inherent to the material itself, the chemical reactions for different conditions need to be considered.

Physics Letters B, 795 (2019) 682–688. 10.1016/j.physletb.2019.06.069

A fast method is presented to fabricate plasmonic light trapping structures in just ten minutes ({\textgreater}5 × faster than the present state of art), with excellent light scattering properties. The structures are composed of silver nanoparticles (Ag NPs) deposited by thermal evaporation and self-assembled using a rapid thermal annealing (RTA) system. The effect of the RTA heating rate on the NPs production reveals to be crucial to the decrease of the annealing process. The Ag NPs are integrated in thin film silicon solar cells to form a plasmonic back reflector (PBR) that causes a diffused light reflectivity in the near-infrared (600–1100 nm wavelength region). In this configuration the thicknesses of the AZO spacer/passivating layers between NPs and rear mirror, and between NPs and silicon layer, play critical roles in the near-field coupling of the reflected light towards the solar cell absorber, which is investigated in this work. The best spacer thicknesses were found to be 100 and 60 nm, respectively, for Ag NPs with preferential sizes of about 200 nm. The microcrystalline silicon ($μ$c-Si:H) solar cells deposited on such improved PBR demonstrate an overall 11{%} improvement on device efficiency, corresponding to a photocurrent of 24.4 mA/cm2 and an efficiency of 6.78{%}, against 21.79 mA/cm2 and 6.12{%}, respectively, obtained on flat structures without NPs.

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{\textless}h2{\textgreater}Summary{\textless}/h2{\textgreater}{\textless}p{\textgreater}Recent trends in photovoltaics demand ever-thin solar cells to allow deployment in consumer-oriented products requiring low-cost and mechanically flexible devices. For this, nanophotonic elements in the wave-optics regime are highly promising, as they capture and trap light in the cells' absorber, enabling its thickness reduction while improving its efficiency. Here, novel wavelength-sized photonic structures were computationally optimized toward maximum broadband light absorption. Thin-film silicon cells were the test bed to determine the best performing parameters and study their optical effects. Pronounced photocurrent enhancements, up to 37{%}, 27{%}, and 48{%}, respectively, in ultra-thin (100- and 300-nm-thick) amorphous, and thin (1.5-$μ$m) crystalline silicon cells are demonstrated with honeycomb arrays of semi-spheroidal dome or void-like elements patterned on the cells' front. Also importantly, key advantages in the electrical performance are anticipated, since the photonic nano/micro-nanostructures do not increase the cell roughness, therefore not contributing to recombination, which is a crucial drawback in state-of-the-art light-trapping approaches.{\textless}/p{\textgreater}

{\textless}p{\textgreater}Opto-electronics on/with paper is fostering a novel generation of flexible and recyclable devices for sunlight harvesting and intelligent optical sensing.{\textless}/p{\textgreater}

The copper zinc tin sulfide (CZTS) compound is a promising candidate as an alternative absorber material for thin-film solar cells. In this study, we investigate the direct formation of Cu1.92ZnSnx(Sb1-x)S4 compounds [CZT(A)S], with x=1, 0.85, 0.70, and 0.50, via a mechanochemical synthesis (MCS) approach, starting from powders of the corresponding metals, zinc sulfide, and sulfur. The thermal stability of the CZT(A)S compounds was evaluated in detail by in situ synchrotron high-energy x-ray diffraction measurements up to 700 °C. The CZT(A)S compounds prepared via MCS revealed a sphalerite-type crystal structure with strong structural stability over the studied temperature range. The contribution of the MCS to the formation of such a structure at room temperature is analyzed in detail. Additionally, this study provides insights into the MCS of CZTS-based compounds: the possibility of a large-scale substitution of Sn by Sb and the production of single phase CZT(A)S with a Cu-poor/Zn-poor composition. A slight increase in the band gap from 1.45 to 1.49-1.51 eV was observed with the incorporation of Sb, indicating that these novel compounds can be further explored for thin-film solar cells.

The durability performance of stainless steel makes it an interesting alternative for the structural strengthening of reinforced concrete. Like external steel plates or fibre reinforced polymers, stainless steel can be applied using externally bonded reinforcement (EBR) or the near surface mounted (NSM) bonding techniques. In the present work, a set of single-lap shear tests were carried out using the EBR and NSM bonding techniques. The evaluation of the performance of the bonding interfaces was done with the help of the digital image correlation (DIC) technique. The tests showed that the measurements gathered with DIC should be used with caution, since there is noise in the distribution of the slips and only the slips greater than one-tenth of a millimetre were fairly well predicted. For this reason, the slips had to be smoothed out to make it easier to determine the strains in the stainless steel and the bond stress transfer between materials, which helps to determine the bond–slip relationship of the interface. Moreover, the DIC technique allowed to identify all the states developed within the interface through the load–slip responses which were also closely predicted with other monitoring devices. Considering the NSM and the EBR samples with the same bonded lengths, it can be stated that the NSM system has the best performance due to their higher strength, being observed the rupture of the stainless steel in the samples with bond lengths of 200 and 300 mm. Associated with this higher strength, the NSM specimens had an effective bond length of 168 mm which is 71.5% of that obtained for the EBR specimens (235 mm). A trapezoidal and a power functions are the proposed shapes to describe the interfacial bond–slip relationships of the NSM and EBR systems, respectively, where the maximum bond stress in the former system is 1.8 times the maximum bond stress of the latter one.