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2019
Alexandre, Miguel, Manuel Chapa, Sirazul Haque, Manuel J. Mendes, Hugo Águas, Elvira Fortunato, and Rodrigo Martins. "{Optimum Luminescent Down-Shifting Properties for High Efficiency and Stable Perovskite Solar Cells}." ACS Applied Energy Materials. 2 (2019): 2930-2938. AbstractWebsite
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Silva, Sara, Maria João Falcão Silva, Paula Couto, and Fernando Pinho. "Energetic Rehabilitation of Building Towards BIM Methodology." CIAC2019 - 1st Conference on Automation Innovation in Construction. Leiria 2019.
da Silva, Pedro Boto Semblano, Corneliu Cismasiu, and José Vieira de Lemos. "Avaliação da vulnerabilidade sísmica de um arco em alvenaria utilizando o método dos elementos discretos." SÍSMICA 2019 - 11º Congresso Nacional de Sismologia e Enhenharia Sísmica. Lisboa 2019. final_sismica2019.pdf
Rebelo, H. B., D. Lecompte, C. Cismaşiu, A. Jonet, B. Belkassem, and A. Maazoun. "3D printed PLA sacrificial honeycomb cladding blast mitigation." 18th International Symposium for the Interaction of Munitions with Structures (ISIEMS). Panama City Beach, FL, USA 2019.
Yang, Yongming, Hugo Biscaia, Manuel A. G. Silva, and Carlos Chastre. "Monotonic and quasi-static cyclic bond response of CFRP-to-steel joints after salt fog exposure." Composites Part B: Engineering. 168 (2019): 532-549. AbstractWebsite

Deterioration of adhesively bonded CFRP/steel systems in salt fog environment, i.e., deicing salts and ocean environments, has to be taken into account in the design of steel strengthened structures. In the present work, monotonic and quasi-static cyclic loading were applied to CFRP-to-steel double strap joints for two kinds of CFRP laminates after being aged for a period of 5000 h to evaluate the bond behavior. The bonded joints exposed to salt fog had a different failure mode than that observed in the control specimens (0 h of exposure). The severe reduction of the maximum bond stress resulted from damage initiation that occurred in the corrosion region of the steel substrate, associated with final partial rupture on the corroded steel substrate around the edge of the bonded area: it was also correlated with reduced load carrying capacity. Results of pseudo-cyclic tests showed that the relationship between a local damage parameter (D) and normalized local dissipated energy (Wd/Gf) and the normalized slip increment (ΔS/ΔSult) exhibited almost the same trend in the un-aged and aged bonded joints. The normalized slip increment can be seen as a direct indicator for the local and global damage for the un-aged and aged bonded joints. However, monotonic and quasi-static cyclic tests results revealed that the stress concentration due to local corrosion of steel substrate could lead to brittle rupture or accelerated cumulative damage once the aged bonded interface had become weaker. The bonded joints have exhibited also a smaller relative deformation capacity between CFRP and steel.

Pacheco, João Nuno, Jorge de Brito, Carlos Chastre, and Luís Evangelista. "Statistical analysis of Portuguese ready-mixed concrete production." Construction and Building Materials. 209 (2019): 283-294. AbstractWebsite

This paper evaluates and compares the statistics of compressive strength data from three Portuguese ready-mixed concrete plants. A hierarchical model showed that different groups of concrete strength records are not statistically equivalent, even if they were produced in the same plant and using the same concrete composition. This finding is related to autocorrelation. For the same specified strength class, compositions produced less often result in higher average compressive strength and variability. The statistics of one of the plants were quite different from those of the others, even though the concrete of this plant also complied with the specifications. It was found that the average compressive strength of a mix may be quite dependent on the plant that produced it, even if the compressive strength complies with quality control specifications. Conformity with the target slump and strength class was checked following the conformity criteria of EN 206-1 for continuous production. Nonconformity with slump is more frequent than failure to comply with the strength class. A bias factor for reliability analyses was proposed.

Pacheco, J., J. de Brito, C. Chastre, and L. Evangelista. "Uncertainty models of reinforced concrete beams in bending: code comparison and recycled aggregate incorporation." Journal of Structural Engineering. 145 (2019): 04019013. AbstractWebsite

The bias factor of the Eurocode 2 [CEN (European Committee for Standardization) (2008). Eurocode 2: Design of ConcreteStructures–Part 1-1: General Rules and Rules for Buildings] and ACI 318 [ACI (American Concrete Institute) (2014). Building CodeRequirements for Structural Concrete and Commentary] flexural resistance models of reinforced concrete beams are compared withemphasis on the effect of the incorporation of coarse recycled aggregates sourced from concrete waste. The bias factor of the yielding momentcalculations according to both codes is also investigated, and the bias in the cracking moment when Eurocode 2 material clauses are used. Thedatabase was composed of 174 beams, and the criteria that led to its development are discussed. The effect of recycled aggregate incorporationon the statistical descriptors of the bias factor is evaluated and probabilistic modeling using lognormal distributions is argued for. Preliminarypartial safety factors for the bias factor of recycled aggregate concrete beams are proposed. No significant differences in the bias of theultimate moment were found between the two comparison vectors: Eurocode 2 versus ACI 318 specifications and recycled versus naturalcoarse aggregate. The bias of the cracking moment increased when coarse recycled aggregates were incorporated, most probably due to thehigher heterogeneity of recycled aggregates.

Pacheco, J., J. de Brito, C. Chastre, and L. Evangelista. "Experimental investigation on the variability of the main mechanical properties of concrete produced with coarse recycled concrete aggregates." Construction and Building Materials. 201 (2019): 110-120. AbstractWebsite

Research on the variability of the properties of recycled aggregate concrete is lacking and is necessary for the development of reliability analyses and code calibration procedures. This paper presents an experimental programme on the within-batch variability of the compressive strength, Young’s modulus, and splitting tensile strength of several recycled and natural aggregate concrete mixes. The influence of the recycled concrete aggregates on the mechanical properties and variability of concrete is analysed and discussed and benchmarks with standard predictions for the variability of natural aggregate concrete are made. It was found that full recycled aggregate concrete incorporation did not increase the variability of any of the properties tested, but intermediate ratios of recycled aggregate incorporation did. The properties of high-strength concrete mixes were more variable than that of all other mixes, irrespective of recycled aggregate incorporation. All properties of all compositions were suitably modelled by normal distributions. The coarse recycled aggregates were sourced from concrete waste.

Yang, Yongming, Manuel A. G. Silva, Hugo Biscaia, and Carlos Chastre. "Bond durability of CFRP laminates-to-steel joints subjected to freeze-thaw." Composite Structures. 212 (2019): 243-258. AbstractWebsite

The degradation mechanisms of bonded joints between CFRP laminates and steel substrates under severe environmental conditions require more durability data and studies to increase the database and better understand their causes. Studies on bond properties of double-strap CFRP-to-steel bonded joints with two different composite materials as well as adhesive coupons subjected to freeze-thaw cycles for 10,000 h were conducted to reduce that gap. In addition, the equivalent to the number of thermal cycles and their slips induced in the CFRP laminates was replicated by an equivalent (mechanical) loading-unloading history condition imposed by a static tensile machine. The mechanical properties of the adhesive coupons and the strength capacity of the bonded joints were only slightly changed by the artificial aging. It was confirmed that the interfacial bond strength between CFRP and adhesive is critically related to the maximum shear stress and failure mode. The interfacial bond strength between adhesive and steel degraded with the aging. However, the equivalent thermal cyclic bond stress caused no detectable damage on the bond because only the interfacial elastic regime was actually mobilized, which confirmed that pure thermal cycles aging, per se, at the level imposed, have a low impact on the degradation of CFRP-to-steel bonded joints.

Biscaia, Hugo C., Carlos Chastre, and Manuel A. G. Silva. "Estimations of the debonding process of aged joints through a new analytical method." Composite Structures. 211 (2019): 577-595. AbstractWebsite

The estimation of the long-term durability of adhesively bonded interfaces between Fiber Reinforced Polymers (FRP) and concrete substrates is crucial because degradation potentiates FRP premature debonding. One of the main reasons for mistrusting the use of FRP composites is the premature debonding phenomenon, which, associated to degradation, has been preventing their widespread use. In this research work, an analytical model is proposed that introduces ageing to estimate the effects of degradation of Glass (G) FRP externally bonded to concrete. Cycles were used to experimentally accelerate ageing of beam specimens, namely, (i) salt fog cycles; (ii) wet-dry cycles with salted water; (iii) temperature cycles between −10 °C and +30 °C; and (iv) temperature cycles between +7.5 °C and +47.5 °C. Based on the experimental results obtained and a corresponding bond-slip curve, the analytical model predicts the complete debonding process between FRP composites and a substrate. Consequently, the temporal evolution of the degradation of the bonded interfaces can be calculated and compared with the initial situation prior to exposure. The effects of the environmental conditions are reported and compared.

Gião, Rita, Valter Lúcio, and Carlos Chastre. "Gravity load effects on the behaviour of reinforced concrete beam critical zones subjected to cyclic loads." Engineering Structures. 181 (2019): 503-518. AbstractWebsite

The aim of the present study was to proceed to a numerical analysis of the gravity load effects on the behaviour of reinforced concrete beam critical zones when subjected to cyclic loads. A parametric study to assess the influence of different levels of gravity load on RC beam critical zones subjected to cyclic loading was carried out. For this purpose, assuming the level of gravity load as a variable parameter, a nonlinear numerical model of a beam-column connection, previously calibrated with experimental data, was used. In order to evaluate the gravity load effects in the global response, a numerical study of a RC frame system is also presented. The numerical results are analysed in terms of global hysteretic response, accumulated energy dissipation and equivalent viscous damping ratio. In this numerical study, it was observed that the hysteretic response depends on the load path. In the presence of higher gravity load levels, the structure hysteretic behaviour exhibits higher damage levels, associated to a failure mechanism corresponding to the formation of four span plastic hinges. Thus, the proper test procedure should involve the imposition of a reverse cyclic displacement history starting each cycle from the gravity load effects.

Chaparro, Catarina IP, Liliana R. Loureiro, Manuel Almeida Valente, Paula A. Videira, Joao Paulo Borges, and Paula I. P. Soares. "Application of Hyperthermia for Cancer Treatment: Synthesis and Characterization of Magnetic Nanoparticles and their internalization on Tumor Cell Lines." IEEE, 2019. 1-4. Abstract
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Pardoux, R., A. Fiévet, C. Carreira, C. Brochier-Armanet, O. Valette, Z. Dermoun, B. Py, A. Dolla, S. R. Pauleta, and C. Aubert. "The bacterial MrpORP is a novel Mrp/NBP35 protein involved in iron-sulfur biogenesis." Scientific Reports. 9.1 (2019). AbstractWebsite
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Micaelo, Rui, José Neves, Rui Lopes, and Alexandra Jesus. "A Different Perspective on the Production and Application of Warm Mix Asphalt Under Unfavorable Temperature Conditions." Transportation and Geotechniques: Materials, Sustainability and Climate. Eds. Manik Barman, Musharraf Zaman, and Jia-Ruey Chang. Cham: Springer International Publishing, 2019. 20-32. Abstract

Warm mix asphalt (WMA) is produced by a variety of technologies at lower temperatures that enable to gain important environmental and social benefits and, in consequence, to contribute to a more sustainable transportation infrastructure. The producer usually defines the temperatures used in WMA production. However, some references suggest the increase of temperature in order to allow a longer time to transport or to compact in cases of unfavourable weather conditions, mainly under low temperatures. The objective of this paper is to analyse the feasibility of producing WMA at the same temperatures of hot mix asphalt (HMA) guaranteeing an adequate compaction, and final performance in service. The paper describes a laboratory study to investigate the properties of a WMA using different additives and varying the mixing and compaction temperatures. The effect of production temperatures on the performance of the WMA was evaluated through binder drainage (production phase), volumetric properties (compaction phase), and resistance to permanent deformation (service phase). The paper also presents a numerical study on the time available for paving WMA under unfavourable climatic conditions. Results demonstrated that it is possible to produce WMA at high temperatures without problems of binder drainage, during transport, and of performance in service if adequate compaction is achieved. In fact, the production temperatures influenced the compaction phase. However, it is possible to increase the temperature without negatively affecting the required volumetric properties. The rut depth of the permanent deformation test was mostly influenced by the air-voids of the compacted WMA and the binder. From the numerical study, it was concluded that the time available for in situ compaction increased substantially when WMA was paved at higher temperature. However, in cases of low air temperature and thin layer, the increase of temperature may not be sufficient to obtain the desired level of density or air-voids.

Cordas, C. M., M. Campaniço, R. Baptista, L. B. Maia, I. Moura, and JJG Moura. "Direct electrochemical reduction of carbon dioxide by a molybdenum-containing formate dehydrogenase." Journal of Inorganic Biochemistry. 196 (2019). AbstractWebsite
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Gomes, F. O., L. B. Maia, C. Cordas, I. Moura, C. Delerue-Matos, JJG Moura, and S. Morais. "Electroanalytical characterization of the direct Marinobacter hydrocarbonoclasticus nitric oxide reductase-catalysed nitric oxide and dioxygen reduction." Bioelectrochemistry. 125 (2019): 8-14. AbstractWebsite
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Ramos, DJ, H. Carrelo, J. P. Borges, Nuria Calero Romero, Jenifer Santos García, and María Teresa Cidade. "Injectable Hydrogels Based on Pluronic/Water Systems Filled with Alginate Microparticles for Biomedical Applications." Materials. 12.7 (2019): 1083. Abstractmaterials-12-01083.pdf

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Samhan-Arias, A. K., C. M. Cordas, M. S. Carepo, L. B. Maia, C. Gutierrez-Merino, I. Moura, and JJG Moura. "Ligand accessibility to heme cytochrome b 5 coordinating sphere and enzymatic activity enhancement upon tyrosine ionization." Journal of Biological Inorganic Chemistry. 24.3 (2019): 317-330. AbstractWebsite
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Cordas, C. M., and JJG Moura. "Molybdenum and tungsten enzymes redox properties – A brief overview." Coordination Chemistry Reviews. 394 (2019): 53-64. AbstractWebsite
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Peixoto, Daniela, Gabriela Malta, Hugo Cruz, Sónia Barroso, Ana Luísa Carvalho, Luísa M. Ferreira, and Paula S. Branco. "N-Heterocyclic Olefin Catalysis for the Ring Opening of Cyclic Amidine Compounds: A Pathway to the Synthesis of ε-Caprolactam- and γ-Lactam-Derived Amines." The Journal of Organic ChemistryThe Journal of Organic Chemistry (2019). AbstractWebsite
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Pauleta, S. R., M. S. P. Carepo, and I. Moura. "Source and reduction of nitrous oxide." Coordination Chemistry Reviews. 387 (2019): 436-449. AbstractWebsite
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Chastre, Carlos, Marco Ludovico-Marques, and Hugo Biscaia. "Ensaios não destrutivos para a inspeção e avaliaçao de edifícios históricos de alvenaria de pedra." TEST&E 2019 - 2º Congresso de Ensaios e Experimentação em Engenharia Civil. ISEP, Porto, Portugal 2019. 12. Abstract

Ao longo da sua vida útil os edifícios históricos estão sujeitos a alterações de uso, a agentes ambientais e a diferentes ações como assentamentos do solo, incêndios, inundações ou sismos, para os quais podem não estar preparados. Além disso, a falta de manutenção contínua ajuda a colocar grande parte desse património em risco devido a problemas estruturais que reduzem sua própria segurança e a dos seus utilizadores. A preservação e mitigação de riscos do património cultural construído requer o uso de ferramentas confiáveis, a fim de avaliar o seu estado de conservação e identificar e prevenir potenciais vulnerabilidades. Os testes destrutivos tradicionais não são possíveis de realizar na maioria dos edifícios históricos, por isso é necessário selecionar testes não destrutivos (NDT) que permitam a caracterização física e mecânica dos materiais e do comportamento da estrutura. Neste artigo apresenta-se uma visão geral de diferentes equipamentos e testes NDT que permitem o levantamento geométrico e o mapeamento dos danos do edifício, a análise petrográfica da pedra de alvenaria, a caracterização das propriedades físicas e mecânicas dos materiais e o comportamento estrutural do edifício.

Biscaia, Hugo, Noel Franco, and Carlos Chastre. "Ligações coladas entre barras de aço inox exteriormente coladas a elementos de betão: Análise teórica vs. experimental." TEST&E 2019 - 2º Congresso de Ensaios e Experimentação em Engenharia Civil. ISEP, Porto, Portugal 2019. 11. Abstract

Os sistemas de reforço por colagem exterior têm sido alvo de várias abordagens, não só do ponto de vista do tipo de material a utilizar, como também sob o ponto de vista da técnica mais eficiente a seguir. As fibras reforçadas com polímeros (FRP) têm sido, no último par de décadas, alvo de investigação exaustiva, tendo-se verificado que esses sistemas nutrem de ductilidade algo reduzida devido ao descolamento prematuro do material de reforço da superfície de betão. Por conseguinte, o aço inox devidos às suas boas características anticorrosivas e ductilidade apresenta-se como uma alternativa viável aos compósitos de FRP. Assim, com vista a melhorar a ductilidade dos elementos estruturais reforçados, em vez de se recorrer a técnicas de reforço não tradicionais (e.g., Externally Bonded Reinforcement (EBR) ou Near Surface Mounted (NSM)) que estão sempre associadas a roturas prematuras por colagem do elemento de reforço quando a extensão nele instalada está muito aquém do seu valor de rotura, dever-se-á seguir outras técnicas de reforço por colagem. Com vista a interpretar e perceber o desempenho da ligação aço-inox, desenvolveu-se uma campanha experimental em que os ensaios visam em testar e comparar a técnica EBR com uma técnica inovadora e desenvolvida pelos autores (CREatE – Continuous Reinforcement Embedded at Ends) através da realização de ensaios de arrancamento de ligações aço inox/betão. Estes ensaios consistem em aplicar uma força à barra de aço inox segundo uma direção que permite induzir uma rotura da ligação consistente com o Modo II de fratura. A técnica de correlação de imagem digital (DIC) foi utilizada na monitorização de todos estes ensaios tendo-se desenvolvido ainda diferentes modelos, analíticos e numéricos com recurso a um programa de cálculo automático não linear, que permitiram simular os processos de descolamento da ligação aço inox/betão segundo as técnicas EBR e CREatE.

Chastre, Carlos, and Marco Ludovico-Marques. "Metodologia para a caraterização física e mecânica de edifícios históricos de pedra utilizando ensaios não destrutivos." TEST&E 2019 - 2º Congresso de Ensaios e Experimentação em Engenharia Civil. ISEP, Porto, Portugal 2019. 12. Abstract

Os edifícios históricos como os palácios, castelos, igrejas e templos, são exemplos do património construído e constituem uma parte importante do nosso património cultural. Estas construções históricas incluem normalmente paredes de alvenaria maciça e pedra natural. A salvaguarda do património construído em pedra é de importância inquestionável, pelo que devem ser desenvolvidas e estudadas técnicas de intervenção adequadas em materiais e estruturas. Neste artigo, é apresentada uma metodologia de ensaios não destrutivos para avaliar a conservação de edifícios históricos de pedra e, com base nesta metodologia, é mostrado um caso de estudo na Igreja de São Leonardo, monumento português construído na Atouguia da Baleia no século XIII.

Boavida, Nuno, António Moniz, Juan Aransanz, Pablo Sanz de Miguel, Maria Caprile, Julia Frias, Linda Nierling, Bettina-Johanna Krings, Leon Küstermann, Csaba Makó, Miklós Illéssy, and Katalin Bácsi Work in digital platforms: Literature review from Germany, Hungary, Portugal and Spain. Lisbon: CICS.NOVA, 2019. Abstract

This 1st Report of the project CrowdWork21 presents a summary of the information collected about workers in digital platforms by country (German, Hungary, Portugal and Spain). Each national report describes first the scientific debates about workers of digital platforms. After, the reports present the information collected about the national public debates and identifies the angles normally covered by the media in relation to the organisation of digital workers. Lastly, the reports present initial conclusions about the information collected in each country.