Mota, Bruna, Maria Isabel Gomes, Ana Carvalho, and Ana Paula Barbosa-povoa. "
Supply chain design and planning accounting for the Triple Bottom Line."
12th International Symposium on Process Systems Engineering and 25th European Symposium on Computer Aided Process Engineering. Copenhagen, Denmark : Elsevier, 2015. 1842-1846.
AbstractIn this work, a multi-objective mixed integer linear programming (moMILP) model is presented for the design and planning of sustainable closed loop supply chains. It includes strategic decisions such as facility location, definition of transportation modes, technology selection and allocation, as well as tactical decisions. The model includes four objectives: 1) The economic pillar, measured through the net present value (NPV); 2) the environmental pillar, which includes Life Cycle Assessment (LCA), through the application of the ReCiPe methodology; 3 and 4) The social pillar measured using two socio-economic indicators applied by the European Union in its Sustainable Development Strategy. The applicability of the model is demonstrated through a representative supply chain case study. Results show that the different objectives influence the supply chain structure and translate in significantly different and conflicting decisions, showing the importance of such type of models to better understand the decisions implications on the different dimensions of sustainability.
Brandao Moniz, António, Go Yoshizawa, and Michiel Van Oudheusden. "
Technology Assessment in East Asia: Experience and New Approaches."
The Next Horizon of Technology Assessment. Prague: Technology Centre ASCR, 2015. 287-293.
AbstractTechnology assessment (TA) and TA-like activities in countries like Japan have a unique history and continue to play a role in contemporary science, technology, and innovation (STI) processes. The aim of the discussion of TA’s experience in East Asia is how STI governance is locally enacted in Asian knowledge-driven economies, as TA activities develop in conjunction with STI policies and programs. To render these processes, policies, and programs visible and to understand their implications for STI governance, a panel at the Berlin conference on TA discussed contributions that described and conceptualized, for example, how TA activities have emerged in Asian knowledge-based economies (KBE), in which particular forms (e.g., academic and parliamentary TA programs), to which technologies and/or actors they are linked, and which methods are used and why. The panel also sought to compare and contrast how TA is (or is not) institutionalized in Asian countries and regions, and to point to prospects for expansion of TA capacity. In doing so, the panellists placed the development of TA in a historical, sociological, and comparative perspective, and opened space for critical reflection on the potential, problems, and limitations associated with initiating TA in Asia and with KBEs overall
Kauf, Thomas, Vitor Rosa, Christophe Fliedel, Roberto Pattacini, Naina Deibel, Teresa Aviles, Biprajit Sarkar, and Pierre Braunstein. "
{Reactivity of TCNE and TCNQ derivatives of quinonoid zwitterions with Cu(I)}."
{DALTON TRANSACTIONS}. {44} (2015): {5441-5450}.
Abstract{The reactions of TCNE- and TCNQ-functionalized (TCNE: tetracyanoethylene and TCNQ: 7,7', 8,8'-tetra-cyanoquinodimethane) zwitterionic benzoquinonemonoimines with a Cu(I)-BIAN complex (BIAN = bis-(o, o'-bisisopropylphenyl)acenaphthenequinonediimine) have been investigated and found to follow a diversity of interesting patterns. The complexes {[}Cu(BIAN)(NCMe)(L2)]BF4 (2) and {[}Cu(BIAN)(L2)(2)]BF4 (4) were obtained by reacting {[}Cu(BIAN)(NCMe) 2] BF4 (1) with one and two equivalents of L2, respectively. Following similar procedures, the complexes {[}Cu(BIAN)(NCMe)(L3)] BF4 (6) and {[}Cu(BIAN)(L3)(2)]BF4 (7) were obtained by reaction of 1 with L3. The reaction of 2 with 0.5 equiv. of 4,4'-bipyridine afforded {[}\{Cu(BIAN)-(L2)\}(2)(mu-4,4'-bipyridine)](BF4)(2) (3). The complexes were characterized by multinuclear NMR, IR and UV-Vis spectroscopic techniques, mass spectrometry, cyclic voltammetry and elemental analysis. The molecular structures of complexes 3 center dot 4CH(2)Cl(2) and 4 center dot CH2Cl2 were determined by single crystal X-ray diffraction. An unexpected coordination polymer {[}Cu(L2(-))(2)](infinity) (5) was also structurally characterized, which contains Cu(II) centres chelated by two N, O-bound ligands resulting from the monodeprotonation of L2.}