Titanium dioxide was synthesized on glass substrates from titanium (IV)isopropoxide and hydrochloride acid aqueous solutions through microwave irradiation using as seed layer either fluorine-doped crystalline tin oxide (SnO2:F) or amorphous tin oxide (a-SnOx). Three routes have been followed with distinct outcome: (i) equimolar hydrochloride acid/water proportions (1HCl:1water) resulted in nanorod arrays for both seed layers; (ii) higher water proportion (1HCl:3water) originated denser films with growth yield dependent on the seed layer employed; while (iii) higher acid proportion (3HCl:1water) hindered the formation of TiO2. X-ray diffraction (XRD) showed that the materials crystallized with the rutile structure, possibly with minute fractions of brookite and/or anatase. XRD peak inversions observed for the materials synthesized on crystalline seeds pointed to preferred crystallographic orientation. Electron diffraction showed that the especially strong XRD peak inversions observed for TiO2 grown from the 1HCl:3water solution on SnO2:F originated from a [001] fiber texture. Transmittance spectrophotometry showed that the materials with finer structure exhibited significantly higher optical band gaps. Photocatalytic activity was assessed from methylene blue degradation, with the 1HCl:3water SnO2:F material showing remarkable degradability performance, attributed to a higher exposure of (001) facets, together with stability and reusability.

The present work reports a simple and easy wet chemistry synthesis of cuprous oxide (Cu2O) nanospheres at room temperature without surfactants and using different precursors. Structural characterization was carried out by X-ray diffraction, transmission electron microscopy, and scanning electron microscopy coupled with focused ion beam and energy-dispersive X-ray spectroscopy. The optical band gaps were determined from diffuse reflectance spectroscopy. The photoluminescence behavior of the as-synthesized nanospheres showed significant differences depending on the precursors used. The Cu2O nanospheres were constituted by aggregates of nanocrystals, in which an on/off emission behavior of each individual nanocrystal was identified during transmission electron microscopy observations. The thermal behavior of the Cu2O nanospheres was investigated with in situ X-ray diffraction and differential scanning calorimetry experiments. Remarkable structural differences were observed for the nanospheres annealed in air, which turned into hollow spherical structures surrounded by outsized nanocrystals. FAU - Nunes, Daniela

Fibre reinforced polymer (FRP) composites may prematurely debond from the surface of concrete, i.e. before its elastic resistance is exhausted. This is a very common situation and can be aggravated if additional factors are not taken into account. These factors include the type of surface preparation, the exposure to aggressive environmental action, the tensile concrete strength or fatigue and creep loading to which the structural element may be subject. An experimental programme based on double shear tests was undertaken to analyse the influence of some of these factors on the performance of the interface between composite glass fibres (GFRP) and concrete. The results allowed the determination and comparison of maximum loads transmitted to the GFRP plates and maximum bond stresses obtained considering various surface treatments and aging conditions. Bond–slip curves were also determined. The experimental results are compared with those obtained from a numerical analysis.

The influence of compressive stresses exerted on FRP-concrete joints created by external strengthening of structural members on the performance of the system requires better understanding especially when mechanical devices are used to anchor the externally bonded reinforcement (EBR). The numerical modelling of those systems is a tool that permits insight into the performance of the corresponding interfaces and was used in the present study, essentially directed to analyse the effectiveness of EBR systems under compressive stresses normal to the composite surface applied to GFRP-to-concrete interfaces. The compressive stresses imposed on the GFRP-to-concrete interface model the effect produced by a mechanical anchorage system applied to the EBR system. An experimental program is described on which double-lap shear tests were performed that created normal stresses externally applied on the GFRP plates. A corresponding bond-slip model is proposed and the results of its introduction in the numerical analysis based in an available 3D finite element code are displayed, showing satisfactory agreement with the experimental data. The results also showed that lateral compressive stresses tend to increase the maximum bond stress of the interface and also originate a residual bond stress which has significant influence on the interface strength. Also, the strength of the interface increases with the increase of the bonded length which have consequences on the definition of the effective bond length.

The historically-famous Lotus Fortress site, a deep 1.5–3.0-meter-high, 200-meter-long horizonal notch high up in near-vertical sandstone cliffs comprising the Cretaceous Jiaguan Formation, has been known since the 13th Century as an impregnable defensive position. The site is also extraordinary for having multiple tetrapod track-bearing levels, of which the lower two form the floor of part of the notch, and yield very well preserved asseamblages of ornithopod, bird (avian theropod) and pterosaur tracks. Trackway counts indicate that ornithopods dominate (69%) accounting for at least 165 trackmakers, followed by bird (18%), sauropod (10%), and pterosaur (3%). Previous studies designated Lotus Fortress as the type locality of Caririchnium lotus and Wupus agilis both of which are recognized here as valid ichnotaxa. On the basis of multiple parallel trackways both are interpreted as representing the trackways of gregarious species. C. lotus is redescribed here in detail and interpreted to indicate two age cohorts representing subadults that were sometimes bipedal and larger quadrupedal adults. Two other previously described dinosaurian ichnospecies, are here reinterpreted as underprints and considered nomina dubia. Like a growing number of significant tetrapod tracksites in China the Lotus Fortress site reveals new information about the composition of tetrapod faunas from formations in which the skeletal record is sparse. In particular, the site shows the relatively high abundance of Caririchium in a region where saurischian ichnofaunas are often dominant. It is also the only site known to have yielded Wupus agilis. In combination with information from other tracksites from the Jiaguan formation and other Cretaceous formations in the region, the track record is proving increasingly impotant as a major source of information on the vertebrate faunas of the region. The Lotus Fortress site has been developed as a spectacular, geologically-, paleontologically- and a culturally-significant destination within Qijiang National Geological Park.

n/a

n/a

The influence of mathematical communication over the students’ learning led to this research, whose main goal is to understand the impact on problem solving of the students’ communication difficulties. The study adopts a qualitative and interpretative methodology, undertaking two case studies of 10th grade students. The reached conclusions point to the students’ difficulties at the interpretation of the problem, namely at the interpretation of figures, and at the interpretation of the available data, especially when part of them is irrelevant to the problem. Some difficulties were also identified at the communication level, in relation to the arguments used by the students to support their ideas, where a clear preference to restrict them to mathematic calculations was identified.

Resumo
A importância da comunicação matemática sobre a aprendizagem dos alunos, levou à realização desta investigação que pretendeu compreender o impacto sobre a resolução de problemas das dificuldades de comunicação evidenciadas pelos alunos. Optou-se por uma metodologia de natureza qualitativa e interpretativa e pela realização de estudos de caso envolvendo dois alunos do 10.º ano. As conclusões alcançadas apontam para dificuldades na interpretação do enunciado, nomeadamente relativamente às figuras e a dados em quantidade superior ao necessário. Também ao nível da comunicação da resolução foram identificadas dificuldades em fundamentar ideias, evidenciando uma preferência pelo recurso ao cálculo.

n/a

A aprendizagem dos nossos alunos é fortemente influenciada pelas caraterísticas das tarefas que lhes propomos e a resolução de problemas é frequentemente apontada como uma das tarefas com mais potencial para promover aprendizagens ricas. Mas aprender implica ser capaz de desenvolver raciocínios, de comunicar as nossas ideias e de compreender as dos outros num processo argumentativo e reflexivo. A avaliação das aprendizagens num contexto de resolução de problemas envolve assim, necessariamente como parte importante do processo, uma análise da comunicação que se estabelece entre todos os envolvidos.
Nesta comunicação iremos focar-nos precisamente na comunicação que se estabelece durante a resolução de problemas, abordando as dificuldades dos alunos e dando atenção à interpretação que fazem do enunciado, à compreensão que manifestam das figuras apresentadas, à relação que conseguem estabelecer entre a situação em causa e a informação disponibilizada através de um gráfico, à forma como conseguem explicitar o seu raciocínio e à linguagem matemática que utilizam no decurso do processo de argumentação. Para tal vamos basear-nos num conjunto de problemas propostos a alunos do 10.º ano de escolaridade no decorrer do estudo de funções.

n/a

n/a

As people have become increasingly aware, the age of the European population is rising and the percentage of adults aged 65 years and older is expected to increase. In addition, older people spend about 20 hours per day indoors, and many of them spend essentially their time in elderly care centers (ECC). In this sense, the study of indoor environments and how elder people may be particularly at risk of adverse health effects from pollutants, even at low exposures, due to multiple underlying chronic diseases is becoming an important issue to be addressed by research. Such conditions are highly prevalent, multifactorial, and associated with multiple comorbidities and poor outcomes, such as increased disability and decreased quality of life. The importance of this topic was heightened in 2012 by the World Health Day in 2012 Ageing and health with the theme "Good health adds life to years" and also the ?European Year for Active Ageing and Solidarity between Generations?. Accordingly, this project is suitable to integrate these initiatives and to ensure greater recognition of what older people bring to society and create more supportive conditions for them. To our knowledge, this is the first study in Portugal to assess effects of indoor air contaminants on health status and quality of life in older persons living in ECC. The aim of GERIA project is to carry out a risk assessment, often difficult for older people, involving the identification of multiple factors potentially affecting health and quality of life, the quantification of human exposure to pollutants, and the evaluation of the individual?s response to these stimuli. The results of this project contribute to the understanding of health effects due to indoor environment variables and to provide health benefits to ECC residents with relatively simple measures.

A Mixed Integer Linear Programming model for the design and planning of green supply chains is developed. Strategic and tactical decisions are taken, namely on facility location and capacity installation, supplier selection, technology selection, transportation network definition, supply planning, and product recovery. The aim of this work is to study the use of environmental indicators in these decisions while accounting for profit objectives. Different objective functions concerning environmental aspects are implemented. ReCiPe quantifies the environmental performance of the supply chain and combinations of ReCiPe’s midpoint categories allow a deeper analysis of the impact of these categories in strategic and tactical decisions. The goal is to understand if focusing on selected categories affects supply chain decisions and overall supply chain environmental impact. Net Present Value quantifies the economic performance and is used for lexicographic optimization. The model is applied to a case-study and important managerial insights are obtained. From a holistic point of view, it answers the question: how should supply chain environmental impact be assessed? From a case-study perspective, insights are obtained regarding what type of improvements should be implemented to reduce the environmental impact and how this would affect supply chain strategic and tactical decisions, along with economic performance.

Human-Computer-Interaction (HCI) is a key topic on the Accessibility area, namely in what concerns a Smart-City environment, where humans have to interact with artefacts spread all around one particular city. In the last decade HCI has experienced a significant evolution towards a desired fully natural user interface, for example in what concerns the ability to recognize a wide range of hand gestures in real-time. Some efforts have lately been made in the hardware sector in order to deploy sensors that may gather information about the human body movements, as detailed as possible. One example of this effort is the Kinect Sensor from Microsoft. Nevertheless, although these solutions provide a solution for the body movement, they lack on the details, namely the hands, given their small dimension compared to the body as a whole. In other words, the SDKs provided by the vendors of these devices usually lack on the needed details concerning hand movements that would be needed for an accurate hand gesture recognition implementation. This paper presents an extension to the Kinect SDK based on a contour analysis for the estimation of the hand position. This algorithms are then used to provide the creation of a gesture library that might be used afterwards.