Brandao Moniz, António, Go Yoshizawa, and Michiel Van Oudheusden. "
Technology Assessment in East Asia: Experience and New Approaches."
The Next Horizon of Technology Assessment. Prague: Technology Centre ASCR, 2015. 287-293.
AbstractTechnology assessment (TA) and TA-like activities in countries like Japan have a unique history and continue to play a role in contemporary science, technology, and innovation (STI) processes. The aim of the discussion of TA’s experience in East Asia is how STI governance is locally enacted in Asian knowledge-driven economies, as TA activities develop in conjunction with STI policies and programs. To render these processes, policies, and programs visible and to understand their implications for STI governance, a panel at the Berlin conference on TA discussed contributions that described and conceptualized, for example, how TA activities have emerged in Asian knowledge-based economies (KBE), in which particular forms (e.g., academic and parliamentary TA programs), to which technologies and/or actors they are linked, and which methods are used and why. The panel also sought to compare and contrast how TA is (or is not) institutionalized in Asian countries and regions, and to point to prospects for expansion of TA capacity. In doing so, the panellists placed the development of TA in a historical, sociological, and comparative perspective, and opened space for critical reflection on the potential, problems, and limitations associated with initiating TA in Asia and with KBEs overall
Kauf, Thomas, Vitor Rosa, Christophe Fliedel, Roberto Pattacini, Naina Deibel, Teresa Aviles, Biprajit Sarkar, and Pierre Braunstein. "
{Reactivity of TCNE and TCNQ derivatives of quinonoid zwitterions with Cu(I)}."
{DALTON TRANSACTIONS}. {44} (2015): {5441-5450}.
Abstract{The reactions of TCNE- and TCNQ-functionalized (TCNE: tetracyanoethylene and TCNQ: 7,7', 8,8'-tetra-cyanoquinodimethane) zwitterionic benzoquinonemonoimines with a Cu(I)-BIAN complex (BIAN = bis-(o, o'-bisisopropylphenyl)acenaphthenequinonediimine) have been investigated and found to follow a diversity of interesting patterns. The complexes {[}Cu(BIAN)(NCMe)(L2)]BF4 (2) and {[}Cu(BIAN)(L2)(2)]BF4 (4) were obtained by reacting {[}Cu(BIAN)(NCMe) 2] BF4 (1) with one and two equivalents of L2, respectively. Following similar procedures, the complexes {[}Cu(BIAN)(NCMe)(L3)] BF4 (6) and {[}Cu(BIAN)(L3)(2)]BF4 (7) were obtained by reaction of 1 with L3. The reaction of 2 with 0.5 equiv. of 4,4'-bipyridine afforded {[}\{Cu(BIAN)-(L2)\}(2)(mu-4,4'-bipyridine)](BF4)(2) (3). The complexes were characterized by multinuclear NMR, IR and UV-Vis spectroscopic techniques, mass spectrometry, cyclic voltammetry and elemental analysis. The molecular structures of complexes 3 center dot 4CH(2)Cl(2) and 4 center dot CH2Cl2 were determined by single crystal X-ray diffraction. An unexpected coordination polymer {[}Cu(L2(-))(2)](infinity) (5) was also structurally characterized, which contains Cu(II) centres chelated by two N, O-bound ligands resulting from the monodeprotonation of L2.}
Silva, Tiago, Maria Loja, Nuno M. M. Maia, and Joaquim Barbosa A hybrid procedure to identify the optimal stiffness coefficients of elastically restrained beams. Vol. 25. International Journal of Applied Mathematics and Computer Science, 25.2., 2015.
AbstractThe formulation of a bending vibration problem of an elastically restrained Bernoulli-Euler beam carrying a finite number of concentrated elements along its length is presented. In this study, the authors exploit the application of the differential evolution optimization technique to identify the torsional stiffness properties of the elastic supports of a Bernoulli-Euler beam. This hybrid strategy allows the determination of the natural frequencies and mode shapes of continuous beams, taking into account the effect of attached concentrated masses and rotational inertias, followed by a reconciliation step between the theoretical model results and the experimental ones. The proposed optimal identification of the elastic support parameters is computationally demanding if the exact eigenproblem solving is considered. Hence, the use of a Gaussian process regression as a meta-model is addressed. An experimental application is used in order to assess the accuracy of the estimated parameters throughout the comparison of the experimentally obtained natural frequency, from impact tests, and the correspondent computed eigenfrequency.