Packaging waste collection systems are responsible to collect, within a geographic area, three types of packaging materials (paper, glass and plastic/metal) that are disposed by the final consumer into special bins. Those systems are often characterized by having a network with multiple depots that act as transfer and sorting stations, and where the vehicle fleet is based. However, each depot is often managed independently and not as a part of a unique system. In this work, four current tactical/operational practices that contribute to the independent management of each depot are analysed. The change of such practices is investigated and their impact assessed on the total collection cost. A solution methodology based on mathematical formulations is developed to plan service areas, vehicle routes and vehicle schedules taking into account new alternative solutions in managing the system as a whole. Such methodology is applied to a real case study of a company responsible for the collection of the packaging waste in 7 municipalities in mainland Portugal. New service areas, collection routes and vehicle schedules are defined and significant savings are obtained in terms of the total distance travelled as well as in terms of the number of required vehicles, resulting in a decreasing of the total system cost.

Pulsed field gradient spin echo high resolution magic angle spinning nuclear magnetic resonance spectroscopy is a powerful technique to characterize confined biosystems. We used this approach to assess the diffusion of solvent and reaction species within sol–gel matrices differing in enzyme loading.

We show that if the Hardy-Littlewood maximal operator is bounded on a separable Banach function space \(X(\mathbb{R}^n)\) and on its associate space \(X'(\mathbb{R}^n)\), then a pseudodifferential operator \(\operatorname{Op}(a)\) is bounded on \(X(\mathbb{R}^n)\) whenever the symbol \(a\) belongs to the Hörmander class \(S_{\rho,\delta}^{n(\rho-1)}\) with \(0<\rho\le 1\), \(0\le\delta<1\) or to the the Miyachi class \(S_{\rho,\delta}^{n(\rho-1)}(\varkappa,n)\) with \(0\le\delta\le\rho\le 1\), \(0\le\delta<1\), and \(\varkappa>0\). This result is applied to the case of variable Lebesgue spaces \(L^{p(\cdot)}(\mathbb{R}^n)\).

Let \(p:\mathbb{R}\to(1,\infty)\) be a globally log-Hölder continuous variable exponent and \(w:\mathbb{R}\to[0,\infty]\) be a weight. We prove that the Cauchy singular integral operator \(S\) is bounded on the weighted variable Lebesgue space \(L^{p(\cdot)}(\mathbb{R},w)=\{f:fw\in L^{p(\cdot)}(\mathbb{R})\}\) if and only if the weight \(w\) satisfies $$ \sup_{-\infty < a < b < \infty} \frac{1}{b-a} \|w\chi_{(a,b)}\|_{p(\cdot)} \|w^{-1}\chi_{(a,b)}\|_{p'(\cdot)}<\infty \quad (1/p(x)+1/p'(x)=1). $$

We here present fossil Crocodylomorpha eggshells from the Upper Jurassic Lourinhã Formation of Portugal, recovered from five sites: one nest from Cambelas with 13 eggs, and three partial eggs and various fragments from, Paimogo N (I), Paimogo S (II), Casal da Rola, and Peralta. All specimens but the nest were found in association with dinosaur egg material. Our research reveals that on a micro- and ultrastructural analysis, all samples present the typical characters consistent with crocodiloid eggshell morphotype, such as the shell unit shape, the organization of the eggshell layers, and the triangular blocky extinction observed with crossed nicols. We assign the material from the Lourinhã Formation to the oofamily Krokolithidae, making it the oldest crocodylomorph eggs known so far, as well as the best record for eggs of non- crocodylian crocodylomorphs. Furthermore, our study indicates that the basic structure of crocodiloid eggshells has remained stable since at least the Upper Jurassic.

This paper proposes a systematic methodology for supply chain planning optimization and assessment of different scenarios. This methodology will help companies throughout the difficult process of strategic decision-making in what concerns the design of an efficient supply chain structure. The proposed methodology allows the analysis of complex systems as it integrates a decision support tool developed to agile the process of scenario comparison, when designing network structures. This tool allows practitioners to take advantage of the optimization models without the need of learning modelling languages. An example based on a real case study is presented, showing the methodology/tool applicability.

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This study looks at the analysis of the interface between Fiber Reinforced Polymer (FRP)-to-parent material bonded interfaces. The performance of FRP-to-parent material bonded joints for the Externally Bonded Reinforcement (EBR) technique is numerically modelled with the PFC2D software which is based on the Distinct Element Method (DEM). It is believed that this represents the first time the DEM has been used to simulate the delamination process of FRP-to-parent material bonded joints. In order to validate the analysis performed with the DEM, a Pull-out test with no slip constrains was modelled and different linear bond-slip laws were assumed. The numerical results revealed that the DEM is capable of estimating with good accuracy the exact solutions of bond stresses, strains or slippages along the bonded length for linear bond-slip laws. The bi-linear law available in PFC2D was then compared to the numerical results obtained from other another code developed by the author. The delamination process of Pull-out tests with slip constrain at one of the free ends of the FRP plate is also described and analyzed. The results obtained from the DEM revealed that the delamination process ends with stiffness equal to the axial stiffness of the FRP plate. This evidence highlights the need to design mechanical anchor devices capable of preventing premature debonding which is known to occur on EBR systems.

This paper addresses the planning of recyclable waste collection systems while accounting for economic and environmental concerns. Service areas and vehicle routes are defined for multiple-depot logistics networks where different products have to be collected. The problem is modeled as a multi-product, multi-depot vehicle routing problem with two objective functions: distance and CO2 emissions minimization. A decomposition solution method is developed and applied to a real case-study. Six scenarios are studied regarding different service areas configuration and different objective functions. Savings up to 22% in distance and 27% in CO2 emissions are achieved, excelling economical and environmental goals.

Iron oxide nanoparticles are having been extensively investigated for several biomedical applications such as hyperthermia and magnetic resonance imaging. However, one of the biggest problems of these nanoparticles is their aggregation.

Taking this into account, in this study the influence of three different surfactants (oleic acid, sodium citrate and Triton X-100) each one with various concentrations in the colloidal solutions stability was analyzed by using a rapid and facile method, the variation in the optical absorbance along time.

The synthesized nanoparticles through chemical precipitation showed an average size of 9 nm and a narrow size distribution. X-ray diffraction pattern and Fourier Transform Infrared analysis confirmed the presence of pure magnetite. SQUID measurements showed superparamagnetic properties with a blocking temperature around 155 K. In addition it was observed that neither sodium citrate nor Triton X-100 influences the magnetic properties of the nanoparticles. On the other hand, oleic acid in a concentration of 64 mM decreases the saturation magnetization from 67 to 45 emu/g. Oleic acid exhibits a good performance as stabilizer of the iron oxide nanoparticles in an aqueous solution for 24 h, for concentrations that lead to the formation of the double layer.

During the last years several projects and studies have improved the knowledge about Textile Reinforced Mortar (TRM) technology. TRM has already been used in strengthening masonry and reinforced concrete structural elements such as walls, arches, columns and beams. This material is presented as a real alternative to the use of fibre-reinforced polymers (FRP) in situations where these composites have presented some drawbacks or their use is banned. Textile Reinforced Mortar show a complex mechanical behaviour derived from the heterogeneity of the constituent materials. This paper aims to deepen the knowledge of this composite material in terms of tensile behaviour. Following this scope, this paper presents an experimental campaign focused on thirty one TRM specimens reinforced with four different reinforcing ratios. The results are analysed and contrasted with two distinct models. i) the Aveston-Cooper-Kelly theory (ACK) which is based on a tri-linear analytical approach; and ii) a nonlinear numerical simulation with a 3D Finite Element code. The Finite Element Analysis (FEA) of the TRM tensile tests also showed no significant dependence on the basalt-to-mortar interface, i.e., the choice of a bond-slip curve in order to reproduce the bond stresses and slippages along the interface is irrelevant and it can be simply considered as rigid interface.

Nowadays there is a clear increase of products or tailored solutions with the goal of better adept to the needs of
clients. In another context there is a wide growth of computers’ presence in the class rooms, in order to assist
the teacher to captivate and motivate the students using educational games. However not all teachers have the
advanced computer knowledge that would allow them to personalize games, which would benefit children by
providing tailored solutions to their specific needs. Having this problem into consideration it was designed/idealized a system that relies on a framework of game creation that allows a user with less informatics skills to create a game based on a model. Although there are many games of this type it would be useful and innovative for a teacher to be able to create a game that is personalized to the students’ needs and according to the skills that they wish to develop. This system consists in an interface where the user has to follow some established steps, in order to achieve a file containing all the game features, which is later imported to
a framework. That system allows the creation of different games, as long as these games come under the same game mechanics.

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The thermal behavior and transport properties of several ion jellys (IJs), a composite that results from the combination of gelatin with an ionic liquid (IL), were investigated by dielectric relaxation spectroscopy (DRS), differential scanning calorimetry (DSC), and pulsed field gradient nuclear magnetic resonance spectroscopy (PFG NMR). Four different ILs containing the dicyanamide anion were used: 1-butyl-3-methylimidazolium dicyanamide (BMIMDCA), 1-ethyl-3-methylimidazolium dicyanamide (EMIMDCA), 1-butyl-1-methylpyrrolidinium dicyanamide (BMPyrDCA), and 1-butylpyridinium dicyanamide (BPyDCA); the bulk ILs were also investigated for comparison. A glass transition was detected by DSC for all materials, ILs and IJs, allowing them to be classified as glass formers. Additionally, an increase in the glass transition temperature upon dehydration was observed with a greater extent for IJs, attributed to a greater hindrance imposed by the gelatin matrix after water removal, rendering the IL less mobile. While crystallization is observed for some ILs with negligible water content, it was never detected for any IJ upon thermal cycling, which persist always as fully amorphous materials. From DRS measurements, conductivity and diffusion coefficients for both cations (D+) and anions (D–) were extracted. D+ values obtained by DRS reveal excellent agreement with those obtained from PFG NMR direct measurements, obeying the same VFTH equation over a large temperature range (ΔT ≈ 150 K) within which D+ varies around 10 decades. At temperatures close to room temperature, the IJs exhibit D values comparable to the most hydrated (9%) ILs. The IJ derived from EMIMDCA possesses the highest conductivity and diffusion coefficient, respectively, 10–2 S·cm–1 and 10–10 m2·s–1. For BMPyrDCA the relaxational behavior was analyzed through the complex permittivity and modulus formalism allowing the assignment of the detected secondary relaxation to a Johari–Goldstein process. Besides the relevant information on the more fundamental nature providing physicochemical details on ILs behavior, new doorways are opened for practical applications by using IJ as a strategy to produce novel and stable electrolytes for different electrochemical devices.