This study looks at the analysis of the interface between Fiber Reinforced Polymer (FRP)-to-parent material bonded interfaces. The performance of FRP-to-parent material bonded joints for the Externally Bonded Reinforcement (EBR) technique is numerically modelled with the PFC2D software which is based on the Distinct Element Method (DEM). It is believed that this represents the first time the DEM has been used to simulate the delamination process of FRP-to-parent material bonded joints. In order to validate the analysis performed with the DEM, a Pull-out test with no slip constrains was modelled and different linear bond-slip laws were assumed. The numerical results revealed that the DEM is capable of estimating with good accuracy the exact solutions of bond stresses, strains or slippages along the bonded length for linear bond-slip laws. The bi-linear law available in PFC2D was then compared to the numerical results obtained from other another code developed by the author. The delamination process of Pull-out tests with slip constrain at one of the free ends of the FRP plate is also described and analyzed. The results obtained from the DEM revealed that the delamination process ends with stiffness equal to the axial stiffness of the FRP plate. This evidence highlights the need to design mechanical anchor devices capable of preventing premature debonding which is known to occur on EBR systems.