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This work presents the results and the main conclusions of a series of experimental tests carried out to evaluate the efficiency of post-installed stainless steel reinforcement on the flexural strengthening of Reinforced Concrete (RC) T-beams when the bonding techniques EBR (Externally Bonded Reinforcement), NSM (Near Surface Mounted) and MA-EBR (EBR with Mechanical Anchors) are used. The RC T-beams were also modelled using a commercial Finite Element (FE) software in order to predict their behaviour until the rupture. For this purpose, a set of single-lap shear tests were also carried out to evaluate the local bond-slip relationships developed within the Stainless Steel (SS)-to-concrete interface. Due to the experimental bond-slip relationships, the numerical simulations were able to predict, with good accuracy, the different behaviours of the RC T-beams until their rupture. Moreover, the different rupture modes observed on all the RC T-beams herein tested were very well estimated by the numerical analyses. The tests of the RC T-beams showed that all the strengthening techniques allowed their flexural stiffness to be increased. Nevertheless, the RC T–beams strengthened with the EBR and NSM techniques had premature ruptures, i.e. the rupture in the RC T-beams occurred even before the yielding of their steel reinforcements. The RC T-beam strengthened with the MA-EBR technique showed good ductility and the highest load bearing capacity, which means that the MA-EBR technique is the best bonding technique herein used. © 2018 Elsevier Ltd

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The compounds 1-naphthyliminoferrocene{,} 1{,} and 2-methyl-1-naphthyliminoferrocene{,} 2{,} were prepared by the reaction of ferrocenecarboxaldehyde and the corresponding amine{,} 1-naphthylamine and 2-methyl-1-naphthylamine with one drop of pyrrolidine as catalyst{,} in CH2Cl2{,} under inert atmosphere. The compounds were fully characterized by elemental analyses{,} matrix-assisted laser desorption/ionization - time-of-flight mass spectrometry (MALDI-TOF){,} FT-IR{,} 1H and 13C NMR as well as two-dimensional{,} NOESY{,} COSY and HSQC{,} NMR spectroscopy. Mossbauer spectroscopic studies were performed to characterize the iron species in both compounds. The solid-state molecular structures of compounds 1 and 2 were determined by single crystal X-ray diffraction. Analysis of the electrochemical behaviour of complexes 1 and 2 was performed by cyclic and square wave voltammetry. Compounds 1 and 2 were tested as chromogenic and electrochemical sensors for Hg2+.

The non-linear shear behaviour of bovine cortical bone is measured by coupling the Arcan test with digital image correlation. The experimental study is carried out on specimens taken from bovine femur and oriented along the longitudinal-tangential material plane. An ad hoc Arcan fixture is built to transfer the cross-head displacement of the testing machine into a shear loading at the centre of the V-notched section. A validation of predominant shear behaviour at the gauge section is shown from full-field deformation measurements. Moreover, direct evaluation of the shear modulus is obtained by integrating the shear strain component along the V-notches, avoiding numerical correction factors required in the classical data reduction scheme. The shear modulus of bovine cortical bone is found in good agreement with references from literature. Moreover, the shear stress at maximum load is understood as a suitable estimation of the shear strength. Furthermore, the Ramberg�Osgood model is found to provide an accurate description of the non-linear shear behaviour of bone tissue.

Earthquakes, soil settlements, traffic vibrations, and air pollution are some of the actions that can affect historic old buildings. Besides these, the lack of continuous maintenance puts a large part of this heritage in risk due to structural problems that reduce their own safety and that of their users. The preservation and risk mitigation of built cultural heritage require the use of reliable tools in order to assess its state of conservation and to identify and prevent potential vulnerabilities. Having this in mind, it is not possible to carry out destructive tests in most historic old buildings, so it is preferable to opt for nondestructive tests (NDT) or alternative methodologies that allow the physical and mechanical characterization of materials and structure. In this chapter, a general view of NDT methods used in historic buildings to obtain the geometrical information, the damage mapping, the mechanical and physical characterization, and the petrographic analysis of stones is presented. An alternative methodology to physically and mechanically characterize the stone of historic buildings using NDT tests is also proposed. The chapter ends with a case study carried out in the St. Leonard’s Church, a Portuguese monument built in Atouguia da Baleia village in the 13th century, where the alternative methodology here presented was applied. The final results of this study show that the methodology proposed allows the obtention of stress-strain curves in a completely nondestructive way, based on the water absorption coefficient at low pressure.