Abstract This work presents ToBLoOM – Triple Bottom Line Optimization Modelling, a decision support tool for the design and planning of sustainable supply chains. It consists of a multi-objective mixed integer linear programming model which integrates several interconnected decisions: facility location and capacity determination; supplier selection and purchase levels definition; technology selection and allocation; transportation network definition including both unimodal and intermodal options; supply planning; product recovery and remanufacturing. The three pillars of sustainability are addressed as objective functions: economic, through Net Present Value; environmental through the Life Cycle Analysis methodology ReCiPe; and social through a developed GDP-based metric. Uncertainty is considered using a stochastic ToBloOM. This applied to a case of a European based company with markets in Europe and South America. This work contributes to the literature by building on several identified research gaps such as the need for an integrated approach that allows simultaneous assessment of different interacting supply chain decisions, the need to explicitly assess the environmental impact in closed-loop supply chains, the need to assess the impact of supply chains on society, and the need for a multi-objective tool that includes all the three pillars of sustainability. Strategies towards a more sustainable supply chain are also derived from this work.

A new and never yet reported hetero arylidene-9(10H)-anthrone structure (4) was unexpectedly isolated on reaction of 1,2-dimethyl-3-ethylimidazolium iodide (2) and 9-anthracenecarboxaldehyde (3) under basic conditions. Its structure was unequivocally attributed by X-ray crystallography. No cytotoxicity in human healthy fibroblasts and in two different cancer cell lines was observed indicating its applicability in biological systems. Compound 4 interacts with CT-DNA by intercalation between the adjacent base pairs of DNA with a high binding affinity (Kb = 2.0(± 0.20) x 105 M-1) which is 10x higher than that described for doxorubicin (Kb = 3.2 (±0.23) × 104 M-1). Furthermore, compound 4 quenches the fluorescence emission of GelRed-CT-DNA system with a quenching constant (KSV) of 3.3(±0.3) x 103 M-1 calculated by the Stern-Volmer equation.

This study aims to understand the perceptions of lower and upper secondary age teachers of mathematics regarding the use of technology to teach functions. For that, a mixed methodology was adopted, and the perceptions of 129 teachers were collected through a questionnaire (quantitative section) and four teachers through an interview (qualitative section). The main conclusions point to similarities in teachers' perceptions, but also to some differences related to the level that they taught. Teachers show conviction about their knowledge on technology and about the potential of technology in what concerns their teaching and the students’ learning. However, they are not so clear about the best way to articulate technology and paper-and-pencil methods, nor about the use of technology in assessment.

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https://docentes.fct.unl.pt/lblm/files/inorgchem-2018-57-8078.pdf

A aprendizagem de leitura implica no desenvolvimento de competências e habilidades e as TICs possuem o papel de gerar estratégias de relação com o saber. Esta pesquisa identifica competências para uma maior autonomia do sujeito em leitura, via relação entre as tecnologias da informação e comunicação e outros letramentos, através da investigação sobre a prática pedagógica de letramento digital na escola fundamental, no sétimo ano. O método consiste em um estudo, de caráter quantitativo, no qual são analisados os contextos de uso do letramento digital, a junção de diversos outros letramentos e habilidades subjacentes ao letramento digital e a interrelação com plataformas (de gestão de aprendizagem, imagens e vídeos), tecnologias para publicação e partilha de conteúdos, tecnologias de colaboração e construção, redes sociais e tecnologias de comunicação interpessoal. Depois, uma abordagem complementar de investigação-ação Design-Based Research (Db-R) estuda de que forma deve o professor trabalhar com os alunos para favorecer essa autonomia. Os resultados apontam para um conjunto de ações, nas políticas públicas nas práticas pedagógicas, com medidas a superar as dificuldades e os atavismos, com a inserção dos estudantes em práticas com letramento digital e emprego de ferramentas e recursos desenvolvidos de modo específico para o público final. Palavras-chave: Db-R, Letramento, TIC.

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Pseudo-cyclic and cyclic loading were applied to CFRP-to-steel bonded joints built with two different CFRP laminates. In this paper, the strength capacity and bond-slip curves are presented and compared. The modes of failure are also described and associated with the types of material used, and the observed performances are correlated. The analysis of the results showed a threshold value for loading and amplitude level, below which the cyclic loading caused no detectable damage. For cycles above that limit, the region of the joints around the loaded end presented degradation reflected on the bond-slip stiffness and on the increase of residual deformation. It was found that the normalized dissipated energies either obtained from the bond-slip relationship or from the load-slip response had the same trend. The experimental data allowed also to establish a relationship between the damage developed within the interface and the normalized slip. A preliminary estimate of fatigue limit based on those data is suggested. © 2018 Elsevier Ltd

Abstract Sandstones are widely used in the building elements of the world’s stone monuments. Alveolization due to salt crystallization-dissolution is the most important degradation pattern found on the Middle Ages’ sandstone façades of St. Leonardo’s Church in Portugal. An outstanding case of widespread distribution of deep and large alveolization patterns found mainly on portals and vaults of its sandstone façades appeared as a result of the past and present proximity of the seashore. On stonewall façades, a new approach of consolidating products’ treatments using the total head was followed in order to allow full absorption of stone. Physical and mechanical tests were carried out on selected representative specimens of varieties of sandstones on the monument. Treatments with ethyl silicates were assessed by means of its effectiveness, harmfulness, and durability. The comparison of results between the application of this new procedure on this stone monument and the traditional intervention treatments highlighted the potential viability of the former to overcome difficult conditions of absorption of consolidating products.