In this work, we highlight the influence of three different sol stabilizers, namely diethanolamine (DEA), Ammonium Hydroxide (NH4OH), and Nitric Acid (HNO3), on the optical and structural properties of spin-coated zinc oxide (ZnO) thin films. The XRD patterns related to all films exhibit a hexagonal crystal structure with a preferential orientation along the (0 0 2) direction. However an additional {\textless}100{\textgreater} peak arises when the films are prepared with DEA and NH4OH showing a better crystallinity than that displayed by HNO3-prepared films. The elaborated films show a high transparency reaching 80{%} for DEA-prepared films. The analysis of the transmittance and the reflectance measurements confirms a direct band-to-band transition. Depending on the sol stabilizer, the optical band gap energy is varying from 3.16 to 3.22 eV. The relatively wide band-gap of DEA-prepared ZnO films is correlated to their high crystallinity. Room temperature photoluminescence spectra indicate strong UV emission at around 377 nm originated from nearby band-edge transitions. Yet, the use of DEA as a stabilizer leads to a net intensity increase of the blue peak emission.

The high global burden of over one million annual lethal fungal infections reflects a lack of protective vaccines, late diagnosis and inadequate chemotherapy. Here, we have generated a unique set of fully human anti-Candida monoclonal antibodies (mAbs) with diagnostic and therapeutic potential by expressing recombinant antibodies from genes cloned from the B cells of patients suffering from candidiasis. Single class switched memory B cells isolated from donors serum-positive for anti-Candida IgG were differentiated in vitro and screened against recombinant Candida albicans Hyr1 cell wall protein and whole fungal cell wall preparations. Antibody genes from Candida-reactive B cell cultures were cloned and expressed in Expi293F human embryonic kidney cells to generate a panel of human recombinant anti-Candida mAbs that demonstrate morphology-specific, high avidity binding to the cell wall. The species-specific and pan-Candida mAbs generated through this technology display favourable properties for diagnostics, strong opsono-phagocytic activity of macrophages in vitro, and protection in a murine model of disseminated candidiasis.

Semiconductor nanowires are mostly processed by complex, expensive and high temperature methods. In this work, with the intent of developing zinc tin oxide nanowires (ZTO NWs) by low-cost and low-complexity processes, we show a detailed study on the influence of chemical parameters in the hydrothermal synthesis of ZTO nanostructures at temperatures of only 200 °C. Two different zinc precursors, the ratio between zinc and tin precursors, the concentration of the surfactant agent and of the mineralizer were studied. The type and the crystallinity of the nanostructures was found to be highly dependent on the used precursors and on the concentration of each reagent. Conditions for obtaining different ZTO nanostructures were achieved, namely Zn2SnO4 nanoparticles and ZnSnO3 nanowires with length ≈ 600 nm, with the latter being reported for the first time ever by hydrothermal methods without the use of seed layers. Optical and electrical properties were analyzed, being obtained band gaps of 3.60 and 3.46 eV, fo...

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Com o crescente consumo de energia elétrica são cada vez mais os países que procuram fontes de energia renovável e limpa, entre elas a eólica. A quantidade de energia produzida é influenciada pela altura das torres, dimensões das pás e potência dos aerogeradores. Quanto maior for a elevação da turbina maiores são a velocidade e estabilidade dos ventos alcançados. A solução de torre treliçada em concreto armado pré-moldado idealizada por Lúcio e Chastre [2] permite a construção de torres altas e é competitiva em relação aos outros sistemas estruturais.As ligações têm uma importância fundamental no comportamento global das estruturas pré-moldadas. A viabilidade da ligação (fácil execução, baixo custo, comportamento/capacidade resistente) é preponderante na viabilização da construção destas torres.Até à data foram estudadas quatro ligações (S1, S2, S3 e S4), sendo neste artigo abordadas apenas as ligações do modelo S3 com junta de 3mm (barras salientes/bainhas corrugadas/selagem com grout) e do modelo S4 com junta de 50 mm (ligações aparafusadas produzidas comercialmente).Através dos resultados experimentais pode-se concluir que o mecanismo de rutura foi o mesmo nos dois modelos e que as soluções estudadas preenchem os requisitos para a sua utilização em estruturas pré-moldadas de concreto armado para suporte de aerogeradores.

Este artigo avalia se, para especificações de betão correntes, a resistência à compressão de betão pronto é significativamente dependente da central que o produziu, bem como se a variabilidade entre amassaduras de uma determinada composição é dependente da classe de resistência especificada. É apresentado um parâmetro probabilístico que converte a resistência à compressão característica especificada para a resistência à compressão expectável em provetes de betão cúbicos em condições padronizadas.É feita uma análise estatística e probabilística dos resultados de ensaios de resistência à compressão aos 28 dias de betão pronto produzido em três centrais de betão portuguesas durante o ano de 2017. Após a avaliação da representatividade da base de dados analisada, é feito um estudo comparativo dos parâmetros estatísticos dos dados de produção das diferentes centrais e é avaliada a influência da classe de resistência à compressão do betão nestes parâmetros. Define-se e analisa-se um parâmetro probabilístico que converte a resistência à compressão especificada para a resistência potencial de betão, para cubos de 150 mm. Este parâmetro contribui para uma futura proposta de um modelo probabilístico, a ser utilizado em análises de fiabilidade, que converte a resistência à compressão especificada para a resistência à compressão de elementos de betão em obra.Quer a análise estatística dos ensaios de resistência à compressão, quer o parâmetro de conversão são comparados com os resultados de investigações internacionais na área, aferindo-se se a qualidade da produção de betão pronto nacional é semelhante à de outras regiões.

Concrete structures Externally Bonded Reinforced (EBR) with Fibre Reinforced Polymers (FRP) have been studied and used since the end of the last century. However, several issues need to be better studied in order to improve performance. The influence of size of anchorage plates used on Reinforced Concrete (RC) structures strengthened with EBR FRP composites, the external compressive stress to be applied on the anchorage plate and the numerical simulation of this region are some of the topics that need to be more carefully studied in order to clarify the performance of the FRP-to-concrete interface within the anchorage plate region. This study proposes a design methodology to estimate the amount of external compressive stress necessary to be applied on the anchorage plate of EBR systems with FRP composites, in order to avoid premature debonding. The external compressive stress imposed on the FRP composite is intended to simulate the effect produced by a mechanical anchorage system tightened to the EBR system. The results from the design proposal, when compared with the numerical ones, were efficient enough on the prediction of the bond strength improvement of FRP-to-concrete interfaces.

Power Hardware-in-the-Loop (PHiL) system for asynchronous electric drives application based on power inverter with Field Programmable Gate Array (FPGA)-based control system is discussed. Proposed PHiL structure and scheme for asynchronous electric drives are under discussion as well. Described PHiL can be used for power inverters multi-stage testing.

A low power wireless sensor network utilizing the neutral to earth voltage as a power source is developed and analyzed. It consists of a batteryless energy harvesting powered wireless sensor nodes, a gateway (if needed) and a local or remote server (if used). An invasive energy harvesting method to use the voltage between the neutral conductor and the ground conductor is used for the sensor module. A test network is built in a household. Statistics of the household's electric current and the corresponding neutral conductor's voltage is obtained during a two months period. The statistics is further processed to verify the working principle of the proposed network and to enlighten its strengths and weaknesses. The sensor nodes are developed using widely existing electronic components and don't require specialized devices.

Problem of the reliability increasing of the vehicles electric drives is discussed in context of the reduction of the electric motor heating during variable character of movement. Opportunities of the induction motor stator winding heating reduction by means of the control of the vehicles electric drives in transient and steady state modes of movement are shown. Analytical expressions for dynamic torque, optimal on minimal of the winding temperature rise during acceleration, as well as expressions for dynamic torque and value of the motor torque limitation, optimal on energy consumption during acceleration are presented. It is shown that desire to reduce the stator winding temperature rise by means of dynamic torque optimal value selection or motor torque limitation can lead to the rise of energy consumption. Results of the modeling are presented.

This paper presents a wireless energy transfer system operating at the frequency values of kHz order: modeling, simulation, and comparison with prototype measurement results. Wireless energy transfer system model using finite element method was carried out to simulate the electric field and the magnetic flux density for different air gap sizes between the transmitter and the receiver coils. Results are presented and compared with the electromagnetic emission measurements radiated by the wireless energy transfer system prototype. The electric field comparison between the simulated and the prototype measurement values shows an error of roughly 8.7{%}. In the recent years, the interest in the wireless energy transfer technology, especially for electric vehicles batteries charging, is rapidly increasing. As a result of the increasing application of this technology in the industrial and consumer electronic products, more concerns are raised about the electromagnetic compatibility, since the wireless energy transfer systems produce electromagnetic emissions in the surrounding environment.

Although tourism is a major engine of economic growth, it also creates a burden hard to manage, and has a great impact on the conservation of the heritage. The HERIT-DATA project aims to reduce the impact of human activities, related to tourism, on cultural heritage, with a special focus on two kind of cultural destinations that can benefit from and be affected by mass tourism: Old towns and places of specific cultural heritage or archaeological interest for visitors, including UNESCO World Heritage Sites. In that framework, HERIT-DATA plans to develop of a sustainable and responsible tourism management towards cultural heritage in MED regions, in particular by taking advantage of technology and innovation in management tools (Smart Cities), as well as other policy and social measures.

The use of adhesively bonded joints between Fiber Reinforced Polymers (FRP) and concrete elements have been spread out in the past decades. However, due to their recent applications, the durability aspects related with these bonded joints requires the use of high safety factors which strongly restricts the mechanical capacity of the FRP composites. The experimental assessment of the degradation of FRP-to-concrete interfaces is an important task because it provides useful data that can be used to calibrate analytical or numerical models with the aim of helping on the correct understanding of the interfacial degradation. In this work, a new and simple interfacial bond-slip model that needs only one parameter to be experimentally defined is proposed. Compared to unaged Glass (G) FRP-to-concrete interfaces, the relative degradation of these bonded interfaces is studied after being subjected to: (i) salt fog cycles; (ii) wet-dry cycles; (iii) temperature cycles between -10ºC and +30ºC; and (iv) between +7.5ºC and +47.5ºC. The subsequent full debonding processes are predicted through an analytical model that takes into account the degradations experimentally determined from the tests.