The fluid phase behaviour for the binary systems carbon dioxide+cyclobutanone and propane+cyclobutanone has been determined experimentally, using Cailletet equipment. For both the systems bubble points have been determined for a number of isopleths covering the whole mole fraction range. Additionally, for the binary system carbon dioxide+cyclobutanone dew points and critical points could be observed for a number of overall-compositions rich in carbon dioxide. The temperature and pressure range were, respectively, from 278 to 369K and from 0.1 to 14.0MPa. Correlation of the experimental data of both systems has been performed using the Soave-Redlich-Kwong (SRK) equation of state. Satisfactory results have been achieved using only one binary interaction parameter. © 2003 Elsevier B.V. All rights reserved.

In this paper we extend results on Fredholmness of singular integral operators with piecewise continuous coefficients in reflexive rearrangement-invariant spaces \(X(\Gamma)\) with nontrivial Boyd indices \(\alpha_X,\beta_X\) [K98] to the weighted case. Suppose a weight \(w\) belongs to the Muckenhoupt classes \(A_{\frac{1}{\alpha_X}}(\Gamma)\) and \(A_{\frac{1}{\beta_X}}(\Gamma)\). We prove that these conditions guarantee the boundedness of the Cauchy singular integral operator \(S\) in the weighted rearrangement-invariant space \(X(\Gamma,w)\). Under a ``disintegration condition'' we construct a symbol calculus for the Banach algebra generated by singular integral operators with matrix-valued piecewise continuous coefficients and get a formula for the index of an arbitrary operator from this algebra. We give nontrivial examples of spaces, for which this ``disintegration condition'' is satisfied. One of such spaces is a Lebesgue space with a general Muckenhoupt weight over an arbitrary Carleson curve.

Let \(\Gamma\) be an oriented Jordan smooth curve and \(\alpha\) a diffeomorphism of $\Gamma$ onto itself which has an arbitrary nonempty set of periodic points. We prove criteria for one-sided invertibility of the binomial functional operator \(A=aI-bW\) where $a$ and $b$ are continuous functions, \(I\) is the identity operator, \(W\) is the shift operator, \(Wf=f\circ\alpha\), on a reflexive rearrangement-invariant space \(X(\Gamma)\) with Boyd indices \(\alpha_X,\beta_X\) and Zippin indices \(p_X,q_X\) satisfying inequalities
\[
0<\alpha_X=p_X\le q_X=\beta_X<1.
\]

This article is based on the lesson presented in the scope of academy activities in the area of Sociology (at FCT-UNL). It is intended to approach the controversies concerning the relation between technology and society (technological determinism, effect on employment, importance of the social behaviours in the definition of needs for new products and equipment), and on the most recent trends (over all, since middle of the last century) in terms of technological evolution and of its social and cultural change. Finally, this subject was dedicated to the presentation of the main factors that has lead to the development of the contribution of sociology for the training and education in engineering. Thus, one intends to acquire new elements on this area of knowledge also presented in other schools of engineering of other countries (for examples, United States and Holland), and how the theoretical beddings are been developed since the beginning of 20th century on the modalities of work organization that imply a cooperation between engineering and social sciences.

Rheocasting, as a semi-solid process, allows the production of aluminium matrix composites at relatively low temperatures (ca. 580ºC), thus favouring a reduced reactivity at the reinforcement-metal matrix interface. When one considers the possibility of further processing (such as any treatment involving remelting, even if partial) of the material, this trait allows a more rigorous control of the interfaces. Composite samples have been produced using as matrix an Al-7Si-0.3Mg alloy reinforced with SiCp (granulometry: 120 μm; Vr = 0.30). These were rheocast at 583ºC, followed by forging and subsequent water-quenching. A structural characterisation (optical microscopy and XRD) of the as-received matrix material, as well as of the reinforced and non-reinforced rheocast material was performed. The phases identification will provide a basis for the understanding of the further processing where the rheocast material will be used as a raw material to produce functionally graded metal-matrix composites by centrifugal casting.

The incorporation of a Keggin-type heteropolyanion, the phosphotungstate ([PW12O40](3-)), into polypyrrole has been achieved during the electrochemical preparation of the polymer films in aqueous solution. The redox behaviour of these modified electrodes is described by using cyclic voltammetry (CV) and electrochemical quartz crystal microbalance (EQCM). The data allowed to estimate the doping level that indicates the extent of the heteropolyanion insertion. It is found that the polymer films, in aqueous solution, exhibit sensibility to cations, namely to Na+. (C) 2002 Elsevier Science Ltd. All rights reserved.

Recent studies continue to indicate the existence of a narrow relationship between flexible work organizations and the economic growth, in particular, Sweden and Germany. The measure of this relationship is many times the result of the value added per worker. Therefore, the causes of economic growth must be perceived from the interior of the company (work organization, technology, infrastructures, product design). On the other hand, the capacity of innovation can be perceived by the market through new products and services, and still significant changes with the introduction of new equipment and design of an efficient work organization. In this article it is analyzed the evolution of the productivity and employment levels in Portugal and other European countries, over all, during the decade of 90. An analysis for sector is made still. One verifies often that economic growth can be without employment growth. However, the growth can be obtained when if it reaches bigger added value and the efficiency can be verified when there are diminished costs for a same period of time, although that the labor productivity is also the pointer of the quality of life in a economy, therefore it represents the value produced by the work. Moreover, the total factors productivity is the measure of the technological and organizational progress (don’t includes only the technological investments). It is tried to get and to analyze the available statistics on these dimension in Portugal, concluding that Portugal presents an enterprise structure predominantly based on small and very small companies, a great number of which is market by a weak potential of adaptability, innovation and sustainability. It becomes urgent to take the non-material factors that integrate the productivity dimension, as factors of intervention for a benchmarking that allows a process of sustainable growth.

The Portuguese National Action Plan for Employment (NAP) is the main instrument for the labour market policy. It was adopted in 1998. The NAP transposes to the Portuguese reality the contents of such guidelines, with the adequate adjustments required by the national specificities, establishing objectives, quantified targets and action deadlines, as well as defining new programmes and measures. Therefore, the objectives of the labour market policy were focusing on the promotion of an adequate transition of the youngsters in active life, on the promotion of social and professional insertion and fight against long term unemployment and exclusion, on the improvement of basic and professional qualification of the working population in a perspective of lifelong training, namely as a way to prevent unemployment phenomena, and on the preventive management and follow-up of sectoral restructuring processes.

A propose for this article is to present information on the emergence of the knowledge field of sociology of work and labor studies in Portugal. The period of 1974-1984 produced an interesting bibliography in the fields of social stratification, labor conflicts and social history. However, and since the mid-1980s, significant changes have emerged. There took place an increased theoretical diversity and also there was a major preoccupation with the development of a more professional teaching of the discipline. At this time, the first graduated specialists in Sociology appeared in the labor market since 1980, working in municipalities, industrial firms, public health institutions, schools, or even in research and development (R&D) units. The Portuguese association in this field (APSIOT) organized many scientific meetings, debates with unionists, managers and politicians, beside the regular publication of review “Organizações e Trabalho” (Organization and Work) since 1989. It started the diffusion of a professional culture of sociologists who associate science and their occupation concerning themselves not only with scientific quality, but also with technical competence and social responsibility. At the same time, one could assist to the participation of sociologists in the social and organizational molding of new technologies in order to promote alternative production systems.