We present a first theoretical determination of the hyperfine coupling constants of a spherical top molecule using ab initio methods. The scalar and tensorial contributions to the spin-rotation constants and the diamagnetic and paramagnetic contributions to the nuclear shielding constant are calculated for the ³²SF₆ molecule. The corrections to the spin-rotation constants due to nuclear Thomas precession are evaluated and discussed. Our results are compared with previously reported experimental values.

We present a first theoretical determination of the hyperfine coupling constants of a spherical top molecule using <i>ab initio</i> methods. The scalar and tensorial contributions to the spin-rotation constants and the diamagnetic and paramagnetic contributions to the nuclear shielding constant are calculated for the ³²SF₆ molecule. The corrections to the spin-rotation constants due to nuclear Thomas precession are evaluated and discussed. Our results are compared with previously reported experimental values.

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To evaluate the evolution of a dark film formation on silver surface objects, several coupons were catalogued and place inside a museum, located in an urban area. The changes on these samples were measured by spectroscopic ellipsometry, in periods of months. This technique allows the reduction of the coupons exposure time, in several months, due to its high sensitivity to surface modifications, with acceptable results for the evaluation of its degradation. The thicknesses of the degradation layers and the optical properties of silver oxide, chloride and sulphide reference samples were determined using a mixture of Tauc-Lorentz and Drude models. The composition of the silver corrosion layer was determined by fitting the layer using a Bruggeman Effective Medium Approximation (BEMA) of the three products plus voids. It was found that the thickness of the layer depends in the placement of the coupons, namely, inside or outside displayers. The average film thickness after 6 months was of 180 Å and 280 Å, inside and outside the displayers, respectively. The main compounds found in the layers were the silver chlorides and sulphides, which composition changed with the thickness of the layer, and the exposition time. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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This paper presents the design of a test rig for an all HTS linear synchronous motor. Although this motor showed to have several unattractive characteristics, its design raised a number of problems which must be considered in future HTS machines design. HTS electromagnetic properties led to the development of new paradigms in electrical machines and power systems, as e. g. in some cases iron removal and consequent assembly of lighter devices. This is due to superconductor's ability to carry high currents with minimum losses and consequent generation in the surrounding air of flux densities much higher than the allowed by ferromagnetic saturation. However, severe restrictions in HTS power devices design that goes further beyond cryogenic considerations must be accounted in. This is usually the case when BSCCO tapes are used as conductors. Its bending limitations and the presence of flux components perpendicular to tape surface, due to the absence of iron, have to be considered for it may turn some possible applications not so attractive or even practically unfeasible. An all HTS linear synchronous motor built by BSCCO tapes as armature conductors and two trapped-flux YBCO bulks in the mover was constructed and thrust force measurements are starting to be performed. Although the device presents severe restrictions due to the exposed and other reasons, it allowed systematising its design. A pulsed-field magnetiser to generate opposite fluxes for both YBCO bulks is also detailed. Thrust force numerical predictions were already derived and presented.

This paper presents the design of a test rig for an all HTS linear synchronous motor. Although this motor showed to have several unattractive characteristics, its design raised a number of problems which must be considered in future HTS machines design. HTS electromagnetic properties led to the development of new paradigms in electrical machines and power systems, as e. g. in some cases iron removal and consequent assembly of lighter devices. This is due to superconductor's ability to carry high currents with minimum losses and consequent generation in the surrounding air of flux densities much higher than the allowed by ferromagnetic saturation. However, severe restrictions in HTS power devices design that goes further beyond cryogenic considerations must be accounted in. This is usually the case when BSCCO tapes are used as conductors. Its bending limitations and the presence of flux components perpendicular to tape surface, due to the absence of iron, have to be considered for it may turn some possible applications not so attractive or even practically unfeasible. An all HTS linear synchronous motor built by BSCCO tapes as armature conductors and two trapped-flux YBCO bulks in the mover was constructed and thrust force measurements are starting to be performed. Although the device presents severe restrictions due to the exposed and other reasons, it allowed systematising its design. A pulsed-field magnetiser to generate opposite fluxes for both YBCO bulks is also detailed. Thrust force numerical predictions were already derived and presented.

This paper presents the design of a test rig for an all HTS linear synchronous motor. Although this motor showed to have several unattractive characteristics, its design raised a number of problems which must be considered in future HTS machines design. HTS electromagnetic properties led to the development of new paradigms in electrical machines and power systems, as e. g. in some cases iron removal and consequent assembly of lighter devices. This is due to superconductor's ability to carry high currents with minimum losses and consequent generation in the surrounding air of flux densities much higher than the allowed by ferromagnetic saturation. However, severe restrictions in HTS power devices design that goes further beyond cryogenic considerations must be accounted in. This is usually the case when BSCCO tapes are used as conductors. Its bending limitations and the presence of flux components perpendicular to tape surface, due to the absence of iron, have to be considered for it may turn some possible applications not so attractive or even practically unfeasible. An all HTS linear synchronous motor built by BSCCO tapes as armature conductors and two trapped-flux YBCO bulks in the mover was constructed and thrust force measurements are starting to be performed. Although the device presents severe restrictions due to the exposed and other reasons, it allowed systematising its design. A pulsed-field magnetiser to generate opposite fluxes for both YBCO bulks is also detailed. Thrust force numerical predictions were already derived and presented.

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The spread of systems that provide parallelism either ‘‘in-the-large’’ (grid infrastructures, clusters) or ‘‘in-the-small’’ (multi-core chips), creates new opportunities for exploiting parallelism in a wider spectrum of application domains. However, the increasing complexity of parallel and distributed platforms renders the programming, the use, and the management of these systems a costly endeavor that requires advanced expertise and skills. Therefore, there is an increasing need for powerful support tools and environments that will help end-users, application programmers, software engineers and system administrators to manage the increasing complexity of parallel and distributed platforms.

The spread of systems that provide parallelism either «in-the-large» (grid infrastructures, clusters) or «in-the-small» (multi-core chips), creates new opportunities for exploiting parallelism in a wider spectrum of application domains. However, the increasing complexity of parallel and distributed platforms renders the programming, the use, and the management of these systems a costly endeavor that requires advanced expertise and skills. Therefore, there is an increasing need for powerful support tools and environments that will help end-users, application programmers, software engineers and system administrators to manage the increasing complexity of parallel and distributed platforms.

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As organizações são concebidas com o enfoque principal na eficiência. As práticas de gestão que adoptam pressupõem, regra geral, a estabilidade do ambiente onde estão inseridas. Por isso, as organizações ficam vulneráveis aos distúrbios a que são sujeitas, e cuja frequência é cada vez maior, o que condiciona a sua eficiência, o seu nível de produtividade e, consequentemente, a sua competitividade. Porque existe uma relação de interdependência mais ou menos definida entre as organizações, a ocorrência de um distúrbio numa delas pode afectar todas as que dela dependem. É, por isso, fundamental que as organizações sejam mais resilientes, isto é, sejam capazes de reagir a um distúrbio inesperado, regressando rapidamente ao estado original ou a um melhor, após a cessação do distúrbio. Neste sentido, uma das acções que pode ser tomada é a definição de planos de mitigação e/ou de contingência. A adequação de planos, de mitigação e/ou de contingência, a implementar quando uma organização está perante um distúrbio, sendo por natureza uma actividade pró-activa, pressupõe a identificação dos distúrbios a que a organização pode ficar sujeita. Atendendo a que os distúrbios podem ter características muito diferentes, no que concerne à frequência de ocorrência, efeito crítico, nível de previsibilidade, área afectada na organização e duração, e podem, ainda, ter origem em fontes diversas, internas ou externas à organização produzidas pelo Homem ou pela Natureza, é fundamental que existam modelos que permitam a sua caracterização e a quantificação do grau de severidade das suas consequências para a organização onde incidem. É possível identificar na bibliografia modelos cujo desenvolvimento está associado aos distúrbios. Contudo, o âmbito em que são desenvolvidos é muito diverso. Nenhum deles, porém, permite caracterizar os distúrbios. O principal objectivo deste artigo é apresentar um modelo conceptual que permita caracterizar os distúrbios e avaliar a severidade dos seus efeitos para a organização onde incidem.

This paper addresses an implementation of the upper bound limit analysis theorem using a parallel mixed finite element formulation. The intrinsic characteristics of the adopted upper bound formulation proved to be suitable to adapt it to an efficient parallelization scheme. In order to illustrate the computational power provided by the new parallel processing method, accurate upper bound collapse load estimates, for 3D problems, are produced using a cluster of common PC machines.

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