The isoconversional methods (Friedman (FR), Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS)) were applied for evaluating the dependencies of the activation energy (E) on the mass loss (Δm) corresponding to the non-isothermal decomposition of two Zn acetate-based gel precursors for ZnO thin films whose preparation differs by the drying temperature of the liquid sol-precursor (125°C for sample A, and 150°C for sample B). Although both investigated samples exhibit similar decomposition steps, strong differences between E vs. Δm curves as well as among the characteristic parameters of the decomposition steps, directly evaluated from TG, DTG and DTA curves, were put in evidence. © 2007 Springer Science+Business Media LLC.

This paper presents a finite element model based on mathematical non-linear programming in order to determine upper bounds of colapse loads of a mechanical structure.The proposed formulation is derived within a kinematical approach framework, employing two simultaneous and independent field approximations for the velocity and strain rate fields. The augmented Lagrangian is used to establish the compatibility between these two fields. In this model, only continuous velocity fields are used.Uzawa's minimization algorithm is applied to determine the optimal kinematical field that minimizes the difference between external and dissipated work rate. The use of this technique allows to bypass the complexity of the non-linear aspects of the problem, since non-linearity is addressed as a set of small local subproblems of optimization for each finite element.The obtained model is quite versatile and suitable for solving a wide range of collapse problems. This paper studies 3D strut-and-tie structures, 2D plane strain/stress and 3D solid problems.

Here we describe an innovative optoelectronic platform which enables the specific detection of unamplified nucleic acid sequences with the integration of oligonucleotide-derivatized gold nanoparticles, a colour sensor and a light emission source for a colorimetric detection method. This new low cost, fast and simple optoelectronic platform permits detection of less than 1 picomole quantities of nucleic acid without target or signal amplification. ©2007 IEEE.

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{Let $X_i$ be i.i.d. r.v.s with heavy-tailed CDF $F(x)$ such that $$1-F(x)=(x/C)^{-1/\gamma}((1+(\beta/\rho)(x/C)^{\rho/\gamma} +\beta'(x/C)^{2\rho/\gamma}(1+o(1))),$$ where $\gamma$ is the tail index ($\gamma>0$), and $\rho<0$ and $\beta$ are the ``second order parameters''. The authors construct an estimator for $\beta$ based on the ``tail moments'' $$M_n^{(\alpha)}=(k)^{-1}\sum_{i=1}^k [łog X_{n-i+1:n}-łog X_{n-k:n}]^\alpha. $$ Consistency and asymptotic normality of the estimator are demonstrated. The small sample properties of the estimator are investigated via simulations.}

In this work, the optical and structural properties of high k materials such as tantalum oxide and titanium oxide were studied by spectroscopic ellipsometry, where a Tauc-Lorentz dispersion model based in one (amorphous films) or two oscillators (microcrystalline films) was used. The samples were deposited at room temperature by radio frequency magnetron sputtering and then annealed at temperatures from 100 to 500 °C. Concerning the tantalum oxide films, the increase of the annealing temperature, up to 500 °C does not change the amorphous nature of the films, increasing, however, their density. The same does not happen with the titanium oxide films that are microcrystalline, even when deposited at room temperature. Data concerning the use of a four-layer model based on one and two Tauc-Lorentz dispersions is also discussed, emphasizing its use for the detection of an amorphous incubation layer, normally present on microcrystalline films grown by sputtering. © 2006 Elsevier B.V. All rights reserved.

Thin films of indium molybdenum oxide (IMO) were rf sputtered onto glass substrates at room temperature. The films were studied as a function of sputtering power (ranging 40-180 W) and sputtering time (ranging 2.5-20 min). Thickness of the films found varied between 50-400 nm. The films were characterized for their structural (XRD), electrical (Hall measurements) and optical (Transmittance spectra) properties. XRD studies revealed that the films are amorphous for the sputtering power ≤ 100 W and deposition time ≤ 5 min. All the other films are polycrystalline and the strongest refection along (222) plane showing a preferential orientation. A minimum bulk resistivity of 2.65 × 10-3 Ω-cm and a maximum carrier concentration of 4.16 × 1020 cm-3 have been obtained for the films sputtered at 180 W (10 min). Whereas maximum mobility (19.5 cm2 V-1 s-1) has been obtained for the films sputtered at 80 W (10 min). A maximum visible transmittance of 90% (500 nm) has been obtained for the films sputtered at 80 W (10 min) with a minimum of 27% for those sputtered at 180 W. The optical band gap of the films found varying between 3.75 and 3.90 eV for various sputtering parameters. © 2006 Materials Research Society.

This work focuses on the role of the native oxide layer (SiO2) on the nickel (Ni)-assisted crystallization of amorphous silicon (a-Si). In some samples, the native oxide was removed using a HF-diluted solution before Ni layers with 0.5 nm be deposited on a-Si. The results show that the presence of a thin SiO2 layer of about 3 nm between the a-Si and the Ni delays the crystallization process. Ellipsometry data show that, after annealing for 5 h at 500 °C, the HF-cleaned sample presents a crystalline fraction of 88%, while the one with the native oxide has only 35%. This difference disappears after 20 h where both samples present similar crystalline fraction. These facts are also reflected on the film's electrical properties, where the activation energy for samples annealed for 5 h rises from 0.42 eV to 0.55 eV, when the oxide layer is removed. After 20 h and 30 h, the activation energy is around 0.55 eV for both kinds of samples, meaning that films with similar electrical properties are now obtained. However, the XRD data suggest the presence of some structural differences attributed to slight differences on the crystallization process. © 2005 Elsevier B.V. All rights reserved.

Total hip replacement is a common practice in every day clinical work. Artificial hip implants consist of a femoral component and an acetabular component. Nowadays the acetabular component is composed of a polymeric cup and a metallic shell. This study focuses the development of an innovative acetabular component substituting the metallic shell by a multilayer coating on the acetabular cup. A titanium coating was deposited onto ultra-high molecular weight polyethylene (UHMWPE) samples by physical vapour deposition (PVD), having an in situ pre-treatment with argon ion bombardment in order to optimize the adhesive strength by surface modification, followed by the deposition of a thin film of hydroxyapatite (HA) using rf magnetron sputtering technique, at room temperature. Results obtained seem to indicate that these multilayer coatings can be a viable alternative to the metallic shell, leading to the substitution of a two part for a one part acetabular component.

The paper reports experimental and numerical simulation of ballistic impact problems on thin composite laminated plates reinforced with Kevlar 29. Ballistic impact was imparted with simulated fragments designed in accordance with STANAG-2920 on plates of different thickness. Numerical modelling was developed and used to obtain an estimate for the limit perforation velocity V50 and simulate failure modes and damage. Computations were carried out using a commercial code based on nite differences and values obtained are compared with the experimental data to evaluate the performance of the simulation. Good correlation between computational simulation and experimental results was achieved, both in terms of deformation and damage of the laminates. Future work is advanced to include the interposition of an outer ceramic layer as well as examining the influence of dry-wet and temperature cycles on the mechanical strength of the plates and their temporal evolution under accelerated ageing.