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This paper is a synthesis of an Educational Sciences’ doctoral thesis in Technology, Networks, and Multimedia in Education and Training. The thesis’ main goal was to conceive, propose, implement and compare the design of four teachers’ workshop in distance e-Learning, about the potential of tangible and virtual robotics for students with special educational needs. The study was divided into three distinct phases, distributed over three academic years, from 2013 to 2016. The methodology adopted was mixed and based on a Design-based Research model approach. The participants were 74 teachers teaching in Portugal and Brazil. The results indicated that virtual robotics workshops had the highest enrolment and the lowest withdrawal rate among the participants. Keywords: Educational robotics; Special Educational Needs; Inclusive education; Teachers’ training; Design-based Research.

{\textless}p{\textgreater}Opto-electronics on/with paper is fostering a novel generation of flexible and recyclable devices for sunlight harvesting and intelligent optical sensing.{\textless}/p{\textgreater}

In this work, we highlight the influence of three different sol stabilizers, namely diethanolamine (DEA), Ammonium Hydroxide (NH4OH), and Nitric Acid (HNO3), on the optical and structural properties of spin-coated zinc oxide (ZnO) thin films. The XRD patterns related to all films exhibit a hexagonal crystal structure with a preferential orientation along the (0 0 2) direction. However an additional {\textless}100{\textgreater} peak arises when the films are prepared with DEA and NH4OH showing a better crystallinity than that displayed by HNO3-prepared films. The elaborated films show a high transparency reaching 80{%} for DEA-prepared films. The analysis of the transmittance and the reflectance measurements confirms a direct band-to-band transition. Depending on the sol stabilizer, the optical band gap energy is varying from 3.16 to 3.22 eV. The relatively wide band-gap of DEA-prepared ZnO films is correlated to their high crystallinity. Room temperature photoluminescence spectra indicate strong UV emission at around 377 nm originated from nearby band-edge transitions. Yet, the use of DEA as a stabilizer leads to a net intensity increase of the blue peak emission.

Semiconductor nanowires are mostly processed by complex, expensive and high temperature methods. In this work, with the intent of developing zinc tin oxide nanowires (ZTO NWs) by low-cost and low-complexity processes, we show a detailed study on the influence of chemical parameters in the hydrothermal synthesis of ZTO nanostructures at temperatures of only 200 °C. Two different zinc precursors, the ratio between zinc and tin precursors, the concentration of the surfactant agent and of the mineralizer were studied. The type and the crystallinity of the nanostructures was found to be highly dependent on the used precursors and on the concentration of each reagent. Conditions for obtaining different ZTO nanostructures were achieved, namely Zn2SnO4 nanoparticles and ZnSnO3 nanowires with length ≈ 600 nm, with the latter being reported for the first time ever by hydrothermal methods without the use of seed layers. Optical and electrical properties were analyzed, being obtained band gaps of 3.60 and 3.46 eV, fo...

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This paper deals with the experimental and theoretical evaluation of punching shear capacity of steel fiber reinforced concrete (SFRC) slab–column connections. Five experimental specimens with a thickness of 160 mm, different fiber volume contents (0, 1.0, and 1.5%) and different flexural reinforcement ratios (0.75 and 1.5%) have been tested. The experimental results were evaluated using a physical–mechanical model based on the critical shear crack theory (CSCT). The model has given a good approximation of experimental punching shear strengths. In general, tests have highlighted a significant increase in load and deformation capacity of fiber reinforced concrete slab–column connections in comparison with reinforced concrete connections.

The p53 tumor suppressor is widely found to be mutated in human cancer. This protein is regarded as a molecular hub regulating different cell responses, namely cell death. Compelling data have demonstrated that the impairment of p53 activity correlates with tumor development and maintenance. For these reasons, the reactivation of p53 function is regarded as a promising strategy to halt cancer. In the present work, the recombinant mutant p53R280K DNA binding domain (DBD) was produced for the first time, and its crystal structure was determined in the absence of DNA to a resolution of 2.0 Å. The solved structure contains four molecules in the asymmetric unit, four zinc(II) ions, and 336 water molecules. The structure was compared with the wild-type p53 DBD structure, isolated and in complex with DNA. These comparisons contributed to a deeper understanding of the mutant p53R280K structure, as well as the loss of DNA binding related to halted transcriptional activity. The structural information derived may also contribute to the rational design of mutant p53 reactivating molecules with potential application in cancer treatment.

This paper uses the combinatorics of Young tableaux to prove the plactic monoid of infinite rank does not satisfy a non-trivial identity, by showing that the plactic monoid of rank n cannot satisfy a non-trivial identity of length less than or equal to n. A new identity is then proven to hold for the monoid of n×n upper-triangular tropical matrices. Finally, a straightforward embedding is exhibited of the plactic monoid of rank 3 into the direct product of two copies of the monoid of 3×3 upper-triangular tropical matrices, giving a new proof that the plactic monoid of rank 3 satisfies a non-trivial identity.