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2004
Lapa, N., J. Morais, C. Borges, B. Mendes, and J. F. Santos Oliveira. "An integrated approach to assess the biodegradability of a wastewater containing chromium by using chemical and biological methods." Global Symposium on Recycling, Waste Treatment and Clean Technology, REWAS’2004. Eds. I. Gaballah, B. Mishra, R. Solozabal, and M. Tanaka. San Sebastián: TMS/INASMET, 2004. 1351-1362. Abstractrewas04_lapa_et_al.pdf

The Water Company of the North Alentejo (Águas do Norte Alentejano) (Portugal) has decided to implement a treatment plant to treat an urban wastewater with a significant influence of tannery effluents. The design of the wastewater treatment plant was attributed to a consortium coordinated by Sisaqua Company. Since the levels of the biodegradability and toxicity of the wastewater to be treated were unknown, Sisaqua Company asked the New University of Lisboa to develop and execute a monitoring plan to define the chemical composition and the levels of the biodegradability and toxicity of the wastewater.
A composite sampling procedure of the wastewater was performed during a daily working cycle of the tanneries. The composite sample was characterized for 19 chemical parameters. Five of these parameters were total Cr, Cr (VI), Zn, Cu and Al, which were determined in the dissolved and suspended fractions. The composite sample was also submitted to a biological test to assess its biodegradability degree. This assay was performed according to the methodology indicated in the test 301E of OECD [1], taking into account the amendment of 1992. A respirometric assay was carried out, to assess the toxic effect of the composite sample on the biological populations involved in the biological stabilization of organic compounds. This assay followed the “Sapromat” methodology developed by Brabander and Vandeputte [2]. Finally, the composite sample was submitted to a coagulation-flocculation process according to the methodologies proposed by Eckenfelder [3, 4] and Pereira [5]. The supernatants were characterized for the same chemical and biological parameters as it was described for the composite sample.
It was possible to conclude that the high levels of Cr present in the composite wastewater were mainly in the trivalent oxidation state. Since this oxidation state is less toxic for biological populations than the Cr (VI) and this metal was mainly in the suspended fraction, it was possible to obtain a biodegradability of the organic compounds quite similar to those observed for domestic wastewaters. The toxicity determined by the “Sapromat” method was slightly higher than those determined for domestic wastewaters. Nevertheless, this toxicity did not affect significantly the wastewater biodegradability. The Cr (III) was easily removed by a chemical coagulation-flocculation process.

Ramos, Luís, Manuela Oliveira, João T. Mexia, and Christoph. Minder. "Models for series of studies with r-order common structure: application to European Union Integration." Proceedings of Summer School DATASTAT03. 15. 2004. 273-278.
Viteva, L., T. Gospodova, Y. Stefanovsky, K. T. Petrova, I. Timtcheva, M. - R. Mazières, and J. - G. Wolf. "Organometalics in the Cyanine Chemistry. Synthesis, Reactivity and Photophysical Properties of some Heptamethine Merocyanine Dyes." Eur. J. Org. Chem.2 (2004): 385-394. DOI: 10.1002/ejoc.200300446.
Cunha, P. P., O. Mateus, and MT Antunes. "The sedimentology of the Paimogo dinosaur nest site (Portugal, Upper Jurassic)." 23 rd IAS Meeting of Sedimentology. Coimbra, Portugal 2004. 93. Abstractcunha_p_p_2004_-_the_sedimentology_of_the_paimogo_dinosaur_nest_site_portugal10467.pdf

Sedimentological features of the Paimogo site, 6 km NNW of Lourinhã, western central Portugal are presented. More than one hundred theropod dinosaur eggs (some containing embryo bones) ascribed to Lourinhanosaurus antunesi Mateus 1998, three crocodilian eggs and some other fossils were found at the 32 m2 excavated area of the egg-bearing horizon (Mateus et al., 1998). The stratigraphic position of the site is the Praia Azul member (Lourinhã Formation), roughly corresponding to the Kimmeridgian-Tithonian boundary or, more likely lowermost Tithonian. The maximum flooding surface of the basinal transgressive event where the horizon is located corresponds to the base of the H depositional sequence defined by Pena dos Reis et al. (2000) and probably correlates to the base of sequence Ti1 identified within western European basins (Jacquin et al., 1998), dated as 150 Ma. Possibly during the normal river discharge, the theropods congregated in nesting colonies at the backswamp of an extensive flood plain with small meandering channels and freshwater ponds. There are no evidences that the nest was dug or the eggs buried. The eggs have probably been laid on a flat, shaded, muddy area near the bank of a large pond. It is probable that the eggs have not been actively incubated. The larger number of eggs suggest that they were laid near simultaneously by, at least, six females. The fossil record shows that crocodilians, mammals, gastropods and fish were also present. A flood event occurred when theropod embryos had attained a late stade of ontogenetic development, probably just before hatching. The overflow from a nearby channel flooded the plain, including the area where the eggs had been laid. The sheet flood flowing over the nest resulted into the scattering and breaking up of some dinosaur eggs. Eggshell and embryos skeletal parts fragments were displaced to an adjacent area where, due to hydrodynamic decline, the flow submerged other clutches and moderately dragged their eggs. The flooding caused the drowning of the embryos and covered the eggs with fine-grained sediment, hiding them from predators and scavengers. Hydrodynamic interpretation of the arrangement of the theropod eggs and egg-fragments suggests that the flow came from the NW. When the floodwaters receded, the fine-grained deposits became exposed to subaerial weathering. Although the sediment surface was often wet and small bodies of standing water may still have existed, the sediments were oxidized and plant remains have consequently been destroyed. Some carbonate cementation and redenning resulted from pedogenesis under alternating dry and moist conditions, in a semiarid/ sub-tropical climate under seasonal changing, contrasting conditions. The thick, stratigraphically above and below the nesting horizon mudrocks indicate a long persistence of periodic flooding, alternating with pedogenesis. During the early stages of diagenesis, vertical pressure crushed the eggs. Silt penetration into the inner part of each egg inhibited later flattening during the burial process.

Mulzer J., Pichlmair S., Green Marques Martin M. P. M. M. B. "Toward the synthesis of the carbacylic ansa antibiotic kendomycin." Proc. Natl. Acad. Sci. U. S. A.. 101 (2004): 11980-11985.
Musat, V. a, B. b Teixeira, E. b Fortunato, R. C. C. b Monteiro, and P. c Vilarinho. "Al-doped ZnO thin films by sol-gel method." Surface and Coatings Technology. 180-181 (2004): 659-662. AbstractWebsite

Transparent and conductive high preferential c-axis oriented ZnO thin films doped with Al have been prepared by sol-gel method using zinc acetate and aluminium chloride as cations source, 2-methoxiethanol as solvent and monoethanolamine as sol stabilizer. Film deposition was performed by dip-coating technique at a withdrawal rate of 1.5 cm min-1 on Corning 1737 glass substrate. The effect of dopant concentration, heating treatment and annealing in reducing atmosphere on the microstructure as well as on the electrical and optical properties of the thin films is discussed. The optical transmittance spectra of the films showed a very good transmittance, between 85 and 95%, within the visible wavelength region. The minimum resistivity of 1.3 × 10-3 Ω cm was obtained for the film doped with 2 wt.% Al, preheated at 400 °C and post-heated at 600 °C, after annealing under a reduced atmosphere of forming gas. © 2003 Elsevier B.V. All rights reserved.

Moura Ramos, Joaquim J., Hermínio P. Diogo, Maria Helena Godinho, Carlos Cruz, and Katarzyna Merkel. "Anomalous thermal behavior of salicylsalicylic acid and evidence for a monotropic transition to a nematic phase." The Journal of Physical Chemistry B. 108.23 (2004): 7955-7962. Abstract
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Bursakov, SA, OY Gavel, G. Di Rocco, J. Lampreia, J. Calvete, AS Pereira, JJG Moura, and I. Moura. "Antagonists Mo and Cu in a heterometallic cluster present on a novel protein (orange protein) isolated from Desulfovibrio gigas." Journal of Inorganic Biochemistry. 98 (2004): 833-840. AbstractWebsite

An orange-coloured protein (ORP) isolated from Desulfovibrio gigas, a sulphate reducer, has been previously shown by extended X-ray absorption fine structure (EXAFS) to contain a novel mixed-metal sulphide cluster of the type [S2MoS2CuS2MoS2] [J. Am. Chem. Soc. 122 (2000) 8321]. We report here the purification and the biochemical/spectroscopic characterisation of this novel protein. ORP is a soluble monomeric protein (11.8 kDa). The cluster is non-covalently bound to the polypeptide chain. The presence of a MoS42- moiety in the structure of the cofactor contributes with a quite characteristic UV-Vis spectra, exhibiting an orange colour, with intense absorption peaks at 480 and 338 nm. Pure ORP reveals an Abs(480)/Abs(338) ratio of 0.535. The gene sequence coding for ORP as well as the amino acid sequence was determined. The putative biological function of ORP is discussed. (C) 2003 Elsevier Inc. All rights reserved.

Mei, S.a, Yang Ferreira Martins J. a J. M. "Aqueous tape casting of low-k cordierite substrate: The influence of glass content." Materials Science Forum. 455-456 (2004): 168-171. AbstractWebsite

Thick films of cordierite-based glass ceramics were prepared by aqueous tape casting from suspensions containing 80-wt% solids. The weight proportions of cordierite/glass ranged from 70/30 to 30/70 in order to investigate the effect of glass content on the rheological behaviour and on the microstructures and properties of the green tapes. Suspensions with 50 to 60-wt% glass content exhibited the lowest viscosity values among all the slurries investigated, while the green tape containing 30-wt% glass presented homogenous microstructures at both top and bottom surfaces, contrarily to the observations for the other compositions. The green densities increased with glass content. The sintered tapes (1150°C, 2h) containing 50 to 60-wt% glass exhibited the lowest values for the dielectric constant (∼5.2) and dielectric loss (∼0.002) at 1MHz.

Pereira, LuÍs, Isabel Ferreira, Rodrigo Martins, Hugo Águas, Elvira Fortunato, and Leandro Raniero. "Batch Processing Method to Deposit a-Si: H Films by PECVD." Materials Science Forum. 455 (2004): 104-107. Abstract
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Raniero, Leandro, Hugo Águas, Lu{\'ıs Pereira, Elvira Fortunato, Isabel Ferreira, and Rodrigo Martins. "Batch processing method to deposit a-Si: H films by PECVD." Materials Science Forum. Vol. 455. Trans Tech Publications, 2004. 104-107. Abstract
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Igreja, R., C. J. Dias, R. Martins, E. Fortunato, I. Ferreira, and C. Dias. "Capacitance response of polysiloxane films with interdigital electrodes to volatile organic compounds." Advanced Materials Forum Ii. Vol. 455-456. 2004. 420-424. Abstract
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Igreja, R., and C. J. Dias. "Capacitance response of polysiloxane films with interdigital electrodes to volatile organic compounds." Advanced Materials Forum Ii. Eds. R. Martins, E. Fortunato, I. Ferreira, and C. Dias. Vol. 455-456. Materials Science Forum, 455-456. 2004. 420-424. Abstract
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Igreja, R., C. J. Dias, R. Martins, E. Fortunato, I. Ferreira, and C. Dias. "Capacitance response of polysiloxane films with interdigital electrodes to volatile organic compounds." Advanced Materials Forum Ii. Vol. 455-456. 2004. 420-424. Abstract
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Zhang, S., L. Raniero, E. Fortunato, L. Pereira, N. Martins, P. Canhola, I. Ferreira, N. Nedev, H. Águas, and R. Martins. "Characterization of silicon carbide thin films prepared by VHF-PECVD technology." Journal of non-crystalline solids. 338 (2004): 530-533. Abstract
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Zhang, S., L. Raniero, E. Fortunato, L. Pereira, N. Martins, P. Canhola, I. Ferreira, N. Nedev, H. Aguas, and R. Martins. "Characterization of silicon carbide thin films prepared by VHF-PECVD technology." Journal of non-crystalline solids. 338 (2004): 530-533. Abstract
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Raniero, L., L. Pereira, Shibin Zhang, I. Ferreira, H. Águas, E. Fortunato, and R. Martins. "Characterization of the density of states of polymorphous silicon films produced at 13.56 and 27.12 MHz using CPM and SCLC techniques." Journal of non-crystalline solids. 338 (2004): 206-210. Abstract
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Raniero, L., L. Pereira, Shibin Zhang, I. Ferreira, H. Águas, E. Fortunato, and R. Martins. "Characterization of the density of states of polymorphous silicon films produced at 13.56 and 27.12 MHz using CPM and SCLC techniques." Journal of non-crystalline solids. 338 (2004): 206-210. Abstract
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Lanca, M. C., E. R. Neagu, J. N. Marat-Mendes, and Ieee Comparative study of space charge in aged low-density polyethylene and crosslinked polyethylene., 2004. AbstractWebsite

Polyethylene is one of the most widely used polymeric insulators in medium and high voltage power cables. However the importance of space charge distribution and its influence on the electrical aging in this polymer is not fully understood. The very good insulating properties of the material implying very long relaxation times (few days and even longer are usual) and low currents (few pA or below) make individual measurements of isothermal charge/discharge currents and thermostimulated currents difficult to analyze and reproduce. A single type of measurements does not take into account the space charge that remains trapped for long times. A combined procedure of isothermal and non-isothermal current measurements developed for high insulating polymers was used for low density polyethylene (LDPE) and crosslinked polyethylene (XLPE) films electrically aged. The press-molded LDPE and XLPE films were electrically aged under similar conditions using an AC electric field while immersed in a sodium chloride aqueous solution at constant temperature (electro-thermal aging). The use of the combined procedure for current measurement allowed obtaining information about space charge traps, activation energies and relaxation times for both LDPE and XLPE. This data was used to compare electrical aging under similar conditions for the two types of polyethylene.

Lanca, M. C., E. R. Neagu, J. N. Marat-Mendes, and Ieee Comparative study of space charge in aged low-density polyethylene and crosslinked polyethylene., 2004. AbstractWebsite

Polyethylene is one of the most widely used polymeric insulators in medium and high voltage power cables. However the importance of space charge distribution and its influence on the electrical aging in this polymer is not fully understood. The very good insulating properties of the material implying very long relaxation times (few days and even longer are usual) and low currents (few pA or below) make individual measurements of isothermal charge/discharge currents and thermostimulated currents difficult to analyze and reproduce. A single type of measurements does not take into account the space charge that remains trapped for long times. A combined procedure of isothermal and non-isothermal current measurements developed for high insulating polymers was used for low density polyethylene (LDPE) and crosslinked polyethylene (XLPE) films electrically aged. The press-molded LDPE and XLPE films were electrically aged under similar conditions using an AC electric field while immersed in a sodium chloride aqueous solution at constant temperature (electro-thermal aging). The use of the combined procedure for current measurement allowed obtaining information about space charge traps, activation energies and relaxation times for both LDPE and XLPE. This data was used to compare electrical aging under similar conditions for the two types of polyethylene.

Ferreira, Isabel, Rodrigo Martins, Pere Roca i Cabarrocas, Hugo Águas, Elvira Fortunato, and Leandro Raniero. "Composition, Structure and Optical Characteristics of Polymorphous Silicon Films Deposited by PECVD at 27.12 MHz." Materials Science Forum. 455 (2004): 100-103. Abstract
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i Martins, R.a, Águas Ferreira Fortunato Raniero Roca Cabarrocas H. a I. a. "Composition, structure and optical characteristics of polymorphous silicon films deposited by PECVD at 27.12 MHz." Materials Science Forum. 455-456 (2004): 100-103. AbstractWebsite

This paper presents data concerning the composition structure and optical characteristics of polymorphous silicon films produced by plasma enhanced chemical vapour deposition at 27.12 MHz and determined respectively by infrared spectrometry, micro Raman, exodiffusion and spectroscopic ellipsometry measurements. When compared to the pm-Si:H films produced at 13.56 MHz, the films produced at 27.12 MHz present hydrogen contents in the range of 21 at%, the sharp peak ascribed to the exodifusion measurements is shifted towards high temperatures and the imaginary part of the dielectric function 〈ε2〉 is larger and shifted to high energies. Apart from that the peaks of the infrared spectra ascribed to the stretching modes shift towards high wave numbers and the half width of the micro Raman peaks shrinks, meaning that the films produced at 27.12 MHz are more compact and dense.

Martins, Rodrigo, Hugo Águas, Isabel Ferreira, Elvira Fortunato, Leandro Raniero, and Pere Roca i Cabarrocas. "Composition, structure and optical characteristics of polymorphous silicon films deposited by PECVD at 27.12 MHz." Materials Science Forum. Vol. 455. Trans Tech Publications, 2004. 100-103. Abstract
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Cadima, J., J. O. Cerdeira, and M. Minhoto. "Computational aspects of algorithms for variable selection in the context of principal components." Computational Statistics and Data Analysis. 47 (2004): 225-236. Abstract
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