The façades of St. Leonard’s church and the castle in Atouguia da Baleia village in western region of Portugal are monuments built in Middle Ages. Significant stone degradation patterns are visible, being the alveolization an outstanding case study.The more porous type of sandstones similar to the variety found in the vernacular architecture of Atouguia da Baleia was treated with ethyl silicates. In order to allow the study of the durability of these conservation treatments, accelerated artificial ageing salt crystallization tests were carried out and an automatic ageing chamber was developed.Physical and mechanical behaviour was assessed on consolidated specimens before and after accelerated artificial ageing salt crystallization tests. The authors propose a prediction of the durability of these consolidation treatments by means of the salt crystallization ageing results.

Neste artigo é apresentado um resumo das intervenções de conservação realizadas no século passado na Igreja de São Leonardo, bem como um resumo dos estudos realizados na última década. Em seguida mostra-se o padrão de degradação que ocorre nos portais de arenito da igreja e é analisada a evolução da alveolização que ocorreu nos portais de arenito ao longo dos últimos sessenta a setenta anos. No final, a inspeção visual dos portais de arenito é comparada com um levantamento realizado através de varrimento por laser tridimensional.

In this work we present a fully automated plasma-enhanced reactive thermal evaporation system (rf-PERTE) that can be used for the deposition of transparent metal oxide films without intentional heating of the substrate. The system and developed software enables the full control over critical deposition conditions such as mass flow of oxygen, process pressure, current flowing through crucible and rf-power. These parameters are automatically adjusted during the deposition thus keeping them in a narrow process window. This way, highly transparent and conductive coating can be deposited with a high degree of reproducibility of the optical and electrical characteristics. The resistivity of 9×10^-4 Ω-cm and the peak transmittance of 90% in the visible spectral range were achieved for indium oxide films deposited on glass substrates. This technique is also suitable for the deposition of transparent conducting coatings in a wide range of plastic materials for flexible solar cells. In particular, we have successfully deposited indium oxide on PEN (polyethylene naphtalate) sheets with electrical and optical properties approaching the ones for films on glass.

© 2016, Springer-Verlag Berlin Heidelberg.The glaze and in-glaze pigments of the historical nineteenth-century glazed tiles from the Pena National Palace (Sintra, Portugal) were characterized using a multi-analytical approach. Chemical composition and microstructural characterization were ascertained by µ-PIXE, µ-Raman, optical microscopy and VP-SEM–EDS. The manufacturing technique and colour palette in these tiles were found to be close to the ceramic pigments used in traditional majolica. The blue and purple colours derive from cobalt oxide and manganese oxide, respectively. A mixture of Pb–Sn–Sb yellow with cobalt oxide and iron oxide was used for green and dark yellow, respectively, while grey tonalities consist of a complex mixture of cobalt oxide, manganese oxide and Pb–Sn–Sb yellow in different proportions. Results obtained allowed the determination of the oxides and elements used in pigments as well as production techniques, resorting to traditional majolica manufacture, although the tiles were produced by the end of the nineteenth century.

Punching-shear capacity of slab-column connections in existing R/C structures may be inadequate to bear design loads, so strengthening works are required. The lack of punching resistance may be due to detailing, design or building errors; in other cases, such lack is due to a change of use, which requires an increase of resistance. Different techniques have been developed for strengthening R/C slabs against punching: enlargement of the support, gluing external fibre reinforced polymers or casting a bonded concrete overlay (BCO) on the slab's top surface, insertion of post-installed steel bolts, application of fibre reinforced polymers cords as shear reinforcement. In the paper, the authors apply the Critical Shear Crack Theory (CSCT) to all of these techniques and evaluate their efficacy with reference to a case study.

The work reported here addresses load matching improvement in Net Zero Energy Buildings (Net-ZEBs). The related relevant literature shows that currently research work is mainly focused on improving the load matching of individual buildings. In this paper the concept of a Cooperative Net Zero Energy Community (CNet-ZEC) is introduced, extending discussion to the enhancement of load matching at a wider community level. Both building and community levels are compared in order to assess the work proposed here, through the analysis of three distinct scenarios where five Net-ZEBs work individually or in community.

The results presented here were obtained through a detailed simulation based on 1-min resolution stochastic load profiles and recorded weather data. The results indicate that over the period of a year the CNet-ZEC has the potential to increase the electrical demand covered by onsite electricity generation up to 21% and the on-site generation that is used by the building up to 15%. The following elements are considered by the CNet-ZEC in order to produce those results: (i) demand heterogeneity of the buildings integrating the community; (ii) the higher number of controllable devices; and (iii) the potential higher amount of energy available to satisfy the community demand.

An alternative technique for production of devices which uses both silicon crystalline wafers (p-type) and heavy doped amorphous silicon thin films (n-type) is reported. The amorphous silicon acts as a finite source of dopant and is deposited (at low temperature, 70 °C) by plasma enhanced chemical vapor deposition on silicon wafers. Afterwards, the process of dopant diffusion into the crystalline silicon occurs in a diffusion furnace at 1000 °C for 2 h, to create p–n junctions. Using SIMS analyses, a dopant (P) transfer into c-Si of about 30% is verified and 87% of the dopant transferred is electrically active. Consequently, n-MOSFET devices are produced using a gate oxide thermally grown at the same diffusion temperature for one hour. The preliminary results of the MOSFET (channel length and width of 0.5 and 5 mm, respectively) show a depletion behavior with a threshold voltage, Vth=−8.2 V and afield-effect mobility, µ_FE=187.8 cm²/(Vs).

n/a

n/a

© 2016 Elsevier B.V. All rights reserved.Different glasses based on the ZnO-B2O3-SiO2 system, with a ZnO content ≥ 60 mol{%} and a fixed SiO2 content (20 mol{%}), were synthesised using a melt-quenching method. Glass samples with zinc oxide concentrations as high as 65 mol{%} were prepared successfully without deteriorating the glass-forming ability. The glass samples were submitted to controlled heat-treatments, and the effect of the ZnO/B2O3 molar ratio on the formation of crystalline phases within the glass matrix was investigated by means of differential thermal analysis (DTA), X-ray diffraction (XRD) and scanning electron microscopy (SEM). DTA results indicated that the glass transition and the onset crystallization temperatures of the studied glasses tended to increase with the increment on the ZnO/B2O3 ratio. XRD data showed that the zinc binary crystalline phases, willemite (Zn2SiO4), a zinc orthosilicate, and zinc borate (Zn3B2O6) could be present in the crystallized glasses, depending on the heat-treatment conditions. The formation of willemite was promoted by an increasing ZnO/B2O3 ratio. Microstructural observations performed by SEM indicated that under controlled experimental parameters (glass composition, heat-treatment temperature and time) the precipitation of nanocrystals within the glass matrix can be achieved, resulting in transparent and translucent willemite glass-ceramics.

We compute the generalized Cauchy index of some semi-almost periodic functions, which are important
in the study of the Fredholm index of singular integral operators with shifts and slowly oscillating data.

A importância do papel do Arquiteto-urbanista na caracterização dos conceitos e no planejamento das Smart Cities é um tema com muito por estudar e desenvolver. Este artigo faz uma aproximação a esta questão através de análise crítica com a seguinte abordagem: 1 - é feita uma descrição mais detalhada do porquê deste trabalho de investigação; 2 – apresenta-se uma contextualização da transição dos cenários; 3 - é levantada a problematização e a identificação de alguns motivos do “desenquadramento” da atuação do arquiteto-urbanista na cena; 4 – são discutidos aspectos e elencadas algumas características para “(re)enquadramento” dentro do cenário ideal, 5 – são analisados alguns casos de estudo; 6 - são tecidas conclusões. Este artigo mostra, portanto, o resultado deste estudo comparativo entre panorama atual e desejado, considerando este último como o cenário conceitual. É inicialmente caracterizada a situação atual através de levantamento da crítica especializada, depois é descrita a situação desejada tendo como base a análise de quatro casos de estudo; sendo dois de Smart Cities construídas a partir do zero e dois de cidade existentes que estão sendo transformadas em Smart Cities. Por fim, são identificados elementos que contribuem, na opinião dos autores, para o reassumir do papel do arquiteto-urbanista. Com este trabalho, foi possível, de uma forma sistematizada, estudar e suscitar ações deficitárias na atuação dos arquitetos-urbanistas, como também descortinar potenciais ações que podem induzir e reverter a transformação do cenário atual. Ficou claro que as necessidades intrínsecas ao novo modelo de cidade exigem ainda mais proposições criativas. O delinear das futuras cenas seria então ideal se os arquitetos-urbanistas retomassem posicionamento crítico propositivo e o utilizassem na solução que imagina novas e condizentes maneiras de habitar o espaço. O prelúdio já delineado convida então, os protagonistas na produção do espaço a alforriar-se da inércia, saindo da condição de espectadores e passando a condição de entendedores antecipados do cenário.

© 2016 Taylor {&} Francis.A laboratory-based methodology was designed to assess the bioreceptivity of glazed tiles. The experimental set-up consisted of multiple steps: manufacturing of pristine and artificially aged glazed tiles, enrichment of phototrophic microorganisms, inoculation of phototrophs on glazed tiles, incubation under optimal conditions and quantification of biomass. In addition, tile intrinsic properties were assessed to determine which material properties contributed to tile bioreceptivity. Biofilm growth and biomass were appraised by digital image analysis, colorimetry and chlorophyll a analysis. SEM, micro-Raman and micro-particle induced X-ray emission analyses were carried out to investigate the biodeteriorating potential of phototrophic microorganisms on the glazed tiles. This practical and multidisciplinary approach showed that the accelerated colonization conditions allowed different types of tile bioreceptivity to be distinguished and to be related to precise characteristics of the material. Aged tiles showed higher bioreceptivity than pristine tiles due to their higher capillarity and permeability. Moreover, biophysical deterioration caused by chasmoendolithic growth was observed on colonized tile surfaces.

This study focuses on the assessment of the degradation processes occurring in three sandstone infills of fossilized Late Jurassic ornithopod tridactyl footprints, found in 2001 in a coastline cliff in Porto das Barcas (Lourinhã, Portugal) and exhibited in a museum display since 2004. These dinosaur footprints present nowadays severe decay phenomena compromising their physical integrity and are leading gradually to their loss of value. The deterioration patterns were recorded, a map of their distribution was prepared and several samples were collected both in the dinosaur footprints and in the coastline cliff. Different analytical procedures were applied such as XRD, FTIR, FESEM and Ion Chromatography. A microclimatic survey was also performed and air temperature and relative humidity was measured during eight months both indoor and also outdoor. The decay patterns observed are a combination intrinsic and extrinsic factors the stone material, namely swelling of clay minerals in the rock matrix (smectite and chlorite-smectite mixed-layer), presence of salts (mainly chlorides), application of past conservation treatments (poly(vinyl) acetate and epoxy resins) and with the museum's indoor thermohygrometric conditions (mainly non-stable hygrometric conditions). This scientific knowledge is therefore essential to the sustainable preservation of this paleontological heritage.

Games are commonly appointed as a methodological tool capable of promoting students’ effective learning. In this context, this study intends to analyze the impact of mathematical discussions developed while
playing a polynomial game. Namely it intends to analyze the impact on the consolidation of mathematical concepts previously worked in the classroom and on the communications skills. Two case studies where developed involving 10th grade students. Data gathering was based on direct observation and an inquiry. The main conclusions suggest that the game encouraged the discussion about the mathematical contents and therefore promoted the development of the mathematical discourse. Besides that, it allowed a deeper apprehension of mathematical concepts, and the overcome of some difficulties.