For years the development of software artifacts was the sole domain of developers and project
managers. However, experience has taught us that the Users play a very important role in
software development and construction. On Domain Specific Languages the inclusion of the
domain experts directly in the development cycle is a very important characteristic, as they have
often an important role in making and constraining the domain of the language.
DSLs are credited with increased productivity and ease of use, but this fact is hardly ever proven.
Moreover, usability tests are frequently only performed at the final stages of the project when
changes have a significant impact on the budget. To help prevent this, in this paper we present a
pattern language for evaluating the usability of DSLs. Our patterns can help show how to use an
iterative usability validation development strategy to produce DSLs that can achieve a high
degree of usability.

In this work a two-stage scenario-based modeling approach is proposed in order to simultaneously deal with the design and planning decisions in supply chain networks, where both forward and reverse flows are considered (closed-loop supply chains) subject to uncertain conditions. A mixed integer linear programming (MILP) approach is developed with the underlying objective of profit maximization. Planning takes into account raw material acquisition and processing, storage and distribution of several products flowing through the network. Uncertainty is associated to the quantity and quality of the flow of products of the reverse network, which are directly affected by customers and sorting centers, respectively. The approach considers, by means of scenarios, the simultaneous integration of two important uncertainty sources, thus presenting an important modeling advantage, i.e. that of providing a better understanding of the CLSCs. The applicability of the formulation is tested with a real sized example of a Portuguese glass company.

Biocompatible and biodegradable water-soluble dendrimers comprising ureas within the interior and amino groups on the periphery were synthesized in supercritical carbon dioxide (dendrimer of generation 1 shown in picture). This novel class of dendrimers shows a pH-dependent intrinsic blue fluorescence at very low concentrations, which makes them potential polymeric fluorescent cell markers.

The present work is devoted to the study of the decontamination of chars obtained in the co-pyrolysis of plastics, biomass and tyre wastes. The chars were extracted with several organic solvents of different polarities either individually or in sequence. The ability of each selected extractant to remove toxic pollutants was evaluated by comparing the extraction yields and by characterizing the crude extracts with a combination of chemical analysis and toxicity bioassays. Also, the mineral composition of the treated and non-treated chars was assessed. The results obtained in this study indicate that hexane is the more efficient extraction solvent to be used in the organic decontamination of chars obtained in the co-pyrolysis of plastics, tyres and biomass. A sequential extraction with solvents of increasing polarity can provide a better decontamination of the raw pyrolysis char than any individual extraction. The compounds removed from the char during the decontamination process are mainly aliphatic hydrocarbons and aromatic hydrocarbons, therefore a material that may be upgraded to be used as a fuel and/or as raw material for the organic chemical industry.

The co-combustion of coal and meat and bone meal (MBM) is a possible energetic valorization route for this residue. Nevertheless, the properties of ashes produced need to be studied. To evaluate these properties, three combustion tests were performed in a fluidized bed reactor: 1) coal combustion; 2) coal + MBM (85% + 15%) co-combustion; 3) MBM combustion. The characterization of ashes was focused on the following aspects: (1) Determination of bulk content of Cr, Zn, Ni, Cu, Pb, Cd, Hg, As, Ba, Mo, Sb, Se, Ca, Na, Mg, Fe, Al and K; (2) Leaching properties of ashes based on the European Standard EN12457-2. The eluates were characterized for some of the metals referred above and for Cr VI, CN−, pH, Cl−, F−, SO42−, dissolved organic carbon and total dissolved solids. The eluates were also characterized for ecotoxicological levels by using the following bio-indicators: bacterium V. fischeri, microalgae S. capricornutum and microcrustacean D. magna. The ashes produced in the combustion of coal and co-combustion of coal + MBM have not shown evidences of ecotoxicity, while the ashes produced in the combustion of MBM were classified as ecotoxic. An assessment of the relationship between the chemical and the ecotoxicological properties of the ashes was performed. pH seemed to be the chemical parameter that most influences the ecotoxicological level of ashes.

Differently shaped polymeric matrices were efficiently coated with stimuli-responsive hydrogels for a wide range of applications using a new methodology. By combining plasma surface activation and polymerization in supercritical media at mild conditions, we report the direct smart coating of microcarriers and membranes in gram-scale quantities with a scalable, green, and low-cost approach.

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A degradação da ligação entre compósitos de matriz polimérica reforçada por fibras (FRP) e o betão é uma das principais causas de possível rotura das vigas e lajes de betão armado reforçadas
externamente por compósitos de FRP. Desde há mais de 10 anos que se estuda, por isso, na UNL o
comportamento dessa ligação, integrado em programa mais alargado de estudo da durabilidade deste tipo de reforço, especialmente quando sujeito a condições ambientais severas que se simulam por processos artificialmente acelerados no laboratório. Em particular a degradação da aderência e o possível descolamento precoce do reforço têm sido modelados física e computacionalmente com principal incidência no uso de fibras de vidro (GFRP) e resina epoxídica. Nesta comunicação mostram-se resultados obtidos em termos de capacidade de carga, força transmitida ao reforço e tensões de aderência após envelhecimentos de pequenas vigas de betão armado (BA) por ciclos de nevoeiro salino, ciclos seco/molhado em solução salina, ciclos de temperatura entre +7,5ºC e +47,5ºC e gelo-degelo de -10ºC a +30ºC. Faz-se recomendação quanto à extensão máxima para diferentes envelhecimentos. Apresenta-se comparação entre resultados de modelação numérica e experimental.

Externally bonded reinforced systems have been widely used in civil engineering. However, the problems associated with bond between structural elements are not yet fully solved. As a consequence, many researchers have been proposing tests and techniques to standardize procedures and reach better agreement for design purposes. In the present paper, an experimental program is described that was developed to characterize the glass FRP/concrete interface by double shear tests made on 15 cm side cubes with GFRP bonded on two opposite faces. The GFRP wrap had two layers applied by the wet lay-up technique and three classes of concrete were considered. With the support of the experimental program, cohesion and friction angle for GFRP–concrete interfaces were found leading to different envelope failure laws, based on the Mohr–Coulomb failure criterion for each concrete class, capable of predicting GFRP debonding. Results are discussed.

Cellulosomes are highly efficient nanomachines that play a fundamental role during the anaerobic deconstruction of complex plant cell wall carbohydrates. The assembly of these complex nanomachines results from the very tight binding of repetitive cohesin modules, located in a noncatalytic molecular scaffold, and dockerin domains located at the C-terminus of the enzyme components of the cellulosome. The number of enzymes found in a cellulosome varies but may reach more than 100 catalytic subunits if cellulosomes are further organized in polycellulosomes, through a second type of cohesin-dockerin interaction. Structural studies have revealed how the cohesin-dockerin interaction mediates cellulosome assembly and cell-surface attachment, while retaining the flexibility required to potentiate catalytic synergy within the complex. Methods that might be applied for the production, purification, and structure determination of cohesin-dockerin complexes are described here. Copyright 2012 Elsevier Inc. All rights reserved.

We can regard Domain-Specific Languages (DSLs) as User Interfaces (UIs) because they bridge the gap
between the domain experts and the computation platforms. Usability of DSLs by domain experts is a key
factor for their successful adoption. The few reports supporting improvement claims are persuasive, but
mostly anecdotal. Systematic literature reviews show that evidences on the effects of the introduction of
DSLs are actually very scarce. In particular, the evaluation of usability is often skipped, relaxed, or at
least omitted from papers reporting the development of DSLs. The few exceptions mostly take place at
the end of the development process, when fixing problems is already too expensive. A systematic
approach, based on techniques for the experimental evaluation of UIs, should be used to assess suitability
of new DSLs. This chapter presents a general experimental evaluation model, tailored for DSLs’
experimental evaluation, and instantiates it in several DSL’s evaluation examples.

Os compósitos de FRP podem descolar prematuramente da superfíce de betão, isto é, antes de esgotada a sua resistência elástica. Esta situação é mais provável se não forem tidos em conta factores como o tipo de preparação da superfície, a exposição a acção ambiental severa, e a resistência do próprio betão. Com o objectivo de analisar a influência de parte destes factores no desempenho da ligação compósito de fibra de vidro (GFRP) e betão, empreendeu-se uma campanha experimental baseada em ensaios de corte duplo. Os resultados permitiram determinar e comparar as forças máximas transmitidas ao GFRP e tensões de aderência máxima para diferentes tratamentos de superfície e condições de envelhecimento. Foram também determinadas aproximações para curvas de tensão de aderência vs. deslizamento (bond-slip). Os resultados obtidos são contrastados com resultados obtidos por modelação numérica.

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