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The electron transfer pathways for the enzymes involved in the four sequential steps of the denitrification pathway are reviewed. In addition, brief information on the electron transfer events is also provided on two enzymes that participate in the dissimilatory nitrate reduction to ammonia. The two main aspects discussed are the intra- and inter-molecular electron transfer pathways and the molecular recognition processes involving the redox partners. When available, information on the residues that are involved in these pathways is given, and their role in electron transfer and/or the formation of the transient electron transfer complexes is discussed. © The Royal Society of Chemistry 2017.

Weathering imposes vital effects on stony monuments. Mostly, the degree of weathering is determined by simple test results, ignoring simultaneous effects of various weathering factors. Hence, the main purpose of this study is to develop prediction models with fuzzy inference systems to determine the weathering degree of the Persepolis stone, using various accelerated ageing tests in laboratory condition and to extrapolate the results to the natural condition, considering climatic information. The results suggest reliable conformity between the prediction of the weathering degree of the stone and the weathering degree observed in the Persepolis complex in natural condition.

Biodegradable polymers such as PLA have been studied for medical applications, human ligament repair is one of such cases. However, these materials can be applied in other sectors as aerospace, aeronautics, automotive, food packaging. PLA presents a relatively brittle on the mode I fracture behavior, being often blend with other biodegradable or non-degradable polymers to improve its fracture energy. For some existing applications, PLA components exhibit accumulated permanent deformation resulting from dynamic mechanical inputs, resulting on failure by laxity of parts. Aiming the improvement of PLA mechanical properties, the inclusion of carbon nanofillers into PLA matrix, in particular, CNT-COOH and GNP have been developed, due to their strong sp2 carbon-carbon bondings and their geometric arrangement that enhance mechanical properties of the polymer matrix. PLA and nanocomposites were produced by melt blending followed by compression moulding in a hot press, with small weight percentages of nanofillers added to the matrix. Nanocomposites dispersion was evaluated by SEM. Quasi static tensile tests were performed on a mechanical testing machine (Instron� ElectroPuls E1000) along with strain field measurements of specimens with centred crack with digital image correlation, revealing strain distribution along specimens.

The effect of ply thickness on the onset of intralaminar and interlaminar damage is extremely important for the structural response of laminated composite structures. This subject has gained particular interest in recent years due to the introduction in the market of spread-tow, ultra-thin carbon-fibre reinforcements with different configurations. In the present paper, an experimental test campaign was carried out to study the structural response of aerospace-grade plain weave spread-tow fabrics (STFs) of different areal weights. The results showed that, in spite of an apparent superior longitudinal tensile strength of the thick STF, the multidirectional thin-STF laminate exhibited an improved tensile unnotched strength over the thick-STF laminate, attributed to its damage suppression capability. However, damage suppression was also responsible for similar tensile notched strengths. In compression, the thin-STF laminate performed substantially better than the thick-STF laminate in both unnotched and notched configurations. Finally, a similar bearing response was obtained in both STF laminates, in spite of a slightly higher resistance of the thin-STF laminate to the propagation of subcritical damage mechanisms.

Hybrid materials have been widely studied for structural applications. Polysaccharide-based fibers, especially cellulosic fibers, have been explored in the last two decades as substitutes of the traditional reinforcements made of glass or carbon fibers due to their mechanical properties. However, their biocompatibility, biodegradability, and chemistry have attracted the researchers and new developments in the field of smart and functional materials arise in diverse applications. This chapter will focus on the biomedical applications of polysaccharide-based smart and functional materials, namely those concerning biosensors and actuators, theranostic systems, and tissue-engineering applications. Special attention will be given to cellulose- and chitin/chitosan-based hybrid materials because these are the two most abundant polysaccharides and probably the most promising for the development of hybrid materials for biomedical applications. Biomimetic strategies for the development of smart and functional hybrid materials will also be highlighted. © 2017 Elsevier Ltd All rights reserved.