Bone grafting and surgical interventions related with orthopaedic disorders consist in a big business, generating large revenues worldwide every year. There is a need to replace the biomaterials that currently still dominate this market, i.e., autografts and allografts, due to their disadvantages, such as limited availability, need for additional surgeries and diseases transmission possibilities. The most promising replacement materials are biomaterials with bioactive properties, such as the calcium phosphate-based bioceramics group. The bioactivity of these materials, i.e., the rate at which they promote the growth and directly bond with the new host biological bone, can be enhanced through their electrical polarization.In the present work, the electrical polarization features of pure hydroxyapatite (Hap), pure β-tricalcium phosphate (β-TCP) and biphasic hydroxyapatite/β-tricalcium phosphate composites (HTCP) were analyzed by measuring thermally stimulated depolarization currents (TSDC). The samples were thermoelectrically polarized at 500. °C under a DC electric field with a magnitude of 5. kV/cm. The biphasic samples were also polarized under electric fields with different magnitudes: 2, 3, 4 and 5. kV/cm. Additionally, the depolarization processes detected in the TSDC measurements were correlated with dielectric relaxation processes observed in impedance spectroscopy (IS) measurements.The results indicate that the β-TCP crystalline phase has a considerable higher ability to store electrical charge compared with the Hap phase. This indicates that it has a suitable composition and structure for ionic conduction and establishment of a large electric charge density, providing great potential for orthopaedic applications.

Abstract Pipelines and piping components may experience large cyclic deformations during a reduced number of cycles (Ni = 1�100 cycles), when subjected to extreme cyclic loading events (e.g. hurricanes, support settlements, earthquakes). In accordance with these loading scenarios, a lateral movement can be applied to the pipeline inducing bending stresses that gradually promotes strain localization, due to progressive plastic instabilities (buckling), damage evolution and final failure. This work aims at characterizing ultra-low cycle fatigue (ULCF) behaviour of the \{X52\} piping steel under bending and local buckling state. An experimental program was carried out to derive \{ULCF\} data for smooth, notched and flat-grooved specimen geometries under cyclic bending. Furthermore, the small-scale tests were simulated in ABAQUS� with the objective of computing the parameters governing the fatigue damage models. The classical Coffin-Manson strain-life relation commonly used in the low cycle fatigue (LCF) regime is proposed to model the fatigue lives. In addition, the Xue model, particularly dependent of the monotonic fracture strain was also used for the prediction of the number of cycles until the crack initiation. The numerical data obtained with these models are compared, being achieved similar fatigue lives predictions for notched plane specimens. For the case of flat-grooved specimens which provides plain strain conditions, an overestimation from the Coffin-Manson relation was observed while the Xue model reproduces very good results for both specimens' series.

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The Urban-Architect role in smart cities is a topic that has not received much attention from the scientific community. This article studies the work of the traditional responsible for thinking the cities, the Urban Architect. Under a critical proposition, aspects of this problematic are identified, which is in part nourished by the deficient action of these professionals.
The study was divided into two parts, the first one materialized through a bibliographical survey, in this section it is presented; 1 - a more detailed description of why this research work; 2 - a contextualisation of the transition of the scenarios is explained; 3 - the problematization and the reflection are raised for some reasons of the "disqualification" of the action of the architect-urbanist in the scene.
The second is based on the discussion between the authors and case studies; 4 - aspects are discussed and some characteristics are listed for "(re) framing" within the ideal scenario; 5 - four case studies are described: two smart cities built from scratch and two cities being transformed into smart cities; 6 - the limitations, conclusions and strands for future work are woven.

Despite increasing calls for evidence-based policies, knowledge about the practical use of evidences remains limited. This paper studies the process of construction of evidences in decisions of innovation policy to understand how evidences were used. It analysis the use of indicators and other evidences through interviews conducted to inquire about the two decisions: an electric mobility policy and a nanotechnology laboratory. Results show indicators and other evidences were brought to decision processes according to their availability and capacity to support the different interests of the actors and
the stakeholders. Their role was influenced by the particular situation of the decision makers. More importantly, the use of persuasive analytical evidences appears to be related with the adversity of the policy context. In addition, research suggests that indicators are one tool among others to foster innovation decisions. In fact, the relatively minor instrumental role of indicators suggests that indicators are mostly a complementary instrument of decision. When used relevantly, indicators can offer support to a decision. But there are other significant influences that need to be taken into account to understand the specific role indicators and other evidences play, such as the social relations of the decision makers and their emotional-intuitive decisions.

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This paper presents a comparative evaluation of efficiencies of different accelerated ageing tests (freezethaw, thermal shock, salt crystallization, dissolution and wetting-drying) and fuzzy inference system in predicting weathering degrees of some monument stones from three historical sites (Anahita Temple, Anobanini reliefs and Eshkaft-e Salman reliefs, Iran). The combined effects of natural weathering processes (heating and cooling, wetting and drying, and freezing and thawing) and climatic information were used for assessing the natural weathering degrees. Finally, the natural weathering degrees were multiplied by time effect coefficients to obtain more realistic natural weathering degrees of the monuments. The predicted natural weathering degrees for Anahita Temple, Anobanini reliefs and Eshkaft-e Salman reliefs are 56%, 61%, and 47%, respectively. These predicted values reasonably support the weathering degrees defined by progressive decay indices (calculated equal to 2.77, 3.42 and 2.66 for Anahita Temple, Anobanini reliefs and Eshkaft-e Salman reliefs, respectively), which means the fuzzy model potentially could accurately predict the weathering of stones.

Carbon Fiber Reinforced Polymer (CFRP) composites have a large potential for strengthening and retrofitting steel parts but due to their premature debonding from steel, further data and research are still required for wider application in such situations. In the present paper, the bond characteristics of CFRP-to-steel joints in pull-pull loaded conditions were studied. Monotonic loading of the double strap joints with different bond lengths was applied and the failure modes and interfacial bond-slip curves were obtained. A tri-linear bondslip model is proposed and it was derived from the experimental data. A closed-form solution approach is also proposed based on the tri-linear bond-slip model. The strength of the CFRP-to-steel interface, the distribution of the relative displacements between bonded materials, the strains developed in the CFRP laminate and the bond stresses along the interface are reported and the closed-form solution is compared with the experimental results. Two cases are selected for presentation: (i) one with the bond length greater than the effective bond length; and, inversely, (ii) one with bond length which is shorter than the effective bond length. The results predicted by the closed-form solutions are shown to be accurate enough when compared to the experiments.