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The strengthening of structures such as columns, beams, arches or slabs with Fibre Reinforced Polymers (FRP) has been the focus of several studies. However, the studies dedicated to the FRP debonding phenomenon of curved bonded joints affected by elevated temperatures are surprisingly limited and no studies on this topic are known, at present, to use nonlinear analytical or numerical approaches. Still, the available studies found in the literature are unanimous in affirming that the debonding phenomenon on such curved interfaces demands the interaction between Fracture Modes I and II. The present work aims to develop an analytical solution capable of simulating the debonding process of curved CFRP-toconcrete interfaces with a constant radius subjected to mechanical and/or thermal loads. Some examples are presented in which the influence of the radius of the interface and the temperature level is analysed. The analytical solution proposed here is based on adhesion laws in which, in the case ofMode II, an exponential bond vs. relative displacement law with temperature dependency is assumed, whereas the Mode I adhesive law is based on a linear with fragile rupture law with the same temperature dependency as Mode II.

The teacher’s knowledge has long been viewed as a strong influence on the students’ learning. Several authors have sought to develop procedures to assess this knowledge, but this has proved to be a complex task. In this paper I present an outline of a conceptualization to analyze the teacher's knowledge, based on the model of the Knowledge for Teaching Mathematics with Technology (KTMT) and a set of tasks. These tasks are chosen by the teacher taking into account the potential of the tasks to take advantage of the technology’s potential. The analysis of the teacher’s KTMT is based on the characteristics of the tasks chosen by the teacher; the balance established between the representations provided by the technology that the tasks advocate; the way how the tasks pay attention to the new issue of seeking for a suitable viewing window; and also the way how the tasks take into account the expectable difficulties of the students in the process of looking for the window.

Abstract We report here new and the first mammaliamorph tracks from the Early Cretaceous of Africa. The tracksite, that also bears crocodylomorph and sauropod dinosaurian tracks, is in the Catoca diamond mine, Lunda Sul Province, Angola. The mammaliamorph tracks have a unique morphology, attributed to Catocapes angolanus ichnogen. et ichnosp. nov. and present an anterolateral projection of digit I and V. The tracks with an average length of 2.7 cm and width of 3.2 cm are the largest mammaliamorph tracks known from the Early Cretaceous unmatched in size in the skeletal fossil record. The crocodylomorph trackways and tracks are attributed to Angolaichnus adamanticus ichnogen. et ichnosp. nov. (‘ichnofamily’ Batrachopodidae) and present a functionally pentadactyl pes, an extremely outwardly rotated handprint, and an unusual tetradactyl and plantigrade manus. One medium-sized sauropod dinosaur trackway preserved skin impressions of a trackmaker with stride length of 1.6 m; a second is that of a small-sized sauropod trackmaker with a pace length of 75 cm.

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Neste artigo é apresentado um resumo das intervenções de conservação realizadas no século passado e dos estudos e testes não destrutivos realizados na última década na Igreja de São Leonardo na Atouguia da Baleia. Em seguida mostra-se o padrão de degradação que ocorre nos portais de arenito da igreja e é analisada a evolução da alveolização que ocorreu nos portais de arenito ao longo dos últimos sessenta a setenta anos. No final, a inspeção visual dos portais de arenito é comparada com um levantamento realizado através de varrimento por laser 3D.

tInspired by chitin based hierarchical structures observed in arthropods exoskeleton, this work reportsthe capturing of chitin nanowhiskers’ chiral nematic order into a chitosan matrix. For this purpose, highlycrystalline chitin nanowhiskers (CTNW) with spindle-like morphology and average aspect ratio of 24.9were produced by acid hydrolysis of chitin. CTNW were uniformly dispersed at different concentrationsin aqueous suspensions. The suspensions liquid crystalline phase domain was determined by rheologicalmeasurements and polarized optical microscopy (POM). Chitosan (CS) was added to the CTNW isotropic,biphasic and anisotropic suspensions and the solvent was evaporated to allow films formation. The Films’morphologies as well as the mechanical properties were explored. A correlation between experimentalresults and a theoretical model, for layered matrix’ structures with fibers acting as a reinforcement agent,was established. The results evidence the existence of two different layered structures, one formed bychitosan layers induced by the presence of chitin and another formed by chitin nanowhiskers layers.By playing on the ratio chitin/chitosan one layered structure or the other can be obtained allowing thetunning of materials’ mechanical properties.

This book is devoted to denitrification, an anaerobic process that is used by a wide range of bacteria for energy generation. The overall process involves nitrate, which is present in soil or water, being reduced to gaseous dinitrogen. This initial chapter aims to place denitrification in the larger context of the nitrogen biogeochemical cycle (a bird’s eye view). Detailed topics are developed through the many following contributions. Denitrification is a landscape for probing the structures, functions and mechanisms of action of a wide range of highly specialised metalloenzymes. These carry out, sequentially, four oxo-transfer reactions: NO₃⁻ → NO₂⁻ → ^˙NO → N₂O → N₂. The environmental implications of these processes are of particular relevance. Nitrate accumulation and the release of nitrous oxide into the atmosphere due to the excessive use of fertilisers in agriculture are examples of two environmental problems in which denitrification plays a central role.

http://docentes.fct.unl.pt/lblm/files/rsc_book-denitrification-2017-chap_1.pdf

In this paper, we address the solution of the symmetric eigenvalue complementarity problem (EiCP) by treating an equivalent reformulation of finding a stationary point of a fractional quadratic program on the unit simplex. The spectral projected-gradient (SPG) method has been recommended to this optimization problem when the dimension of the symmetric EiCP is large and the accuracy of the solution is not a very important issue. We suggest a new algorithm which combines elements from the SPG method and the block active set method, where the latter was originally designed for box constrained quadratic programs. In the new algorithm the projection onto the unit simplex in the SPG method is replaced by the much cheaper projection onto a box. This can be of particular advantage for large and sparse symmetric EiCPs. Global convergence to a solution of the symmetric EiCP is established. Computational experience with medium and large symmetric EiCPs is reported to illustrate the efficacy and efficiency of the new algorithm.

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The cyclic shift graph of a monoid is the graph whose vertices are elements of the monoid and whose edges link elements that differ by a cyclic shift. For certain monoids connected with combinatorics, such as the plactic monoid (the monoid of Young tableaux) and the sylvester monoid (the monoid of binary search trees), connected components consist of elements that have the same evaluation (that is, contain the same number of each generating symbol). This paper discusses new results on the diameters of connected components of the cyclic shift graphs of the finite-rank analogues of these monoids, showing that the maximum diameter of a connected component is dependent only on the rank. The proof techniques are explained in the case of the sylvester monoid.

Glass samples with a molar composition (64+x)ZnO-(16-x)B2O3-20SiO2, where x=0 or 1, were successfully synthesized using a melt-quenching technique. Based on differential thermal analysis data, the produced glass samples were submitted to controlled heat-treatments at selected temperatures (610, 615 and 620{\{}$\backslash$textdegree{\}}C) during various times ranging from 8 to 30h. The crystallization of willemite (Zn2SiO4) within the glass matrix was confirmed by means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). Under specific heat-treatment conditions, transparent nanocomposite glass-ceramics were obtained, as confirmed by UV-vis spectroscopy. The influence of temperature, holding time and glass composition on crystal growth was investigated. The mean crystallite size was determined by image analysis on SEM micrographs. The results indicated an increase on the crystallite size and density with time and temperature. The change of crystallite size with time for the heat-treatments at 615 and 620{\{}$\backslash$textdegree{\}}C depended on the glass composition. Under fixed heat-treatment conditions, the crystallite density was comparatively higher for the glass composition with higher ZnO content. {\{}©{\}} 2016.

Crystal graphs, in the sense of Kashiwara, carry a natural monoid structure given by identifying words labelling vertices that appear in the same position of isomorphic components of the crystal. In the particular case of the crystal graph for the q-analogue of the special linear Lie algebra sln, this monoid is the celebrated plactic monoid, whose elements can be identified with Young tableaux. The crystal graph and the so-called Kashiwara operators interact beautifully with the combinatorics of Young tableaux and with the Robinson--Schensted correspondence and so provide powerful combinatorial tools to work with them. This paper constructs an analogous `quasi-crystal' structure for the hypoplactic monoid, whose elements can be identified with quasi-ribbon tableaux and whose connection with the theory of quasi-symmetric functions echoes the connection of the plactic monoid with the theory of symmetric functions. This quasi-crystal structure and the associated quasi-Kashiwara operators are shown to interact just as neatly with the combinatorics of quasi-ribbon tableaux and with the hypoplactic version of the Robinson--Schensted correspondence. A study is then made of the interaction of the crystal graph of the plactic monoid and the quasi-crystal graph for the hypoplactic monoid. Finally, the quasi-crystal structure is applied to prove some new results about the hypoplactic monoid.