Trace elemental content was analysed in edible tissues of Mytilus galloprovincialis collected in five different sampling areas near the mouth of river Tagus estuary in Lisbon. The concentrations of essential elements (S, K, Ca, Fe, Cu, Zn, As, Br and Sr) were determined by energy-dispersive X-ray fluorescence (EDXRF) spectrometry, while toxic elements (Cr, Cd, Hg, Se and Pb) were measured by inductively coupled plasma-atomic emission spectrometry (ICP-AES). The results show that the essential elements K and S are present at the highest concentrations in all the studied samples reaching 2,920 and 4,520 μg g(-1) (fresh weight), respectively. The highest levels of heavy metals found were in two areas close to the city for Pb and Cd, but below the maximum allowed values.

We have measured the x-ray spectra from highly charged Si, S and Cl ions in collisions with thin foils using a high-resolution x-ray spectrometer. The observed lines have been assigned to various transitions in H-, He- and Li-like ions. For proper identification of line positions, the theoretical calculations have been carried out using a state-of-the-art MCDF code including QED effects, with which the experimental data is in excellent agreement. We have also observed, for the first time, x-rays arising out of the decay of long-lived resonant states in the He-like ions of each species. Details will be presented.

Os protocolos de replicação parcial de dados apresentam um grande potencial de escalabilidade. O SCORe é um protocolo para replicação parcial proposto recentemente que faz uso de controlo de concorrência multi-versão. Neste artigo abordamos um dos problemas principais que afeta o desempenho deste tipo de protocolos: a localidade dos dados, i.e., pode-se dar o caso do nó local não ter uma cópia dos dados a que pretende aceder, e nesse caso é necessário realizar uma ou mais operações de leitura remota. Assim, a não ser que se empreguem técnicas para melhorar a localidade no acesso aos dados, o número de operações de leitura remota aumenta com o tamanho do sistema, acabando por afetar o desempenho do mesmo. Nesse sentido, introduzimos um mecanismo de caching que permite replicar cópias de dados remotos de maneira a que seja possível servir localmente dados remotos enquanto que se mantém a consistência dos mesmos e a escalabilidade oferecida pelo protocolo. Avaliamos o mecanismo de caching com um benchmark conhecido da literatura e os resultados experimentais mostram resultados animadores com algum aumento no desempenho do sistema e uma redução considerável da quantidade de operações de leitura remota.

Systems externally reinforced by bonded fibre reinforced polymers (FRP) are widely used in the retrofitting and strengthening of reinforced concrete (RC) structures. A drawback of the usage of this technique lies on the uncertainty of the long term behaviour of those reinforcements. Researchers have paid heed to this aspect and a number of tests and alternative techniques have recently been described. An experimental programme developed to supplement work of the authors recently published and which focused on specimens not submitted to aggressive environments is described. The specimens used have the same geometry as in the previous paper, but they were exposed to salt fog cycles and dry/wet cycles with salt water for periods of 3000 h, 5000 h and 10,000 h. The interface of the glass fiber polymeric composite (GFRP)-to-concrete was characterized after the systems underwent such aggressive conditions. The GFRP wrap comprised of two layers and wet lay-up technique was used on its preparation and application. The cohesion and friction angle for GFRP-to-concrete interfaces were measured tat selected stages of ageing process and envelope failure laws were obtained based on the Mohr–Coulomb failure criterion. Changes of 27% in cohesion and 8% in the friction angle were found due to the attack of the interface and consequences of the changes are examined.

Currentcomputationalsystemsareheterogeneousbynature, featuring a combination of CPUs and GPUs. As the latter are becoming an established platform for high-performance computing, the focus is shifting towards the seamless programming of the heterogeneous systems as a whole. The distinct nature of the architectural and execution models in place raise several challenges, as the best hardware configuration is behavior and data-set dependent. In this paper, we focus the execution of compound computations in multi-CPU/multi-GPU environments, in the scope of Marrow algorithmic skeleton framework, the only, to the best of our knowledge, to support skeleton nesting in GPU computing. We address how these computations may be efficiently scheduled onto the target hardware, and how the system may adapt itself to changes in the CPU’s load and in the input data-set.

AbstractThe use of Fibre Reinforced Polymers (FRP) has recently become widespread in the construction industry. However, some drawbacks related to premature debonding of the FRP composites from the bonded substrates have been identified. One of the solutions proposed is the implementation of mechanical anchorage systems. Although some design guidelines have been developed, the actual knowledge continues to be rather limited. Thus, designers and researchers have not yet achieved any consensus on the efficiency of any particular anchor device in delaying or preventing the premature debonding failure mode that can occur in Externally Bonded Reinforcement (EBR) systems. This paper studies the debonding phenomenon of FRP anchoring systems with a linear variable width, with a numerical analysis based on the Distinct Element Method (DEM). Combined systems with constant and variable width are also discussed. The FRP-to-parent material interfaces are modelled with a rigid-linear softening bond–slip law. The numerical results showed that it is possible to attain the FRP rupture force with a variable width solution. This solution is particularly attractive when the bonded length is shorter than the effective bonded length because the strength of the interface can be highly incremented.

In many statistic methods, including distribution-free methods, we assume to work with random samples. In this note, we present randtests: an R package implementation of several nonparametric randomness tests. After a brief description of the tests included in the package, we present an application to real data sets in the field of Agricultural.In many statistic methods, including distribution-free methods, we assume to work with random samples. In this note, we present randtests: an R package implementation of several nonparametric randomness tests. After a brief description of the tests included in the package, we present an application to real data sets in the field of Agricultural.

This paper presents a remote laboratory linked with mobile devices for real data analysis on the field of power quality. A global system was developed from the power quality analyzer into the human machine interface devoted to the m-learning system. This m-learning system is intended to be used in a long life learning perspective. The developed remote laboratory is a good opportunity for people, even without deep knowledge on the field, to learn power quality principles in an applied way. Since the system is based on real data, is a good approach to give trainees practical knowledge on the field.

Vermilion red, mercury sulphide (α-HgS), was one of the most important reds in art and its use as a pigment dates back to Antiquity. In medieval Europe, it could be mined as cinnabar, or produced as vermilion by heating mercury with sulphur. This work aims to study the production of synthetic vermilion as a medieval pigment and to confirm which was the source (mineral or artificial) of the reds used in Portuguese medieval illuminations. The production of synthetic vermilion was based on the process described in the Judaeo-Portuguese medieval treatise “The book on how to make colours”, using materials and technologies as close as possible to the medieval ones. The reaction mechanism was studied by following the heating process by X-ray diffraction, and it was possible to conclude that the transformation from black cubic β-HgS into red hexagonal α-HgS is a solid-state phase transition, occurring at 235 °C. This result is contrary to what published in technical art literature, in which this process is described as a sublimation. Moreover, Scanning Electron Microscopy evidenced a sinterization effect on the artificial vermilion, not found in medieval original samples nor in paints prepared with mineral cinnabar from Almadén (Spain). Red mercury sulphide, natural and synthetic, was then prepared as a parchment-glue paint and compared to proteinaceous red paints from 12th–13th century miniatures produced in important medieval monasteries, previously fully characterized by a multi-analytical approach (μ-Energy dispersive X-ray fluorescence, μ-Fourier Transform Infrared Spectroscopy, Raman microscopy). A comparative Electron probe microanalysis of the red paints point to a mineral provenance for medieval vermilion found in Portuguese illuminations.