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Structural design relies essentially on tests made on cylinders of small size to estimate the probability of failure of prototype members, since full-scale testing of structures to determine their strength is not feasible. The confidence that such scale modeling deserves in terms of representation of actual behavior needs careful examination, due to such factors as material nonlinearities, difficulties of scale representation of particulate materials, and sometimes the impossibility of simultaneously satisfying independent dimensionless parameters. Some failures explained by linear fracture mechanics are associable with strong size effects, as opposed to the cases where small cracks are a material property. Besides research centered on these problems, a number of studies of scale effects have been associated with the increased probability of finding a flaw in larger objects. In fact, geometric similitude may coexist with microscopic randomness of flaws that cause size effects to appear. The type of material of the object under study may also be a decisive factor. For example, scatter of the mechanical properties in unidirectional fiber-reinforced polymers (FRPs) is much larger than in metals due to a larger density of flaws. Thus the strength of FRP laminates may depend on the volume of material involved. Strengthening reinforced concrete columns with FRP wraps leads to new constitutive laws for the overall response of the columns and requires small-scale testing followed by extrapolation for design use. The present paper focuses on the difficulties of this step, based on the experimental data obtained. The questions mentioned above are addressed, and the relevance of the adequate representation of the lateral stiffness of the FRP jacket in the scaled cylinders is emphasized. The paper also addresses the problem of testing confined cylinders with a given slenderness ratio H/D=height/diameter, within the range usually characteristic of short columns, and extrapolating the results for columns of different H/D. The importance of the parameter (thickness of jacket/diameter of column, representative of stiffness of jacket/stiffness of concrete core) is also examined. The influence of the parameter is shown to be relatively minor, whereas the nonscaling of the relative stiffness of the core and jacket would be a major cause of error. The experimental data, in terms of strain and strength, are also compared with numerical models proposed in the literature, and the quality of the approximations is analyzed.

This paper addresses the design and planning of supply chains with product return. A graph approach is used as the modelling methodology. Commonly, the application of graph approaches to the design of supply chains, considers nodes as chain entities and arcs as connections between them. These assumptions are extended in the present work where products may also be associated with both nodes and arcs. A multi-product network formulation is obtained which is further generalised to consider the modelling of time, resulting in a dynamic multi-product network model with product return. This generalisation assumes that any node is a transformation point which allows inbound and outbound products to differ. Considering four different kinds of entities (factories, warehouses, sorting centres and customers), proper functions are defined for each one: production, postponement, usage and selection. An example, base on a Portuguese industry case, is applied in order to corroborate the model applicability and adequacy to real world problems.

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The effect of rigid inclusions on the densification during isothermal sintering of glass matrix composites was investigated. Mixtures containing borosilicate glass powder and 0, 5, 10 and 25 vol. % alumina (Al 2O3) particles were prepared and powder compacts isostatically pressed at 200 MPa have been used. The sintering behaviour of the samples heated at 800°C during various times was investigated through density measurement, axial and radial shrinkage measurements. The microstructure was analysed by SEM and the crystalline phases present in the sintered composites were identified by XRD. The relative density of the isothermally treated borosilicate glass-Al2O3 composites decreased significantly with the increase in Al2O3 content because the presence of rigid inclusions retarded the densification of the compacts. The borosilicate glass exhibited anisotropic shrinkage behaviour, showing a radial shrinkage higher than the axial shrinkage and isotropic shrinkage was favoured by Al2O3 additions. Sintered glass showed a dense microstructure with some spherical closed pores. The microstructure of composites with 5 vol. % Al2O3 revealed that most of the pores were filled by capillary flow of the glass. The microstructure of composites with higher Al2O3 additions showed dense areas together with interconnected pores, which appeared at the sites of large glass particles in the green compacts.

Diphasic silicon films (nc-Si/a-Si:H) have been prepared by a new regime of plasma enhanced chemical vapour deposition in the region adjacent of phase transition from amorphous to microcrystalline state. Comparing to the conventional amorphous silicon (a-Si:H), the nc-Si/a-Si:H has higher photoconductivity (σph), better stability, and a broader light spectral response range in the longer wavelength range. It can be found from Raman spectra that there is a notable improvement in the medium range order. The blue shift for the stretching mode and red shift for the wagging mode in the IR spectra also show the variation of the microstructure. By using this kind of film as intrinsic layer, a p-i-n junction solar cell was prepared with the initial efficiency of 8.51% and a stabilized efficiency of 8.01% (AM1.5, 100 mw/cm2) at room temperature. © 2006.

Thin films of molybdenum doped indium oxide (IMO) were rf sputtered onto glass substrates at room temperature. The films were studied as a function of oxygen volume percentage (OVP) ranging 1.4 - 10.0% in the sputtering chamber. The thickness of the films found varying between 180 and 260 nm. The X-ray diffraction pattern showed the films are polycrystalline with the peaks corresponding to (222) and (400) planes and one among them showing as a preferential orientation. It is observed that the preferred orientation changes from (222) plane to (400) as the OVP increases from 1.4 to 10.0%. The transmittance spectra were found to be in the range of 77 to 89%. The optical band gap calculated from the absorption coefficient of transmittance spectra was around 3.9 eV. The negative sign of Hall coefficient confirmed the films were n-type conducting. The bulk resistivity increased from 2.26×10 -3 to 4.08×-1 Ωcm for the increase in OVP from 1.4 to 4.1%, and thereafter increased dramatically so as the Hall coefficients were not detectable. From the AFM morphologies it is evaluated that the RMS roughness of the films ranges from 0.9 to 3.2 nm. © 2006 Materials Research Society.

Cross-linked polyethylene (XLPE) peelings from aged power cables from three different sources were studied using a combined procedure of isothermal and thermo-stimulated current measurements. Different parameters, such as electric field, temperature, charging/discharging times, can be selected in order to make an analysis of the space charge characteristics (such as, relaxation times and activation energies). Three different cables peelings were analyzed: A - electrically aged in the laboratory at high temperature, B - service aged for 18 years and C - thermally aged in the laboratory at high temperature. The results were compared for the different types of samples and also with previous results on laboratory aged and produced films of low-density polyethylene (LDPE) and XLPE.

The aim of this work is to present a spectroscopic ellipsometry study focused on the annealing time effect on nickel metal induced crystallization of amorphous silicon thin films. For this purpose silicon layers with 80 and 125 nm were used on the top of which a 0.5 nm Ni thick layer was deposited. The ellipsometry simulation using a Bruggemann Effective Medium Approximation shows that films with 80 nm reach a crystalline fraction of 72% after 1 h annealing, appearing to be full crystallized after 2 h. No significant structural improvement is detected for longer annealing times. On the 125 nm samples the crystalline volume fraction after 1 h is only around 7%, requiring 5 h to get a similar crystalline fraction than the one achieved with the thinner film. This means that the time required for full crystallization will be strongly determined by the Si layer thickness. Using a new fitting approach the Ni content within the films was also determined by SE and related to the silicon film thickness. © 2006 Elsevier B.V. All rights reserved.