Atomic Data and Nuclear Data Tables, 117-118 (2017) 439-457. doi:10.1016/j.adt.2017.01.001

A utilização de Polímeros Reforçados com Fibras (FRP) no reforço de estruturas de Betão Armado (BA) tem tido cada vez mais aceitação devido à sua elevada resistência e rigidez, baixo peso específico e excelente resistência aos efeitos dos agentes ambientais. No entanto, actualmente, é comum utilizarem-se técnicas de reforço que dificilmente permitem tirar partido da resistência total destes materiais. Com o objectivo de explorar a capacidade total de Polímeros Reforçados com Fibras de Carbono (CFRP), foram estudadas e desenvolvidas duas novas técnicas de reforço de vigas à flexão designadas por Continuous Reinforcement Embedded at Ends (CREatE) e Horizontal Near Surface Mounted Reinforcement (HNSMR). Posteriormente realizou-se um estudo comparativo entre o desempenho destes sistemas de reforço e o de duas outras técnicas já estudadas e usuais, nomeadamente os sistemas Externally Bonded Reinforcement (EBR) e Near Surface Mounted Reinforcement (NSMR). A técnica CREatE provou ser a mais eficaz de todas as alternativas testadas mobilizando a totalidade do compósito de CFRP e dotando as vigas de BA com uma maior capacidade resistente e com uma ductilidade mais elevada.Como complemento deste trabalho experimental, desenvolveu-se também um programa de cálculo em MATLAB, capaz de simular o problema em estudo através de um modelo numérico de análise não linear através do equilíbrio de secções. A representatividade dos dados obtidos foi verificada através de uma análise comparativa entre os valores numéricos e os obtidos experimentalmente.The use of Fiber Reinforced Polymers (FRP) in order to strengthen Reinforced Concrete (RC) structures has been increasingly accepted due to their strength and stiffness, low weight and excellent resistance to the effects of environmental aggressive agents. However, the bonding techniques available and described in the literature can not allow the full use of the mechanical properties of these materials and premature failures are often observed and described by several researchers. In order to explore the full capacity of CFRP composites, two new bonding strengthening techniques of RC beams when subjected to 4-point bending tests were studied and developed. For these new techniques, the designation of Continuous Reinforcement Embedded at Ends (CREatE) and Horizontal Near Surface Mounted Reinforcement (HNSMR) has been assigned. Posteriorly, a comparative study has been carried out between those strengthening systems performance and two traditional techniques, namely, the Externally Bonded Reinforcement (EBR) and Near Surface Mounted Reinforcement (NSMR). The CREatE technique has proved to be the most effective of all alternatives tested, with the full utilization of the CFRP composite and the highest strength, combined with the highest ductility. A code using MATLAB software was developed as a complement of this experimental work, which is able to simulate the problem under study through a nonlinear numerical model based on the equilibrium of sections. The representativeness of the numerical data has been verified afterwards through a comparative analysis between those and the experimental results.

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Neste artigo apresentam-se e analisam-se um conjunto de ensaios realizados em vigas de betão armado reforçadas com armaduras pós-instaladas de aço ou de FRP, incluindo os referentes a uma nova técnica (CREatE) desenvolvida na FCT NOVA. Os resultados experimentais permitiram concluir que a técnica CREatE possibilita aumentos de resistência e ductilidade consideráveis face às técnicas tradicionais.

Abstract The current chromatographic approaches used in protein purification are not keeping pace with the increasing biopharmaceutical market demand. With the upstream improvements, the bottleneck shifted towards the downstream process. New approaches rely in Anything But Chromatography methodologies and revisiting former techniques with a bioprocess perspective. Protein crystallization and precipitation methods are already implemented in the downstream process of diverse therapeutic biological macromolecules, overcoming the current chromatographic bottlenecks. Promising work is being developed in order to implement crystallization and precipitation in the purification pipeline of high value therapeutic molecules. This review focuses in the role of these two methodologies in current industrial purification processes, and highlights their potential implementation in the purification pipeline of high value therapeutic molecules, overcoming chromatographic holdups.

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TThis chapter concerns the need to evaluate the reliability of structural elements produced with recycled aggregates concrete (RAC) in order to address some designers’ scepticism towards the use of this eco-friendly material. The current knowledge on RAC’s behaviour demonstrates its viability for structural purposes. However, of the investigations performed so far very few are related to a fundamental aspect towards RAC world-wide application as a structural material: structural codes have a probabilistic basis.After briefly presenting the state-of-the-art knowledge on the material properties and structural behaviour of RAC, the limitations of the current knowledge are debated. Afterwards, an introduction to structural codification is presented, as well as the fundamentals of reliability analysis. Examples of code verifications are contextualized with their underlying assumptions and the information necessary for code calibration is discussed. The role of reliability in the calibration of structural codes is shown, common techniques for reliability calculations are briefly explained, and relevant references in the area are cited for the readers’ perusal.Having established how structural codes are calibrated, the state-of-the-art on the probabilistic and statistical knowledge of RAC properties is reviewed. The implications of the very reduced number of studies on this area are discussed and the need to conduct further studies is emphasized.Afterwards, investigations that used reliability analysis to calibrate partial safety factors applicable to RAC are reviewed. The methodology of each investigation is presented, the experimental tests that led to the definition of the probabilistic information of the RAC’s parameters are described and the need to have a wide range of data coming from different RAC compositions and aggregate sources is debated.This chapter finishes by contextualizing the current knowledge on RAC properties with the necessary information for code calibration procedures. The relevance of a code proposal towards RAC affirmation as a structural material is highlighted, as well as the requirements of such code. Suggestions for future studies are made.

Journal of Quantitative Spectroscopy and Radiative Transfer, 182 + (2016) 87-93. doi:10.1016/j.jqsrt.2016.05.012

The two-photon $1{s}^{2}2s2p\phantom{\rule{0.16em}{0ex}}{}^{3}{P}_{0}\ensuremath{\rightarrow}1{s}^{2}{s}^{2}\phantom{\rule{0.16em}{0ex}}{}^{1}{S}_{0}$ transition in berylliumlike ions is investigated theoretically within a fully relativistic framework and a second-order perturbation theory. We focus our analysis on how electron correlation, as well as the negative-energy spectrum, can affect the forbidden $E1M1$ decay rate. For this purpose, we include the electronic correlation via an effective local potential and within a single-configuration-state model. Due to its experimental interest, evaluations of decay rates are performed for berylliumlike xenon and uranium. We find that the negative-energy contribution can be neglected at the present level of accuracy in the evaluation of the decay rate. On the other hand, if contributions of electronic correlation are not carefully taken into account, it may change the lifetime of the metastable state by up to 20%. By performing a fully relativistic $jj$-coupling calculation, we find a decrease of the decay rate by two orders of magnitude compared to nonrelativistic $LS$-coupling calculations, for the selected heavy ions.

We report the 94 % assignment of DVU2108, a protein belonging to the Orange Protein family, that in Desulfovibrio vulgaris Hildenborough forms a protein complex named the Orange Protein complex. This complex has been shown to be implicated in the cell division of this organism. DVU2108 is a conserved protein in anaerobic microorganisms and in Desulfovibrio gigas the homologous protein was isolated with a novel Mo-Cu cluster non-covalently attached to the polypeptide chain. However, the heterologously produced DVU2108 did not contain any bound metal. These assignments provide the means to characterize the interaction of DVU2108 with the proteins that form the Orange Protein complex using NMR methods.

O dimensionamento de vigas de madeira aos Estados Limites de Utilização (ELUt) tem limites muito apertados tanto para ações de curto prazo como para ações de longo prazo. Uma solução eficiente para este problema passa por aumentar as seções transversais das vigas. Porém, este tipo de solução não só acarreta um aumento de custos como também altera profundamente arquitetura original do edifício abrindo, por conseguinte, uma oportunidade para encontrar outras soluções mais eficientes. Neste sentido, o uso de armaduras de reforço em vigas de madeira pode ser considerado como uma solução promissora uma vez que as estruturas, novas ou velhas, manteriam o aspeto estético original sem introduzir nos elementos reforçados, um aumento significativo do seu peso próprio, melhorando o seu desempenho face a ações de curto e longo prazo. O presente estudo é dedicado à análise de vigas de madeira antigas reforçadas à flexão com materiais compósitos de fibras de carbono, vulgarmente designados na literatura internacional por Carbon Fiber Reinforced Polymers (CFRP). Neste trabalho, foram reforçados e ensaiados à flexão pavimentos antigos de madeira tendo-se analisado os respetivos desempenhos aquando da utilização de uma técnica de reforço por colagem tradicional (Externally Bonded Reinforcement - EBR) e aquando da utilização de uma técnica de reforço por colagem inovadora (Continous Reinforcement Embedded at Ends - CREatE). Os ensaios experimentais permitiram verificar que a técnica de colagem inovadora CREatE confere aos pavimentos de madeira uma maior rigidez e resistência face à técnica tradicional conseguindo se mobilizar a totalidade do compósito de CFRP.

For heavy tails, classical extreme value index estimators, like the Hill estimator, are usually asymptotically biased. Consequently those estimators are quite sensitive to the number of top order statistics used in the estimation. The recent minimum-variance reduced-bias extreme value index estimators enable us to remove the dominant component of asymptotic bias and keep the asymptotic variance of the new estimators equal to the asymptotic variance of the Hill estimator. In this paper a new minimum-variance reduced-bias extreme value index estimator is introduced, and its non degenerate asymptotic behaviour is studied. A comparison with another important minimum-variance reduced-bias extreme value index estimator is also provided.For heavy tails, classical extreme value index estimators, like the Hill estimator, are usually asymptotically biased. Consequently those estimators are quite sensitive to the number of top order statistics used in the estimation. The recent minimum-variance reduced-bias extreme value index estimators enable us to remove the dominant component of asymptotic bias and keep the asymptotic variance of the new estimators equal to the asymptotic variance of the Hill estimator. In this paper a new minimum-variance reduced-bias extreme value index estimator is introduced, and its non degenerate asymptotic behaviour is studied. A comparison with another important minimum-variance reduced-bias extreme value index estimator is also provided.