Deterioration of adhesively bonded CFRP/steel systems in salt fog environment, i.e., deicing salts and ocean environments, has to be taken into account in the design of steel strengthened structures. In the present work, monotonic and quasi-static cyclic loading were applied to CFRP-to-steel double strap joints for two kinds of CFRP laminates after being aged for a period of 5000 h to evaluate the bond behavior. The bonded joints exposed to salt fog had a different failure mode than that observed in the control specimens (0 h of exposure). The severe reduction of the maximum bond stress resulted from damage initiation that occurred in the corrosion region of the steel substrate, associated with final partial rupture on the corroded steel substrate around the edge of the bonded area: it was also correlated with reduced load carrying capacity. Results of pseudo-cyclic tests showed that the relationship between a local damage parameter (D) and normalized local dissipated energy (W d /G f ) and the normalized slip increment (ΔS/ΔS ult ) exhibited almost the same trend in the un-aged and aged bonded joints. The normalized slip increment can be seen as a direct indicator for the local and global damage for the un-aged and aged bonded joints. However, monotonic and quasi-static cyclic tests results revealed that the stress concentration due to local corrosion of steel substrate could lead to brittle rupture or accelerated cumulative damage once the aged bonded interface had become weaker. The bonded joints have exhibited also a smaller relative deformation capacity between CFRP and steel. © 2019 Elsevier Ltd

This article presents a nonlinear analytical solution for the prediction of the full-range debonding response of mechanically anchored, fiber-reinforced polymer (FRP) composites from the substrate. The nonlinear analytical approach predicts, for any monotonic loading history or bonded length, the relative displacements (or slips) between materials, the strains in the FRP composite, the bond stresses within the interface, and the stresses developed in the substrate. The load-slip responses of FRP-to-substrate interfaces with short and long bonded lengths are motives of analysis and discussion. The solutions obtained from the proposed approach are also compared with other experimental results found in the literature.

Overexpression of the Thomsen-Friedenreich (TF) antigen in cell membrane proteins occurs in 90% of adenocarcinomas. Additionally, the binding of the TF-antigen to human galectin-3 (Gal-3), also frequently overexpressed in malignancy, promotes cancer progression and metastasis. In this context, structures that interfere with this specific interaction display the potential to prevent cancer metastasis. Herein, a multidisciplinary approach, combining the optimized synthesis of a TF-antigen mimetic with NMR, X-ray crystallography methods and isothermal titration calorimetry assays has been employed to unravel the molecular structural details that govern the Gal-3/TF-mimetic interaction. The TF-mimetic presents a binding affinity for Gal-3 similar to the TF-natural antigen and retains the binding epitope and the bioactive conformation observed for the native antigen. Furthermore, from a thermodynamic perspective a decrease in the enthalpic contribution was observed for the Gal-3/TF-mimetic complex, however this behaviour is compensated by a favourable entropy gain. From a structural perspective, these results establish our TF-mimetic as a scaffold to design multivalent solutions to potentially interfere with Gal-3 aberrant interactions and likely be used to hamper Gal-3-mediated cancer cells adhesion and metastasis.

Orthotropic stiffness components of Pinus pinaster Ait. wood are simultaneously determined by means of a heterogeneous plate bending test. The proposed inverse identification approach couples full-field slope measurements provided by deflectometry with the virtual fields methods. Wooden plates oriented in the longitudinal–radial and longitudinal–tangential material planes were manufactured. A procedure was implemented to allow suitable specular reflective coating of the wooden plates, required in the deflectometry technique. Reconstructed curvature fields, applied load and plate dimensions were input in virtual fields methods for material parameter identification, assuming Kirchhoff–Love classical plate theory. Several virtual fields and load cases were analysed to address the identifiability of the method. The values of the orthotropic elastic constants obtained from the proposed approach were found in good agreement with regard to reference ones for the same species and determined from classical tensile, compression and shear mechanical tests.

The paper presents a nonlinear analytical solution for the prediction of the full-range debonding response of mechanically-anchored FRP composites from the substrate. The nonlinear analytical approach predicts, for any monotonic loading history or bonded length the relative displacements (or slips) between materials, the strains in the FRP composite, the bond stresses within the interface and the stresses developed in the substrate. The load-slip responses FRP-to-substrate interfaces with a short and a long bonded lengths are motive of analysis and discussion. The solutions obtained from the proposed approach are also compared with other experimental results found in the literature.

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https://docentes.fct.unl.pt/lblm/files/refmodchem-2018---1.pdf

Piezoelectric energy harvesting has received great attention over the last 20 years. The main goal of this work is to discuss the potential advantages of introducing non-linearities in the dynamics of a beam type piezoelectric vibration energy harvester. The described device is essentially a cantilever beam partially covered by piezoelectric material with a force electromagnetically applied to the beam. Through experimental tests it has been confirmed the benefits of introducing non-linearities in these types of systems.

This paper investigates whether the model uncertainty of reinforced recycled aggregate concrete (RAC) beams subjected to bending differs from that of reinforced natural aggregate concrete (NAC) beams. An introductory remark concerning the importance of the codification of RAC structural design is made and notions concerning model uncertainties and their role on structural codification are given. Afterwards, the criteria used in the construction of a database of RAC and NAC beams are referred before presenting the key findings of an analysis on the model uncertainty of the cracking, yielding and ultimate moments of beams subjected to four-point bending tests. The analytical moments were calculated following Eurocode 2 provisions. Probabilistic models for model uncertainties are proposed. Negligible differences in the model uncertainty of NAC and RAC beams are reported.

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