Thin films of titanium dioxide (TiO2) and titanium (Ti) were deposited onto glass and optical fiber supports through DC magnetron sputtering, and their transmission was characterized with regard to their use in optical fiber-based sensors. Deposition parameters such as oxygen partial pressure, working pressure, and sputtering power were optimized to attain films with a high reflectance. The films deposited on glass supports were characterized by UV-Vis spectroscopy, X-ray diffraction (XRD), and scanning electron microscopy (SEM). Regarding the deposition parameters, all three parameters were tested simultaneously, changing the working pressure, the sputtering power, and the oxygen percentage. It was possible to conclude that a lower working pressure and higher applied power lead to films with a higher reflectance. Through the analysis of the as-sputtered thin films using X-ray diffraction, the deposition of both Ti and TiO2 films was confirmed. To study the applicability of TiO2 and Ti in fiber sensing, several thin films were deposited in single mode fibers (SMFs) using the sputtering conditions that revealed the most promising results in the glass supports. The sputtered TiO2 and Ti thin films were used as mirrors to increase the visibility of a low-finesse Fabry–Perot cavity and the possible sensing applications were studied.

The contamination of water resources by pollutants resulting from human activities represents a major concern nowadays. One promising alternative to solve this problem is the photocatalytic process, which has demonstrated very promising and efficient results. Oxide nanostructures are interesting alternatives for these applications since they present wide band gaps and high surface areas. Among the photocatalytic oxide nanostructures, zinc tin oxide (ZTO) presents itself as an eco-friendly alternative since its composition includes abundant and non-toxic zinc and tin, instead of critical elements. Moreover, ZTO nanostructures have a multiplicity of structures and morphologies possible to be obtained through low-cost solution-based syntheses. In this context, the current work presents an optimization of ZTO nanostructures (polyhedrons, nanoplates, and nanoparticles) obtained by microwave irradiation-assisted hydrothermal synthesis, toward photocatalytic applications. The nanostructures' photocatalytic activity in the degradation of rhodamine B under both ultraviolet (UV) irradiation and natural sunlight was evaluated. Among the various morphologies, ZTO nanoparticles revealed the best performance, with degradation > 90% being achieved in 60 min under UV irradiation and in 90 min under natural sunlight. The eco-friendly production process and the demonstrated ability of these nanostructures to be used in various water decontamination processes reinforces their sustainability and the role they can play in a circular economy.

The CREMA collaboration is pursuing a measurement of the ground-state hyperfine splitting (HFS) in muonic hydrogen (μp) with 1 ppm accuracy by means of pulsed laser spectroscopy to determine the two-photon-exchange contribution with 2×10-4 relative accuracy. In the proposed experiment, the μp atom undergoes a laser excitation from the singlet hyperfine state to the triplet hyperfine state, then is quenched back to the singlet state by an inelastic collision with a H2 molecule. The resulting increase of kinetic energy after the collisional deexcitation is used as a signature of a successful laser transition between hyperfine states. In this paper, we calculate the combined probability that a μp atom initially in the singlet hyperfine state undergoes a laser excitation to the triplet state followed by a collisional-induced deexcitation back to the singlet state. This combined probability has been computed using the optical Bloch equations including the inelastic and elastic collisions. Omitting the decoherence effects caused by the laser bandwidth and collisions would overestimate the transition probability by more than a factor of two in the experimental conditions. Moreover, we also account for Doppler effects and provide the matrix element, the saturation fluence, the elastic and inelastic collision rates for the singlet and triplet states, and the resonance linewidth. This calculation thus quantifies one of the key unknowns of the HFS experiment, leading to a precise definition of the requirements for the laser system and to an optimization of the hydrogen gas target where μp is formed and the laser spectroscopy will occur.

{The Upper Jurassic Lourinhã Formation is well known for its rich assemblage of fossil vertebrates. In this formation, ornithopod dinosaurs are represented by two iguanodontian species, Eousdryosaurus nanohallucis and Draconyx loureiroi. We recently became aware of unreported material belonging to the holotype of Draconyx loureiroi, consisting of partially articulated manual elements. We here re-describe the holotype specimen ML 357, including the newly discovered material. The specimen was subjected to CT-scanning and its surface data used to assess anatomical characters. Linear measurements of metatarsal III were used to estimate the body length of the specimen. The Draconyx loureiroi holotype was included in two datasets and analysed with maximum parsimony and Bayesian inference approaches to estimate evolutionary rates among Iguanodontia. We present evidence that Draconyx loureiroi is a valid taxon nested in Styracosterna and is clearly diagnosable by a unique combination of characters. Both maximum parsimony and Bayesian inference indicate high evolutionary rates across the Jurassic/Cretaceous transition for the base of Iguanodontia. Length estimation suggests that Draconyx loureiroi was a relatively small, bipedal and possibly cursorial animal. Given its basal phyletic position, we interpret this bauplan was the ancestral condition for Styracosterna, that only later in the Cretaceous evolved into giant quadrupedal forms.}

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Technology is recognized by its potential to promote mathematical learning. However, achieving this potential
requires the teachers to have the knowledge to integrate it properly into their practices. Several authors have intended to characterize the teachers’ knowledge and developed several models, but this approach has often been criticized by its static approach, not attending neither valuing the teachers’ practice. In this study we adopt the KTMT – Knowledge for Teaching Mathematics with Technology model, assuming the teachers’ practice as the main scenario of analysis. We focus on the options guiding the teachers’ decisions when confronted with a situation of lack of mathematical concordance while teaching functions. The situations of lack of mathematical concordance (i.e., situations where the mathematics addressed by the students is different from the one intended by the teacher) are assumed as rich and encapsulating the potential to reveal significant aspects of the teachers’ KTMT. The main goal of the study is to understand what domains of the teachers’ KTMT are highlighted in these circumstances. A qualitative methodology is adopted and one episode of one 10th grade teacher’s practice is analyzed, based on the KTMT model. The conclusions reached show the relevance of different knowledge domains, but emphasize the Mathematics and Technology Knowledge (MTK). They also raise questions about the impact of the specific technology being used on the teachers’ KTMT.

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A exploração de diferentes representações promove a compreensão dos tópicos de funções. Partindo deste pressuposto, com este estudo pretende-se analisar o contributo da representação gráfica na aprendizagem da noção de função inversa e da paridade de uma função por alunos do 10.º ano de escolaridade e identificar dificuldades na exploração dessa representação. Na procura de responder a este objetivo, adotou-se uma abordagem qualitativa e interpretativa para compreender as ações dos alunos na resolução das tarefas
propostas. A análise das resoluções mostra que a representação gráfica serviu de suporte para a instituição das definições dos tópicos em estudo. E isto apesar de alguns alunos revelarem dificuldades ao interpretar e ao construir gráficos; ao identificar imagens e imagens inversas em gráficos de funções; ao representar determinadas características gráficas associadas a alguns conceitos, como é o caso da relação entre a paridade de uma função e a simetria na sua representação gráfica (confundindo eixo de simetria e de reflexão). Globalmente, este estudo mostra como a abordagem de conceitos a partir da representação gráfica pode contribuir para a sua compreensão.

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