Abstract Biodegradable polymers such as poly(lactic) acid (PLA) have been studied for biomaterials applications such as natural human ligament replacement, however these materials could be applied to other sectors as aerospace, aeronautics, automotive, food packaging. \{PLA\} presents a relatively brittle with a mode I fracture behavior, being often blend with other biodegradable or non-degradable polymers to improve its fracture energy. For some existing applications, \{PLA\} components exhibit accumulated permanent deformation resulting from dynamic mechanical inputs, resulting on failure by laxity of parts. Aiming the improvement of \{PLA\} mechanical properties, the inclusion of carbon nanofillers into \{PLA\} matrix, in particular, CNT-COOH and \{GNP\} have been developed, due to their strong sp2 carbon-carbon bondings and their geometric arrangement that enhance mechanical properties of the polymer matrix. \{PLA\} and nanocomposites were produced by melt blending followed by compression molding in a hot press, with small weight percentages of nanofillers added to the matrix. Quasi static tensile tests were performed on a mechanical testing machine (Instron™ ElectroPuls E1000) along with failure analysis of specimens with centered crack with digital image correlation, revealing strain distribution along specimens.

Light has long being used in medicine; however, the high scattering of biological tissues always hindered its use. The aim of this work is the development of methodologies to focus light inside biological tissues. Geant4/GAMOS Monte Carlo platform was used to simulate the possibility of parameterize the time delay of multiple sources of external light, offset in time, as a function of the interest region position in order to create constructive interferences in a breast sample. A computational model was implemented and the platform was configured in order to perform these simulations. Preliminary results using a single light source were performed. It was concluded that scattering in adipose tissue is very high which is consistent with previous studies.

A large collection of vertebrate coprolites from black lacustrine shales in the Late Triassic (Rhaetian–Sinemurian) Kap Stewart Formation, East Greenland is examined with regard to internal and external morphology, prey inclusions, and possible relationships to the contemporary vertebrate fauna. A number of the coprolites were mineralogically examined by X-ray diffraction (XRD), showing the primary mineral composition to be apatite, clay minerals, carbonates and, occasionally, quartz in the form of secondary mineral grains. The coprolite assemblage shows multiple sizes and morphotypes of coprolites, and different types of prey inclusions, demonstrating that the coprolite assemblage originates from a variety of different producers.Supplementary material: A description of the size, shape, structure, texture, contents and preservation of the 328 specimens is available at https://doi.org/10.6084/m9.figshare.c.2134335

The direct identification of the cohesive law in pure mode I of Pinus pinaster is addressed. The approach couples the double cantilever beam (DCB) test with digital image correlation (DIC). Wooden beam specimens loaded in the radial-longitudinal (RL) fracture propagation system are used. The strain energy release rate in mode I (GI ) is uniquely determined from the load-displacement ( P ?? ) curve by means of the compliance-based beam method (CBBM). This method relies on the concept of equivalent elastic crack length ( eq a ) and therefore does not require the monitoring of crack propagation during test. The crack tip opening displacement in mode I ? ? I w is determined from the displacement field at the initial crack tip. The cohesive law in mode I I I (? ? w ) is then identified by numerical differentiation of the I I G ? w relationship. Moreover, the proposed procedure is validated by finite element analyses including cohesive zone modelling. It is concluded that the proposed data reduction scheme is adequate for assessing the cohesive law in pure mode I of P. pinaster.

© The Society for Experimental Mechanics, Inc. 2015. As it is widely known, in structural dynamic applications, ranging from structural coupling to model updating, the incompatibility between measured and simulated data is inevitable, due to the problem of coordinate incompleteness. Usually, the experimental data from conventional vibration testing is collected at a few translational degrees of freedom (DOF) due to applied forces, using hammer or shaker exciters, over a limited frequency range. Hence, one can only measure a portion of the receptance matrix, few columns, related to the forced DOFs, and rows, related to the measured DOFs. In contrast, by finite element modeling, one can obtain a full data set, both in terms of DOFs and identified modes. Over the years, several model reduction techniques have been proposed, as well as data expansion ones. However, the latter are significantly fewer and the demand for efficient techniques is still an issue. In this work, one proposes a technique for expanding measured frequency response functions (FRF) over the entire set of DOFs. This technique is based upon a modified Kidder’s method and the principle of reciprocity, and it avoids the need for modal identification, as it uses the measured FRFs directly. In order to illustrate the performance of the proposed technique, a set of simulated experimental translational FRFs is taken as reference to estimate rotational FRFs, including those that are due to applied moments.

X-ray intensity ratios, such as the Kα2/Kα1 ratio, are parameters with a large application in atomic physics and related scientific and technological areas. D.

A miniaturized version of the double cantilever beam (DCB) test is used to determine the fracture energy in human cortical bone under pure mode I loading. An equivalent crack length based data-reduction scheme is used with remarkable advantages relative to classical methods. Digital image correlation (DIC) technique is employed to determine crack opening displacement at the crack tip being correlated with the evolution of fracture energy. A method is presented to obtain the cohesive law (trapezoidal bilinear softening) mimicking the mechanical behavior observed in bone. Cohesive zone modeling (CZM) (finite-element method) was performed to validate the procedure showing excellent agreement.

The formulation of a bending vibration problem of an elastically restrained Bernoulli-Euler beam carrying a finite number of concentrated elements along its length is presented. In this study, the authors exploit the application of the differential evolution optimization technique to identify the torsional stiffness properties of the elastic supports of a Bernoulli-Euler beam. This hybrid strategy allows the determination of the natural frequencies and mode shapes of continuous beams, taking into account the effect of attached concentrated masses and rotational inertias, followed by a reconciliation step between the theoretical model results and the experimental ones. The proposed optimal identification of the elastic support parameters is computationally demanding if the exact eigenproblem solving is considered. Hence, the use of a Gaussian process regression as a meta-model is addressed. An experimental application is used in order to assess the accuracy of the estimated parameters throughout the comparison of the experimentally obtained natural frequency, from impact tests, and the correspondent computed eigenfrequency.

Nucleation is a critical step determining the outcome of the entire crystallization process. Finding an effective nucleant for protein crystallization is of utmost importance for structural biology. The latter relies on good-quality crystals to solve the three-dimensional structures of macromolecules. In this study we show that crystalline barium sulfate (BaSO4) with an etched and/or ionic liquid (IL)-functionalized surface (1) can induce protein nucleation at concentrations well below the concentration needed to promote crystal growth under control conditions, (2) can shorten the nucleation time, (3) can increase the growth rate, and finally (4) may help to improve the protein crystal morphology. These effects were shown for lysozyme, RNase A, trypsin, proteinase K, myoglobin, and hemoglobin. Therefore, the use of BaSO4 particles enables us to reduce the amount of protein in crystallization trials and increases the chance of obtaining protein crystals of the desired quality. In the context of the underlying mechanism, it is shown that the protein-solid contact formation is governed by the interaction of the polar compartments of the biomacromolecule with the support. The tendency of a protein to concentrate near the solid surface is enhanced by both the hydrophobicity of the protein and that of the surface (tuned by the functionalizing IL). These mechanisms of interaction of biomacromolecules with inorganic hydrophilic solids correspond to the principles of amphiphilic IL-mineral interactions.