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Optimized supply chains, both economically as well as environmentally, are significant instruments to be adopted by companies if they want to succeed in the current competitive world. However, without the support of decision tools to help, at least approximately, the integration of these two aspects in the company’s decision making such aim is difficult to reach. The purpose of this study is to develop a mixed integer linear programming model (MILP), which allows the optimization of closed loop supply chains, considering not only economical aspects, but also environmental ones. The model developed was applied to a Portuguese company where their logistic network structure was redesigned.

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The objective of this study was to analyse the behaviour of prestress strand anchorages by bonding with an epoxy adhesive for structural strengthening use. Pull-out and push-in tests were carried out on 15·2 mm diameter prestress steel strands sealed in 18 mm diameter holes with several embedment lengths, complemented by long-term tests. Experimental results are presented and compared with theoretical results regarding maximum pull-out and transmittable loads and also draw-in results. Theoretical results are obtained by solving the governing equation of the bond phenomenon adopting a non-linear local bond/slip law derived from pull-out tests with short embedment length. The study shows that it is reasonable to assume an average constant bond stress for anchorage design with the studied epoxy adhesive in the range of the studied values of anchor embedment length and diameter. The average values for bond stress to be used for determining the maximum pull-out and transmittable loads were found to be 12·0 and 5·2 MPa, respectively. Experimental draw-in values show a great variability, and so determining transmission length based on draw-in values may lead to a false perception that the transmission length is very variable.

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In this paper an optimization-based approach for the design of RF integrated inductors is addressed. For the characterisation of the inductor behaviour the double π-model is used. The use of this model is twofold. On one hand it enables the generation of the inductor characterisation in a few seconds. On the other hand its integration into the optimization procedure is straightforward. For the evaluation of the model element values analytical expressions based on technology parameters as well as on the device geometric characteristics are used. The use of a technology-based methodology for the evaluation of the model parameters grants the adaptability of the model to any technology. The inductor analytical characterization is integrated into an optimization-based tool for the automatic design of RF integrated inductors. This tool uses a modified genetic algorithm (MGA) optimization procedure, which has proved its validation in previous work. Due to the design parameter constraints nature as well as the topology constraints, discrete variables optimization techniques are used. The accuracy of the results is checked against a non-commercial software.

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This work aims to study a new flat slab strengthening technique based on post-tensioning with anchorages by bonding using an epoxy adhesive. The main advantages of this technique over the traditional prestress strengthening systems that use mechanical anchorages are that it does not need external permanent anchorages, meaning that the forces are introduced into the concrete gradually instead of being localized, thereby preserving aesthetics and useable space. The seven tested slab models show that this technique meets its objective as it is able to reduce reinforcement strains at service loads by up to 80{%} if the strengthening technique is applied in two directions and slab deformations by up to 70{%}, consequently making crack widths smaller. It can also increase punching load capacity by as much as 51{%} when compared to non-strengthened slabs. The results are compared with the EC2 (2004) [20], ACI 318-08 (2008) [23] and MC2010 (2010) [21] provisions. The main conclusions are that this strengthening technique is effective regarding ultimate and serviceability states and that it represents an advance in RC slab strengthening techniques. ?? 2011 Elsevier Ltd.

The high prices currently achieved in the acquisition of non-renewable energy for electricity production and the low levels of energy efficiency in the housing sector are the national situation, which leads the Portuguese government to encourage the acquisition, the installation and the use of technologies which exploit indigenous and renewable energy. This study presents an application that was developed in order to help the citizen in his decision to invest in renewable technologies in their homes. The application is able to elaborate an economic analysis based on the selected type of renewable technology, providing the user with the knowledge of benefits and the annual costs involved in the system that he selected. This tool aims at facilitating the interaction of any user with such technologies and it can be used as a helpful tool to support the decision of investment in such systems.

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Superoxide reductases are enzymes involved in bacterial resistance to reactive oxygen species, catalyzing the reduction of superoxide anions to hydrogen peroxide. So far three structural classes have been identified. Class I enzymes have two iron-center containing domains. Most studies have been focused on the catalytic iron site (center II), but the role of center I is yet poorly understood. The possible roles of this iron site were approached by an integrated study using both classical and fast kinetics measurements as well as direct electrochemistry. A new heterometallic form of the protein with a zinc-substituted center I, maintaining the iron active site center II was obtained, resulting in a stable derivative useful for comparison with the native all-iron from. Second order rate constants for the electron transfer between reduced rubredoxin and the different SOR forms were determined to be 2.8x107 (M-1s-1) and 1.3x106 (M-1s-1) for SORFe(IIII)-Fe(II) and for SORFe(IIII)-Fe(III) forms respectively, and 3.2x106 (M-1s-1) for the SORZn(II)-Fe(III) form. The results obtained seem to indicate that center I transfers electrons from the putative physiologic donor, rubredoxin, to the catalytic active iron site (intramolecular process). In addition, electrochemical results show that conformational changes are associated to the redox state of center I, which may enable a faster catalytic response towards superoxide anion. The apparent rate constants calculated for the SOR-mediated electron transfer also support this observation.

The permeability of gases through uncompressed cork was investigated. More than 100 samples were assessed from different plank qualities to provide a picture of the permeability distribution. A novel technique based on a mass spectrometer leak detector was used to directly measure the helium flow through the central area of small disks 10 mm in diameter and 2 mm thick. The permeability for nitrogen, oxygen, and other gases was measured by the pressure rise technique. Boiled and nonboiled cork samples from different sections were evaluated. An asymmetric frequency distribution ranging 3 orders of magnitude (roughly from 1 to 1000 $μ$mol/(cm·atm·day)) for selected samples without macroscopic defects was found, having a peak below 100 $μ$mol/(cm·atm·day). Correlation was found between density and permeability: higher density samples tend to show lower permeability. However, boiled cork showed a mean lower permeability despite having a lower density. The transport mechanism of gases through cork was also examined. Calculations suggest that gases permeate uncompressed cork mainly through small channels between cells under a molecular flow regime. The diameter of such channels was estimated to be in the range of 100 nm, in agreement with the plasmodesmata size in the cork cell walls.

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