A large collection of vertebrate coprolites from black lacustrine shales in the Late Triassic (Rhaetian–Sinemurian) Kap Stewart Formation, East Greenland is examined with regard to internal and external morphology, prey inclusions, and possible relationships to the contemporary vertebrate fauna. A number of the coprolites were mineralogically examined by X-ray diffraction (XRD), showing the primary mineral composition to be apatite, clay minerals, carbonates and, occasionally, quartz in the form of secondary mineral grains. The coprolite assemblage shows multiple sizes and morphotypes of coprolites, and different types of prey inclusions, demonstrating that the coprolite assemblage originates from a variety of different producers.Supplementary material: A description of the size, shape, structure, texture, contents and preservation of the 328 specimens is available at https://doi.org/10.6084/m9.figshare.c.2134335

Abstract The strain rate dependent mechanical behaviour was studied for the common out-of-autoclave aerospace textile composite 5-harness-satin carbon–epoxy. End-loaded 15 ° , 30 ° and 45 ° off-axis and 90 ° compression tests were carried out at three different strain rate levels ( 4 × 10 - 4 s - 1 , 200 s - 1 and 1000 s - 1 ) to determine the effect of strain rate for transverse compression and combined transverse compression/in-plane shear loading. The dynamic tests were carried out on a split-Hopkinson pressure bar, where high speed photography and digital image correlation allowed a detailed study of the specimen deformation and failure process. Quasi-static reference tests were carried out on an electro-mechanical test machine using the same specimen type and a static \{DIC\} system. Pronounced strain rate effects on the axial stress–strain response were observed for all specimen types. Failure envelopes for the combined σ 22 c - τ 12 stress state were derived from the experimental data and compared with the maximum stress criterion, which appears well suited to approximate the experimental failure envelope at all strain rate levels. It was observed that the failure envelope was simply scaled up with increasing strain rate, while the overall shape was found to be strain rate independent.

Nucleation is a critical step determining the outcome of the entire crystallization process. Finding an effective nucleant for protein crystallization is of utmost importance for structural biology. The latter relies on good-quality crystals to solve the three-dimensional structures of macromolecules. In this study we show that crystalline barium sulfate (BaSO4) with an etched and/or ionic liquid (IL)-functionalized surface (1) can induce protein nucleation at concentrations well below the concentration needed to promote crystal growth under control conditions, (2) can shorten the nucleation time, (3) can increase the growth rate, and finally (4) may help to improve the protein crystal morphology. These effects were shown for lysozyme, RNase A, trypsin, proteinase K, myoglobin, and hemoglobin. Therefore, the use of BaSO4 particles enables us to reduce the amount of protein in crystallization trials and increases the chance of obtaining protein crystals of the desired quality. In the context of the underlying mechanism, it is shown that the protein-solid contact formation is governed by the interaction of the polar compartments of the biomacromolecule with the support. The tendency of a protein to concentrate near the solid surface is enhanced by both the hydrophobicity of the protein and that of the surface (tuned by the functionalizing IL). These mechanisms of interaction of biomacromolecules with inorganic hydrophilic solids correspond to the principles of amphiphilic IL-mineral interactions.

In Late Triassic (Norian–Rhaetian) times, the Jameson Land Basin lay at 40° N on the northern part of the supercontinent Pangaea. This position placed the basin in a transition zone between the relatively dry interior of the supercontinent and its more humid periphery. Sedimentation in the Jameson Land Basin took place in a lake–mudflat system and was controlled by orbitally forced variations in precipitation. Vertebrate fossils have consistently been found in these lake deposits (Fleming Fjord Formation), and include fishes, dinosaurs, amphibians, turtles, aetosaurs and pterosaurs. Furthermore, the fauna includes mammaliaform teeth and skeletal material. New vertebrate fossils were found during a joint vertebrate palaeontological and sedimentological expedition to Jameson Land in 2012. These new finds include phytosaurs, a second stem testudinatan specimen and new material of sauropodomorph dinosaurs, including osteologically immature individuals. Phytosaurs are a group of predators common in the Late Triassic, but previously unreported from Greenland. The finding includes well-preserved partial skeletons that show the occurrence of four individuals of three size classes. The new finds support a late Norian–early Rhaetian age for the Fleming Fjord Formation, and add new information on the palaeogeographical and palaeolatitudinal distribution of Late Triassic faunal provinces.

In 1994 fib Commission 6: Prefabrication edited a successful Planning and Design Handbook that ran to approximately 45,000 copies and was published in Spanish and German.Nearly 20 years later Bulletin 74 brings that first publication up to date. It offers a synthesis of the latest structural design knowledge about precast building structures against the background of 21st century technological innovations in materials, production and construction. With it, we hope to help architects and engineers achieve a full understanding of precast concrete building structures, the possibilities they offer and their specific design philosophy. It was principally written for non-seismic structures.

The handbook contains eleven chapters, each dealing with a specific aspect of precast building structures.
The first chapter of the handbook highlights best practice opportunities that will enable architects, design engineers and contractors to work together towards finding efficient solutions, which is something unique to precast concrete buildings.
The second chapter offers basic design recommendations that take into account the possibilities, restrictions and advantages of precast concrete, along with its detailing, manufacture, transport, erection and serviceability stages.
Chapter three describes the precast solutions for the most common types of buildings such as offices, sports stadiums, residential buildings, hotels, industrial warehouses and car parks. Different application possibilities are explored to teach us which types of precast units are commonly used in all those situations.
Chapter four covers the basic design principles and systems related to stability. Precast concrete structures should be designed according to a specific stability concept, unlike cast in-situ structures.
Chapter five discusses structural connections.
Chapters six to nine address the four most commonly used systems or subsystems of precast concrete in buildings, namely, portal and skeletal structures, wall-frame structures, floor and roof structures and architectural concrete facades.
In chapter ten the design and detailing of a number of specific construction details in precast elements are discussed, for example, supports, corbels, openings and cutouts in the units, special features related to the detailing of the reinforcement, and so forth.
Chapter eleven gives guidelines for the fire design of precast concrete structures. The handbook concludes with a list of references to good literature on precast concrete construction.

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Motivated by the need to describe bear-bull market regime switching in stock prices, we introduce and study a stochastic process in continuous time with two regimes, threshold and delay, given by a stochastic differential equation. When the difference between the regimes is simply given by a different set of real valued parameters for the drift and diffusion coefficients, with changes between regimes depending only on these parameters, we show that if the delay is known there are consistent estimators for the threshold as long we know how to classify a given observation of the process as belonging to one of the two regimes. When the drift and diffusion coefficients are of geometric Brownian motion type we obtain a model with parameters that can be estimated in a satisfactory way, a model that allows differentiating regimes in some of the NYSE 21 stocks analyzed and also, that gives very satisfactory results when compared to the usual Black–Scholes model for pricing call options.

Regime switching processes are usually defined with an external random source driving the regime changes. In this article, we define and study a regime switching diffusion considering two thresholds, and regime switching occurring, by a change in the diffusion drift and volatility, whenever the trajectory touches the upper threshold after having crossed, or touched, the lower threshold or touches the lower threshold after having crossed, or touched, the upper threshold. We develop an estimation procedure for the thresholds and for the regime parameters of the diffusions. We show that a generalized Black–Scholes model with the regime switching diffusion as the law of the risky asset is arbitrage free and complete under an additional hypothesis on the diffusion coefficients of the two regime diffusions.

One possibility for strengthening existing flat slabs consists on gluing fibre reinforced polymers (FRPs) at the concrete surface. When applied on top of slab-column connections, this technique allows increasing the flexural stiffness and strength of the slab as well as its punching strength. Nevertheless, the higher punching strength is associated to a reduction on the deformation capacity of the slab-column connection, which can be detrimental for the overall behaviour of the structure (leading to a more brittle behaviour of the system). Design approaches for this strengthening technique are usually based on empirical formulas calibrated on the basis of the tests performed on isolated test specimens. However, some significant topics as the reduction on the deformation capacity or the influence of the whole slab (accounting for the reinforcement at mid-span) on the efficiency of the strengthening are neglected. In this paper, a critical review of this technique for strengthening against punching shear is investigated on the basis of the physical model proposed by the Critical Shear Crack Theory (CSCT). This approach allows taking into account the amount, layout and mechanical behaviour of the bonded FRP's in a consistent manner to estimate the punching strength and deformation capacity of strengthened slabs. The approach is first used to predict the punching strength of available test data, showing a good agreement. Then, it is applied in order to investigate strengthened continuous slabs, considering moment redistribution after concrete cracking and reinforcement yielding. This latter study provides valuable information regarding the differences between the behaviour of isolated test specimens and real strengthened flat slabs. The results show that empirical formulas calibrated on isolated specimens may overestimate the actual performance of FRP's strengthening. Finally, taking advantage of the physical model of the CSCT, the effect of the construction sequence on the punching shear strength is also evaluated, revealing the role of this issue which is also neglected in most empirical approaches.

Some asymptotic expansions not necessarily related to the central limit theorem are studied. We first observe that the smoothing inequality of Esseen implies the proximity, in the Kolmogorov distance sense, of the distributions of the random variables of two random sequences satisfying a sort of general asymptotic relation. We then present several instances of this observation. A first example, partially motivated by the the statistical theory of high precision measurements, is given by a uniform asymptotic approximation to gX + nn∈, where g is some smooth function, X is a random variable and nn∈ is a sequence going to infinity; a multivariate version is also stated and proved. We finally present a second class of examples given by a randomization of the interesting parameter in some classical asymptotic formulas; namely, a generic Laplace’s type integral, randomized by the sequence nXn∈, X being a Gamma distributed random variable.

A transparent Eu3 +-doped lithium aluminophosphate glass was prepared by melt-quenching technique. The thermal behavior of the glass was investigated by differential thermal analysis (DTA), the structure was studied by X-ray diffraction (XRD) and the morphology was observed by optical polarization microscopy and scanning electron microscopy (SEM). The activation energy of glass transition and the activation energy of crystallization and Avrami exponent have been evaluated under non-isothermal conditions from the data obtained by DTA at different heating rates. DTA curves exhibited an endothermic peak associated with the glass transition and two exothermic peaks. The mean value calculated for the activation energy of glass transition was 545 kJ mol- 1. The activation energy of crystallization was   400 kJ mol- 1 for the first exothermic peak and   170 kJ mol- 1 for the second peak. The Avrami exponent was   1 for both peaks indicating surface crystallization. XRD results showed that the main crystalline phase, aluminum metaphosphate, Al(PO3)3, and aluminum phosphate, AlPO4, were formed together with lithium barium phosphate, Li 3Ba(PO3)7, during the first exothermic peak and together with barium pyrophosphate, Ba2P2O7, during the second peak. Morphological study of heat-treated glass samples revealed microstructural features that confirmed a surface crystallization process. © 2014 Elsevier B.V.

With a 4f6 electronic configuration, europium ions in the trivalent charge state are known to be efficient activators in wide band gap matrices. Embedded in the aluminophosphate (Li2O-BaO-Al 2O3-La2O3-P2O 5) glasses the optically activated Eu3+ ions lead to intense room temperature orange/red luminescence with 16-23 Cd/m2 by using ultraviolet pumping. The as-prepared and heat treated europium doped glasses for temperatures below and above Tg were studied by room temperature Raman spectroscopy, absorption, photoluminescence excitation, temperature dependent and time dependent photoluminescence. When the samples are excited by 325 nm wavelength photons, an enhancement of the red luminescence intensity by ca. one order of magnitude was found to occur for temperatures between 14 K and 350 K, for all the doped glasses. On the other hand, by using resonant excitation on the 5L6 Eu3+ excited state (λexc 390 nm) the ion emission intensity was found to be nearly constant for temperatures up to 500 K. For higher temperatures a steeper decrease of the luminescence intensity occurs due to non-radiative competitive channels described by activation energies of ca. 235 meV and 450 meV by using 325 and 390 nm wavelength photons as excitation, respectively. The lifetime of the 5D0 level in these glasses is ca. 2.93 ms. A discussion of the thermal population and de-excitation mechanisms is performed. © 2013 Elsevier B.V.

The crystallization kinetics and phase transformation of a transparent Tb3+-doped lithium-aluminum phosphate glass, prepared by melt quenching, were investigated. The energy associated to the glass transition and the crystallization parameters (activation energy for crystallization and Avrami exponent) were evaluated by different methods using the experimental data obtained by differential thermal analysis performed at different heating rates. Using an isoconversional method to determine the change of the activation energy for crystallization with the fraction of crystallization, it was verified that with the increase in the fraction of crystallization from 0.1 to 0.9, the value of the activation energy decreased slightly from  370 to  310 kJ mol -1 and that the Avrami exponent varied from 0.8 to 1, suggesting a surface crystal growth mechanism. Observation of the microstructural evolution of heat-treated glass samples confirmed a surface crystallization process revealing spherulitic crystals constituted mainly by aluminum metaphosphate. © 2014 Springer Science+Business Media New York.