ABSTRACT: Type specimens (holotypes, neotypes, syntypes, etc.) are of crucial importance because they are the only tangible evidence of the nomenclatural act that supports the understanding of paleobiodiversity. The list of the vertebrate species whose type specimen is based on fossils from Portugal is presented here. We counted 206 species, of which there are 45 bony fishes, 39 Late Jurassic Mammaliamorpha, 33 Cenozoic mammals, 28 non-avian dinosaurs, 25 non-dinosaur reptiles, 11 Cenozoic Aves, 22 Chondrichthyes and three other vertebrates. Except for the Quaternary fossil record, the type specimens can be used as a shortcut for measuring the fossil record and paleobiodiversity through geological time and rock units because they correlate in 95% with the fossil record by epoch in the case-study of fossil vertebrates of Portugal.

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Silk fibroin is a biobased material with excellent biocompatibility and mechanical properties, but its use in bioelectronics is hampered by the difficult dissolution and low intrinsic conductivity. Some ionic liquids are known to dissolve fibroin but removed after fibroin processing. However, ionic liquids and fibroin can cooperatively give rise to functional materials, and there are untapped opportunities in this combination. The dissolution of fibroin, followed by gelation, in designer ionic liquids from the imidazolium chloride family with varied alkyl chain lengths (2–10 carbons) is shown here. The alkyl chain length of the anion has a large impact on fibroin secondary structure which adopts unconventional arrangements, yielding robust gels with distinct hierarchical organization. Furthermore, and due to their remarkable air-stability and ionic conductivity, fibroin ionogels are exploited as active electrical gas sensors in an electronic nose revealing the unravelled possibilities of fibroin in soft and flexible electronics.

Phys. Rev. C 105, 014611 (2022). doi:10.1103/PhysRevC.105.014611

Relative humidity is simultaneously a sensing target and a contaminant in gas and volatile organic compound (VOC) sensing systems, where strategies to control humidity interference are required. An unmet challenge is the creation of gas-sensitive materials where the response to humidity is controlled by the material itself. Here, humidity effects are controlled through the design of gelatin formulations in ionic liquids without and with liquid crystals as electrical and optical sensors, respectively. In this design, the anions [DCA]− and [Cl]− of room temperature ionic liquids from the 1-butyl-3-methylimidazolium family tailor the response to humidity and, subsequently, sensing of VOCs in dry and humid conditions. Due to the combined effect of the materials formulations and sensing mechanisms, changing the anion from [DCA]− to the much more hygroscopic [Cl]−, leads to stronger electrical responses and much weaker optical responses to humidity. Thus, either humidity sensors or humidity-tolerant VOC sensors that do not require sample preconditioning or signal processing to correct humidity impact are obtained. With the wide spread of 3D- and 4D-printing and intelligent devices, the monitoring and tuning of humidity in sustainable biobased materials offers excellent opportunities in e-nose sensing arrays and wearable devices compatible with operation at room conditions.

Abstract Enhancer binding proteins (EBPs) are key players of σ54-regulation that control transcription in response to environmental signals. In the anaerobic microorganism Desulfovibrio vulgaris Hildenborough (DvH), orp operons have been previously shown to be coregulated by σ54-RNA polymerase, the integration host factor IHF and a cognate EBP, OrpR. In this study, ChIP-seq experiments indicated that the OrpR regulon consists of only the two divergent orp operons. In vivo data revealed that (i) OrpR is absolutely required for orp operons transcription, (ii) under anaerobic conditions, OrpR binds on the two dedicated DNA binding sites and leads to high expression levels of the orp operons, (iii) increasing the redox potential of the medium leads to a drastic down-regulation of the orp operons expression. Moreover, combining functional and biophysical studies on the anaerobically purified OrpR leads us to propose that OrpR senses redox potential variations via a redox-sensitive [4Fe?4S]2+ cluster in the sensory PAS domain. Overall, the study herein presents the first characterization of a new Fe?S redox regulator belonging to the σ54-dependent transcriptional regulator family probably advantageously selected by cells adapted to the anaerobic lifestyle to monitor redox stress conditions.

Found in the Upper Jurassic outcrops of Lourinhã, Portugal, and first published in 1997, the Paimogo dinosaur egg clutch is one of Portugal’s most remarkable fossils, with over one hundred eggs preserved in association with embryonic bones, of the allosauroid theropod Lourinhanosaurus. However, many questions about it have remained unanswered, even until the present day. After its discovery, this extraordinary fossil became the keystone of a small local museum, greatly kick-starting regional tourism, while also holding the fossils in trust for future generations to study. More than 20 years later, continually sustained paleontological interest from the public has even given rise to both a highly successful dinosaur theme park in the region and an aspiring UNESCO Geopark. Recently, a multidisciplinary team of preparators, paleontologists, sedimentologists, mineralogists, and geochemists revisited an unopened jacket from the original excavation using an array of techniques to address various questions. Studies are ongoing, but the corpus of information obtained and the methodologies utilized to gather data have offered an opportunity to design an exhibit around the history of the Paimogo clutch, highlighting the scientific methods involved, and asserting the importance of preserving geological heritage for the future, when new tools will doubtlessly become available to provide yet another new look at old fossils. Here, we describe our analytical procedures and present an innovative exhibit designed to introduce to the public the latest advances on the research behind an iconic piece of Portuguese geoheritage, increasing its value both as a research item and as an educational resource.

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We propose a stochastic algorithm for global optimisation of a regular function, possibly unbounded, defined on a bounded set with regular boundary; a function that attains its extremum in the boundary of its domain of definition. The algorithm is determined by a diffusion process that is associated with the function by means of a strictly elliptic operator that ensures an adequate maximum principle. In order to preclude the algorithm to be trapped in a local extremum, we add a pure random search step to the algorithm. We show that an adequate procedure of parallelisation of the algorithm can increase the rate of convergence, thus superseding the main drawback of the addition of the pure random search step.

We propose and study a simple model for microcredit using two sums, with a random number of terms, of identically distributed random variables, the number of terms being Poisson distributed; the first sum accounts for the payments { the payables{ made to the collective vault by the participants and the second sum, subtracted to the first, accounts for the loans received by the participants, the receivables.
Under a global independence hypothesis we define, by mean of moment generating functions, an easily
implementable condition for the sustainability of the collective vault. That is, if, for all the participants and at any time, on average, the sum of the loans is strictly less than the sum of the payments to the collective vault then the probability of the collective vault failing can be made arbitrarily small, provided the loans only start to be accepted after a sufficiently large delay. We present numerical illustrations of collective vaults for exponential and chi-squared distributed random terms. For the practical management of such a collective vault it may be advisable to have loan granting rules that destroy independence of the random terms. We present a first simulation study that shows the effect of such a breaking dependence loan granting rule on maintaining the stability of the collective vault.

We formulate an optimization stochastic algorithm convergence theorem, of Solis and Wets type, and we show several instances of its application to concrete algorithms. In this convergence theorem the algorithm is a sequence of random variables and, in order to describe the increasing flow of information associated to this sequence we define a filtration – or flow of σ -algebras – on the probability space, depending on the sequence of random variables and on the function being optimized. We compare the flow of information of two convergent algorithms by comparing the associated filtrations by means of the Cotter distance of σ-algebras. The main result is that two convergent optimization algorithms have the same information content if both their limit minimization functions generate the full σ-algebra of the probability space.

Since the 1970s, the application of microprocessor in industrial machinery and the development of computer systems have transformed the manufacturing landscape. The rapid integration and automation of production systems have outpaced the development of suitable human design criteria, creating a deepening gap between humans and systems in which human was seen as an important source of errors and disruptions. Today, the situation seems different: the scientific and public debate about the concept of Industry 4.0 has raised awareness about the central role humans have to play in manufacturing systems, the design of which must be considered from the very beginning. The future of industrial systems, as represented by Industry 4.0, will rely on the convergence of several research fields such as Intelligent Manufacturing Systems (IMS), Cyber-Physical Systems (CPS), Internet of Things (IoT), but also socio-technical fields such as social approaches within technical systems. This article deals with different human social dimensions associated with CPS and IoT and focuses on their conceptual evolution regarding automated production systems’ sociability, notably by bringing humans back in the loop. Hereby, this paper aims to take stock of current research trends to show the importance of integrating human operators as a part of a socio-technical system based autonomous and intelligent products or resources. Consequently, different models of sociability as a way to integrate humans in the broad sense and/or the develop future automated production systems have been identified from the literature and analysed.

Regime switching diffusion processes with one or two thresholds and regime switching occurring by a change in the diffusion drift and/or volatility functions parameters of a stochastic differential equation, whose solution defines a continuous time diffusion process, were defined in previous works; the change in regime occurring whenever the trajectory of the process crosses a threshold, possibly with some delay. In this paper we generalise the previous
results by allowing the underlying diffusion process to change from one family of diffusions in one regime to an entirely different one in the other regime; these families of diffusions are characterised by specific functional forms for drift and volatility coefficients depending on parameters. We propose an estimation procedure for all the parameters, namely the thresholds, the delay and, for both regimes, diffusion’s parameters and we apply the introduced estimation procedure to both simulated and real data.

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Journal of Trace Elements in Medicine and Biology, 68 (2021) 126837. doi:10.1016/j.jtemb.2021.126837