Craciunescu, Corneliu M., Karimbi. K. Mahesh, Rui JC Silva, Francisco M. BRAZ FERNANDES, Y. Brechet, E. Clouet, A. Deschamps, A. Finel, and F. Soisson. "
Structural Transitions in a Co2NiGa Ferromagnetic Shape Memory Alloy."
Solid-Solid Phase Transformations in Inorganic Materials, Pts 1-2. 172-174 (2011): 202-207.
Abstractn/a
Dias, Ricardo, João Louren{\c c}o, and Nuno Pregui{\c c}a. "
Efficient and Correct Transactional Memory Programs Combining Snapshot Isolation and Static Analysis."
Proceedings of the 3nd USENIX conference on Hot topics in parallelism (HotPar’11). HotPar’11. Usenix Association, 2011.
AbstractConcurrent programs may suffer from concurrency anomalies that may lead to erroneous and unpredictable program behaviors. To ensure program correctness, these anomalies must be diagnosed and corrected. This paper addresses the detection of both low- and high-level anomalies in the Transactional Memory setting. We propose a static analysis procedure and a framework to address Transactional Memory anomalies. We start by dealing with the classic case of low-level dataraces, identifying concurrent accesses to shared memory cells that are not protected within the scope of a memory transaction. Then, we address the case of high-level dataraces, bringing the programmer’s attention to pairs of memory transactions that were misspecified and should have been combined into a single transaction. Our framework was applied to a set of programs, collected form different sources, containing well known low- and high-level anomalies. The framework demonstrated to be accurate, confirming the effectiveness of using static analysis techniques to precisely identify concurrency anomalies in Transactional Memory programs.
Duarte, Filipe J. S., Snezhana M. Bakalova, Eurico J. Cabrita, and Gil A. Santos. "
Lewis Acid Catalyzed Reactions of Chiral Imidazolidinones and Oxazolidinones: Insights on the Role of the Catalyst."
Journal of Organic Chemistry. 76.17 (2011): 6997-7004.
AbstractThe mechanism proposed by Evans to justify the selectivity obtained in Lewis acid catalyzed Diels-Alder reactions of cyclopentadiene with acyloxazolidinones has been generalized and used in the rationalization of selectivities obtained in many other systems. However, we recently proposed an alternative mechanism, on the basis of open-chain mono- and bicomplexes, that avoids the need for chelates and explains the selectivity obtained by Evans. In this manuscript we apply our proposal to the catalyzed conjugated addition of amines to acylimidazolidinones, reported by Cardillo, and we clearly show that aluminum chelates are not involved in the reaction, as they induce no selectivity, while Cardillo observed high experimental selectivities. Our data equally show that bicomplexes with carbonyl parallel orientation, proposed by Cardillo to justify the experimental selectivity with nonchelating Lewis acids, indeed induce the opposite selectivity and have also to be dismissed. On the other hand, our mechanistic proposal allows for the full rationalization of the data obtained by Cardillo with aluminum, boron, or zinc Lewis acids and supports our previous proposal on DA cycloadditions of dienes to Evans chiral auxiliary derivatives.
Baptista, Pedro V., Gonçalo Doria, Pedro Quaresma, Miguel Cavadas, Cristina S. Neves, Inês Gomes, Peter Eaton, Eulália Pereira, and Ricardo Franco. "
Nanoparticles in Molecular Diagnostics."
Progress in Molecular Biology and Translational Science: Nanoparticles in Translational Science and Medicine. Elsevier, 2011. 427-488.