In this work we report the role of thickness on electrochromic behavior of nickel oxide (NiO) films deposited by e-beam evaporation at room temperature on ITO-coated glass. The structure and morphology of films with thicknesses between 100 and 500 nm were analyzed and then correlated with electrochemical response and transmittance modulation when immersed in 0.5 M LiClO4–PC electrolyte. The NiO exhibits an anodic coloration, reaching for the thickest film a transmittance modulation of 66% between colored and bleached state, at 630 nm, with a color efficiency of 55 cm2 C−1. Very fast switch between states was obtained, where coloration and bleaching times are 3.6 s cm−2 and 1.4 s cm−2, respectively.

In 1994 fib Commission 6: Prefabrication edited a successful Planning and Design Handbook that ran to approximately 45,000 copies and was published in Spanish and German.Nearly 20 years later Bulletin 74 brings that first publication up to date. It offers a synthesis of the latest structural design knowledge about precast building structures against the background of 21st century technological innovations in materials, production and construction. With it, we hope to help architects and engineers achieve a full understanding of precast concrete building structures, the possibilities they offer and their specific design philosophy. It was principally written for non-seismic structures.

The handbook contains eleven chapters, each dealing with a specific aspect of precast building structures.
The first chapter of the handbook highlights best practice opportunities that will enable architects, design engineers and contractors to work together towards finding efficient solutions, which is something unique to precast concrete buildings.
The second chapter offers basic design recommendations that take into account the possibilities, restrictions and advantages of precast concrete, along with its detailing, manufacture, transport, erection and serviceability stages.
Chapter three describes the precast solutions for the most common types of buildings such as offices, sports stadiums, residential buildings, hotels, industrial warehouses and car parks. Different application possibilities are explored to teach us which types of precast units are commonly used in all those situations.
Chapter four covers the basic design principles and systems related to stability. Precast concrete structures should be designed according to a specific stability concept, unlike cast in-situ structures.
Chapter five discusses structural connections.
Chapters six to nine address the four most commonly used systems or subsystems of precast concrete in buildings, namely, portal and skeletal structures, wall-frame structures, floor and roof structures and architectural concrete facades.
In chapter ten the design and detailing of a number of specific construction details in precast elements are discussed, for example, supports, corbels, openings and cutouts in the units, special features related to the detailing of the reinforcement, and so forth.
Chapter eleven gives guidelines for the fire design of precast concrete structures. The handbook concludes with a list of references to good literature on precast concrete construction.

O desenvolvimento da engenharia de estruturas tem tido grandes avanços nas últimas décadas, baseados em novos meios de cálculo e na investigação em novos materiais e tecnologias a eles associadas. Por sua vez, as atividades de reparação e reforço têm vindo a incrementar devido ao envelhecimento e à degradação das estruturas de betão, o que consequentemente tem dado origem ao aparecimento de novos materiais e tecnologias de reparação e reforço de estruturas. A utilização destes novos materiais na construção tem vindo a substituir outros materiais e técnicas existentes, requerendo, no entanto, mais estudos sobre o seu real comportamento quer em termos de caracteristicas mecânicas quer em termos de durabilidade.

Gravity loads can affect a reinforced concrete structure’s response to seismic actions, however, traditional procedures for testing the beam behaviour do not take this effect into consideration. An experimental campaign was carried out in order to assess the influence of the gravity load on RC beam connection to the column subjected to cyclic loading. The experiments included the imposition of a conventional quasi-static test protocol based on the imposition of a reverse cyclic displacement history and of an alternative cyclic test procedure starting from the gravity load effects. The test results are presented, compared and analysed in this paper. The imposition of a cyclic test procedure that included the gravity loads effects on the RC beam ends reproduces the demands on the beams’ critical zones more realistically than the traditional procedure. The consideration of the vertical load effects in the test procedure led to an accumulation of negative (hogging) deformation. This phenomenon is sustained with the behaviour of a portal frame system under cyclic loads subject to a significant level of the vertical load, leading to the formation of unidirectional plastic hinges. In addition, the hysteretic behaviour of the RC beam ends tested was simulated numerically using the nonlinear structural analysis software – OpenSees. The beam–column model simulates the global element behaviour very well, as there is a reasonable approximation to the hysteretic loops obtained experimentally.

Sandstone building stones are important in the building elements of Portuguese monuments, particularly in the western and southern regions. Alveolization due to salt crystallization was the most important degradation pattern found in the old sandstone façades of St. Leonardo’s Church, a Portuguese monument built in Atouguia da Baleia village in the Middle Age. Its sandstone façades have a widespread distribution of deep and large alveolization patterns mainly on portals and vaults that appeared as a result of the past and present vicinity of seashore. In this paper a summary of conservation interventions carried out in the past century in St. Leonardo’s Church is presented, as well as a summary of the studies carried out in the last decade. Then the degradation patterns on the sandstone walls of St. Leonard’s Church are shown and finally the evolution of the alveolization occurred on the sandstone walls over the last sixty to seventy years is analysed. Visual inspection of sandstone walls is compared with a survey performed by laser scanning, which seems to be a powerful technology to carry out 3D geometric modelling of the building elements of stone monuments and also the 3D mapping of stone degradation patterns.

Sandstones are very important in the building elements of world’s historical and cultural heritage. The façades of St. Leonard’s church in Atouguia da Baleia village in western region of Portugal are an outstanding example of the effect of alveolization on going for several centuries. In Middle ages there was an harbour and a sodium chloride rich environment near this church was responsible for this significant stone degradation pattern.
A new approach of consolidating products application on stone walls façades based on Karsten pipe using total head to allow full absorption of stone was followed.
Experimental research, based on physical and mechanical tests, was carried out on selected representative samples of a variety of sandstones on monuments treated with ethyl silicates in order to assess the effectiveness and harmfulness of these treatments.
The comparison of results between traditional immersion applications and Karsten pipe’s based procedure on stone monument indicate the potential viability of this new approach when difficult conditions of consolidating products’ absorption occurs on stone monuments.

Experimental research was carried out about into ethyl silicate applications on sandstone samples. Consolidation was assessed by drilling strength, impregnation depth and also monotonic and cyclic uniaxial compressive tests in order to evaluate the compressive mechanical behaviour of treated sandstone. The stress–strain compression diagrams showed a significant increase in the values of mechanical parameters after consolidation treatments. The difference in compressive strength values between monotonic and cyclic compression disappears after the consolidation treatments. An equation of consolidation effect was obtained from an analytical model by means of compressive behaviour assessed by stress–strain diagrams. These sandstone samples have values of porosity similar to the more weathered variety of sandstone found in facades of monuments in the village of Atouguia da Baleia, in the western region of Portugal. The most important degradation pattern found on sandstone building stones is alveolization caused by salt crystallization since the Middle Ages.

The use of Fibre Reinforced Polymers (FRP) has recently become widespread in the construction industry. However, some drawbacks related to premature debonding of the FRP composites from the bonded substrates have been identified. One of the solutions proposed is the implementation of mechanical anchorage systems. Although some design guidelines have been developed, the actual knowledge continues to be rather limited. Thus, designers and researchers have not yet achieved any consensus on the efficiency of any particular anchor device in delaying or preventing the premature debonding failure mode that can occur in Externally Bonded Reinforcement (EBR) systems. This paper studies the debonding phenomenon of FRP anchoring systems with a linear variable width, with a numerical analysis based on the Distinct Element Method (DEM). Combined systems with constant and variable width are also discussed. The FRP-to-parent material interfaces are modelled with a rigid-linear softening bond–slip law. The numerical results showed that it is possible to attain the FRP rupture force with a variable width solution. This solution is particularly attractive when the bonded length is shorter than the effective bonded length because the strength of the interface can be highly incremented.

Apresentam-se neste artigo os resultados dos ensaios realizados à escala real de um conjunto de vigas de betão armado com secção em T, levados a cabo para avaliar o desempenho das armaduras de aço inoxidável no reforço à flexão de vigas de betão armado com armaduras pós-instaladas aplicadas com as técnicas de reforço EBR (Externally Bonded Reinforcement), NSM (Near Surface Mounted) e EBR com ancoragens metálicas nas extremidades. Os ensaios realizados demonstraram que as técnicas de reforço utilizadas permitem aumentar a rigidez à flexão em regime elástico. Porém, a viga reforçada através da técnica EBR teve uma rotura prematura antes de atingir o valor da carga de cedência da viga não reforçada. Já as vigas reforçadas com as técnicas NSM e EBR com ancoragens mecânicas superaram o valor da carga de cedência da viga de referência, e as ancoragens mecânicas proporcionaram bastante ductilidade à viga reforçada com esta técnica.

Pulsed field gradient spin echo high resolution magic angle spinning nuclear magnetic resonance spectroscopy is a powerful technique to characterize confined biosystems. We used this approach to assess the diffusion of solvent and reaction species within sol–gel matrices differing in enzyme loading.

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Molybdenum and tungsten enzymes require specific chaperones for folding and cofactor insertion. PaoD is the chaperone of the periplasmic aldehyde oxidoreductase PaoABC. It is the last gene in the paoABCD operon in Escherichia coli and its presence is crucial for obtaining mature enzyme. PaoD is an unstable, 35 kDa, protein. Our biochemical studies showed that it is a dimer in solution with a tendency to form large aggregates, especially after freezing/thawing cycles. In order to improve stability, PaoD was thawed in the presence of two ionic liquids [C4mim]Cl and [C2OHmim]PF6 and no protein precipitation was observed. This allowed protein concentration and crystallization using polyethylene glycol or ammonium sulfate as precipitating agents. Saturation transfer difference – nuclear magnetic resonance (STD-NMR) experiments have also been performed in order to investigate the effect of the ionic liquids in the stabilization process, showing a clear interaction between the acidic ring protons of the cation and, most likely, negatively charged residues at the protein surface. DLS assays also show a reduction of the overall size of the protein aggregates in presence of ionic liquids. Furthermore, cofactor binding studies on PaoD showed that the protein is able to discriminate between molybdenum and tungsten bound to the molybdenum cofactor, since only a Mo-MPT form of the cofactor remained bound to PaoD.

Virtual environments are an increasing trend in today’s society. In this scope, the avatar is the representation of the user in the virtual world. However, that relationship lacks empirical studies regarding the nature of the interaction between avatars and human beings. For that purpose it was studied how the avatar’s modeled morphology and dynamics affect its control by the user. An experiment was conducted to measure telepresence and ownership on participants who used a Kinect Natural User Interface (NUI). The body ownership of different avatars was assessed through a behavioral parameter, based on the concept of affordances, and a questionnaire of presence. The results show that the feelings of telepresence and ownership seem to be greater when the kinematics and the avatar’s proportions are closer to those of the user.

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