http://docentes.fct.unl.pt/lblm/files/chemrev-2014-114-5273_0.pdf

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Previous researches on punching of post-tensioned slabs have shown a number of phenomena significantly influencing their strength and behaviour. However, no general agreement is yet found on a physical theory (either in codes of practice or in design models) suitably describing the influence of prestressing and how should it be accounted on the punching shear behaviour. In this paper, the authors present the results of tests on 15 slabs (3000. ??. 3000. ??. 250. mm) tested to failure under different loading conditions. The aim of the tests was to investigate in a separate manner the different actions induced by prestressing on the punching shear strength (in-plane forces, bending moments and bonded tendons). These results are finally investigated on the basis of the physical model of the Critical Shear Crack Theory. The fundamentals of this theory are presented and adapted to post-tensioned slabs, providing a rational explanation of the observed phenomena and measured strengths. ?? 2014 Elsevier Ltd.

The lipoxygenase (LOX) products have been identified as mediators of a series of inflammatory diseases, namely rheumatoid arthritis, inflammatory bowel disease, psoriasis, allergic rhinitis, atherosclerosis and certain types of cancer. Hence, LOX inhibitors are of interest for the modulation of these phenomena and resolution of the inflammatory processes. During LOX activity, peroxyl radical complexes are part of the reaction and may function as sources of free radicals. Thus antioxidants, such as flavonoids, capable of inhibiting lipid peroxidation and scavenging free radicals, may act as LOX inhibitors. The aim of this work was to assess the structure–activity relationship among a series of flavonoids concerning 5-LOX inhibition, through a systematic study of the inhibition of the formation of LTB4 in human neutrophils. The type of inhibition of the flavonoids was further studied using soybean LOX, type I, and Saturation Transfer Difference 1H NMR (STD-1H NMR) was used to characterize the binding epitopes of the compounds to LOX-1. The obtained results reinforce flavonoids as effective inhibitors of LTB4 production in human neutrophils. It was also possible to establish a structure/activity relationship for the inhibitory activity and the type of inhibition.

This book contains the outcome of the 9th IFIP WG 5.5 International Summer Workshop on Multimodal Interfaces, eNTERFACE 2013, held in Lisbon, Portugal, in July/August 2013. The 9 papers included in this book represent the results of a 4-week workshop, where senior and junior researchers worked together on projects tackling new trends in human-machine interaction (HMI). The papers are organized in two topical sections. The first one presents different proposals focused on some fundamental issues regarding multimodal interactions, i.e., telepresence, speech synthesis and interactive modeling. The second is a set of development examples in key areas of HMI applications, i.e., education, entertainment and assistive technologies.

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The thermal behavior and transport properties of several ion jellys (IJs), a composite that results from the combination of gelatin with an ionic liquid (IL), were investigated by dielectric relaxation spectroscopy (DRS), differential scanning calorimetry (DSC), and pulsed field gradient nuclear magnetic resonance spectroscopy (PFG NMR). Four different ILs containing the dicyanamide anion were used: 1-butyl-3-methylimidazolium dicyanamide (BMIMDCA), 1-ethyl-3-methylimidazolium dicyanamide (EMIMDCA), 1-butyl-1-methylpyrrolidinium dicyanamide (BMPyrDCA), and 1-butylpyridinium dicyanamide (BPyDCA); the bulk ILs were also investigated for comparison. A glass transition was detected by DSC for all materials, ILs and IJs, allowing them to be classified as glass formers. Additionally, an increase in the glass transition temperature upon dehydration was observed with a greater extent for IJs, attributed to a greater hindrance imposed by the gelatin matrix after water removal, rendering the IL less mobile. While crystallization is observed for some ILs with negligible water content, it was never detected for any IJ upon thermal cycling, which persist always as fully amorphous materials. From DRS measurements, conductivity and diffusion coefficients for both cations (D+) and anions (D–) were extracted. D+ values obtained by DRS reveal excellent agreement with those obtained from PFG NMR direct measurements, obeying the same VFTH equation over a large temperature range (ΔT ≈ 150 K) within which D+ varies around 10 decades. At temperatures close to room temperature, the IJs exhibit D values comparable to the most hydrated (9%) ILs. The IJ derived from EMIMDCA possesses the highest conductivity and diffusion coefficient, respectively, 10–2 S·cm–1 and 10–10 m2·s–1. For BMPyrDCA the relaxational behavior was analyzed through the complex permittivity and modulus formalism allowing the assignment of the detected secondary relaxation to a Johari–Goldstein process. Besides the relevant information on the more fundamental nature providing physicochemical details on ILs behavior, new doorways are opened for practical applications by using IJ as a strategy to produce novel and stable electrolytes for different electrochemical devices.

Sign language is the hearing impaired form of communicating with other people, including listeners. Most cases, impaired people have learned sign language form childhood. The problem arises when a listener comes in contact with an impaired person. For instances, if a couple has a child which is impaired, the parents find a challenge to learn the sign language. In this article, a new playful approach to assist the listeners to learn sign language is proposed. This proposal is a serious game composed of two modes: School-mode and Competition-mode. The first offers a virtual school where the user learns to sign letters and the second offers an environment towards applying the learned letters. Behind the scenes, the proposal contains a sign language recognition system, based on three modules: 1 – the standardization of the Kinect depth camera data; 2 – a gesture library relying on the standardized data; and 3 – the real-time recognition of gestures. A prototype was developed – Kinect-Sign – and tested in a Portuguese Sign-Language school and on eNTERFACE’13 resulting in a joyful acceptance of the approach.

MATHEMATICS TEACHING IN EDUCATION AND TRAINING COURSES
H. Rocha

Universidade Nova de Lisboa, Faculdade de Ciências e Tecnologia (PORTUGAL)

Education and Training Courses have been specifically designed to the high number of young people in a situation of school dropout and in transition to working life, particularly those who enter the labor market early with insufficient levels of schooling and professional training. Mathematics is one of the curriculum components of these courses, for its contribution to the exercise of citizenship in a democratic society. Being an important part of the cultural legacy of our society is too often seen by students as a source of exclusion. It is known that young people who enter these courses often had an experience of underachievement in the discipline, what justifies that motivating students is at once the great challenge faced by the teacher. The program suggests taking a more concrete and linked to reality approach, allowing students to learn to recognize the mathematics in the world around them and using technology to promote that learning. However, it is the teacher who is responsible for managing its implementation, shaping the learning situations and integrating them in a coherent and articulated way in the specific course that students attend. In what concerns to assessment, the program also takes into account the usual characteristics of the students. Thus, the assessment includes a strong appreciation of students’ work, its presentation and discussion and further improvement of that work. The directions given to the teacher diverge from the traditional option of the evaluation test, providing guidelines to the form that each evaluation can take depending on the contents in study. However, once again, the teacher's role in curriculum management is not neglected, being valued the adequacy of proposals to the characteristics of the students.
The study presented here had as its main goal to analyze and understand the choices made by the teacher during the different stages of his practice, giving attention to the dilemmas he faced and to the reasons he took into account when making decisions.

The study adopts a qualitative and interpretative methodological approach, undertaking one teacher case study. Data collection included semi-structured interviews, classroom observation and document collection. Data analysis was based on the evidence gathered in the light of the problem under study.

The conclusions of the study point to the important role of technology and suggest that the reduction of prerequisites, the intention of taking into account the students’ interests and the desire of improving students culture is central in what concerns to task selection; while the active involvement of students characterized the implementation of the classes. The dilemmas faced by the teacher focus mainly on the relative importance and on the demanding level that he should give to each content, as well as the articulation that he should promote between formal and intuitive knowledge. In what concerns to assessment, the results achieved highlight the impact that students ideas can have on teacher’s practice, conducting to the inclusion of tests as an assessment element, against the teacher’s intentions.

keywords: education and training courses, mathematics, innovation, technology.

This paper showcases MDSheet, a framework aimed at improving the engineering of spreadsheets. This framework is model-driven, and has been fully integrated under a spreadsheet system. Also, its practical interest has been demonstrated by several empirical studies.

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