We analysed the changes in the metabolites of Lupinus albus organs (leaf-blades, petioles, apexes, hypocotyls and roots) as a consequence of B deficiency. The deficiency did not affect malate concentration and induced only minor changes in the sugar content, suggesting that the carbohydrate metabolism is little affected by the deficiency. Contrarily, marked changes in the content of free amino acids were observed, with some specific variations associated with the different organs. These changes indicate that various aspects of metabolism implicated in the amino acid accumulation were affected by B deficiency. Most of the detected changes appear to have implications with some stress responses or signalling processes. Asparagine and proline that increase in many stresses also accumulated in petioles, apexes and hypocotyls. Accumulation of gamma-aminobutyric acid shunt amino acids, indicative of production of reactive oxygen species, occurs in the same three organs and also the roots. The increase in the branched-chain amino acids, observed in all organs, suggests the involvement of B with the cytoskeleton, whereas glycine decrease in leaf-blades and active growing organs (apexes and roots) could be associated with the proposed role of this amino acids in plant signalling in processes that might be associated with the decreased growth rates observed in B deficiency. Despite the admitted importance of free amino acids in plant metabolism, the available information on this matter is scarce. So our results bring new information concerning the effects of B deficiency in the metabolism of the several L. albus organs.

The European Union directive for electric and electronic waste, published in 2003, enforced all European countries to meet some targets concerning the recycling and recovery of these products. This directive was transposed to the Portuguese legislation in 2004. Following this, a group of EEE producers set up an organization (Amb3e) whose mission was to design and manage a nationwide recovery network for WEEE, which will be the subject matter of this work. A generic MILP model is proposed to represent this network, which is applied to its design and planning, where the best locations for collection and sorting centres are chosen simultaneously with the definition of a tactical network planning. Several analyses are performed to provide further insights regarding the selection of these alternative locations. The results gave support to the company strategic expansion plans for a high number of centres to be opened and to their location near the major WEEE sources.

Theoretical expressions for ionization cross sections by electron impact based on the binary encounter Bethe (BEB) model, valid from ionization threshold up to relativistic energies, are proposed.The new modified BEB (MBEB) and its relativistic counterpart (MRBEB) expressions are simpler than the BEB (nonrelativistic and relativistic) expressions because they require only one atomic parameter, namely the binding energy of the electrons to be ionized, and use only one scaling term for the ionization of all sub-shells.The new models are used to calculate the K-, L- and M-shell ionization cross sections by electron impact for several atoms with Z from 6 to 83.Comparisons with all, to the best of our knowledge, available experimental data show that this model is as good or better than other models, with less complexity.

We prove sufficient conditions for the boundedness of the maximal operator on variable Lebesgue spaces with weights \(\varphi_{t,\gamma}(\tau)=|(\tau-t)^\gamma|\), where \(\gamma\) is a complex number, over arbitrary Carleson curves. If the curve has different spirality indices at the point $t$ and \(\gamma\) is not real, then \(\varphi_{t,\gamma}\) is an oscillating weight lying beyond the class of radial oscillating weights considered recently by V. Kokilashvili, N. Samko, and S. Samko.

The retrofit of reinforced concrete columns with FRP jackets has received considerable attention in recent years. The advantages of this technique compared to other similar techniques include the high strength-weight and stiffness-weight ratios of FRP (Fibre Reinforced Plastics), the strength and ductility increase of RC columns confined with FRP jackets as well as the fact that FRP external shells prevent or mitigate environmental degradation of the concrete and consequent corrosion of the steel reinforcement. Furthermore, this method also reduces the column transversal deformation and prevents the buckling of longitudinal reinforcement. Twenty five experimental tests were carried out on reinforced concrete columns confined with CFRP composites, and subjected to axial monotonic compression. In order to evaluate the influence of several parameters on the mechanical behavior of the columns, the height of the columns was maintained, while changing other parameters: the diameter of the columns, the type of material (plain or reinforced concrete), the steel hoop spacing of the RC columns and the number of CFRP layers. Predictive equations, based on the experimental analysis, are proposed to estimate the compressive strength of the confined concrete, the maximum axial load and the axial or the lateral failure strain of circular RC columns jacketed with CFRP. A stress-strain model for CFRP confined concrete in compression, which considers the effect of the CFRP and the transversal reinforcement on the confined compressive strength of the column is also proposed. The curves, axial load versus axial or lateral strain of the RC column, are simulated based on the stress-strain model and include the longitudinal reinforcement effect. The results demonstrate that the model and the predictive equations represent very well the axial compression behavior of RC circular columns confined with CFRP. The applicability of this model to a large spectrum of RC column dimensions is its main advantage.

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