{We report the preparation and spectro-electrochemical characterization of electrochromic devices (ECD) combining inkjet-printed WO3 as cathode and electro-deposited V2O5 as anode. ECD were prepared for the first time with an optimized formulation of gel polymer electrolyte based on Bisphenol A ethoxylate dimethacrylate and Poly(ethylene glycol) methyl ether methacrylate (BEMA/PEGMA) encompassing the Room Temperature Ionic Liquid (RTIL, 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide) as solvent. The UV-VIS spectrum of ECD was recorded at different potentials during Li+ insertion and de-insertion; additionally the Percent Trasmittance (T%) of ECD vs. time was investigated during repeated bleaching and coloring cycles allowing thus the estimation of switching times and device stability. Due to the lower ionic conductivity and the apparent superior solvent permeability within WO3 active layer, RTIL containing ECD showed slower switching times, but higher contrast with respect to the similar ones with EC/DEC as solvent. These results indicate that the ECD containing environment-friendly RTIL electrolytes are suitable for applications requiring high contrast, high safety and moderately fast switching times.}

{We use resonant photoemission spectroscopy (resPES) to study the electronic properties of amorphous ZnO (a-ZnO) layers. We report on the core levels, the valence band (VB) PES data, and the X-ray absorption (XAS) data which we use for the conduction band (CB) density of states. From these results we are able to derive the partial density of states (pDOS) of O2p and Zn4s4p states in the VB and CB, respectively as well as a band scheme. At the O1s resonance we observe a band of localized defect states which is located between the Fermi energy and the CBM. At the Zn2p edge the XAS data indicate that localized Zn4s4p states are involved in the DOS starting already at the Fermi energy. (C) 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim}

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The CREMA collaboration is pursuing a measurement of the ground-state hyperfine splitting (HFS) in muonic hydrogen (μp) with 1 ppm accuracy by means of pulsed laser spectroscopy to determine the two-photon-exchange contribution with 2×10-4 relative accuracy. In the proposed experiment, the μp atom undergoes a laser excitation from the singlet hyperfine state to the triplet hyperfine state, then is quenched back to the singlet state by an inelastic collision with a H2 molecule. The resulting increase of kinetic energy after the collisional deexcitation is used as a signature of a successful laser transition between hyperfine states. In this paper, we calculate the combined probability that a μp atom initially in the singlet hyperfine state undergoes a laser excitation to the triplet state followed by a collisional-induced deexcitation back to the singlet state. This combined probability has been computed using the optical Bloch equations including the inelastic and elastic collisions. Omitting the decoherence effects caused by the laser bandwidth and collisions would overestimate the transition probability by more than a factor of two in the experimental conditions. Moreover, we also account for Doppler effects and provide the matrix element, the saturation fluence, the elastic and inelastic collision rates for the singlet and triplet states, and the resonance linewidth. This calculation thus quantifies one of the key unknowns of the HFS experiment, leading to a precise definition of the requirements for the laser system and to an optimization of the hydrogen gas target where μp is formed and the laser spectroscopy will occur.

Sauropod dinosaurs are well known for their massive sizes and long necks and tails. Among sauropods, flagellicaudatan dinosaurs are characterized by extreme tail elongation, which has led to hypotheses regarding tail function, often compared to a whip. Here, we analyse the dynamics of motion of a 3D model of an apatosaurine flagellicaudatan tail using multibody simulation and quantify the stress-bearing capabilities of the associated soft tissues. Such an elongated and slender structure would allow achieving tip velocities in the order of 30 m/s, or 100 km/h, far slower than the speed of sound, due to the combined effect of friction of the musculature and articulations, as well as aerodynamic drag. The material properties of the skin, tendons, and ligaments also support such evidence, proving that in life, the tail would not have withstood the stresses imposed by travelling at the speed of sound, irrespective of the conjectural ‘popper’, a hypothetical soft tissue structure analogue to the terminal portion of a bullwhip able to surpass the speed of sound.

Externally bonded fiber-reinforced polymer (FRP) composites have been widely used for the strengthening and repairing of reinforced concrete (RC) beams. Existing studies have denstrated that the full-range behavior and the associated debonding mechanism of the FRP-to-concrete interface between two adjacent cracks in the FRP-plated RC beam are different from those of the pull-off bonded joint. Moreover, the bond behavior between the FRP and the concrete may be affected by interfacial thermal stresses induced by the service temperature variations (i.e., the thermal loadings). Based on a fully reversible bilinear bond-slip model, this paper presents an analytical study to investigate the full-range deformation behavior of the FRP-to-concrete interface between two adjacent cracks under combined mechanical and thermal loadings. The analytical results have indicated that the thermal loadings may significantly influence the full-range deformation behavior and the axial stress distribution of the FRP plate, although the material properties of concrete, adhesive, and FRP are assumed to be not affected by the service temperature variations. A temperature increase leads to an increase in the ultimate load of the bond interface and vice versa. A finite element (FE) model with different considerations of the bondline damage is developed to verify the proposed analytical solution. The reliability of the proposed analytical solution is then validated by the comparisons between the analytical results and the corresponding predictions provided by the FE model. © 2022 Elsevier Ltd

Debonding failures of FRP have been frequently observed in laboratory tests of reinforced concrete (RC) beams flexurally-strengthened with near-surface mounted (NSM) fibre-reinforced polymer (FRP). A number of numerical and theoretical studies have been carried out to predict debonding failures in NSM FRP-strengthened beams, and several strength models have also been proposed. The existing studies, however, were all based on the scenario of a simply supported beam tested under one or two-point loading, while the influence of load distribution has not yet been investigated. This paper presents the first ever study into the effect of load distribution on the behaviour of NSM FRP-strengthened RC beams. A series of large-scale RC beams flexurally-strengthened with NSM FRP strips were first tested under different load uniformities; then a finite element (FE) model, which can give close predictions to the behaviour of such strengthened beams, was developed; finally, the proposed FE model was utilized to investigate the influence of bond length of NSM FRP on the load uniformity effect. It was found that the load uniformity has a significant effect on the beam behaviour, and the degree of this effect varies with the bond length of NSM FRP. © 2021 Elsevier Ltd

In this paper, the influence of salt fog and ambient condition exposure on CFRP-to-steel bonded joints (CSJs) with a near end mechanical anchorage was studied. The tests of the CSJs were carried out with a monotonic loading history respectively with and without a near end mechanical anchorage both unaged and after being exposed to the ageing conditions. The results revealed failures in the adhesive for some CSJs with a near end mechanical anchorage, among which also exhibited the best bond performance both in aged and unaged specimens. Due to the high state of degradation after ageing exposure, local damage of the CFRP located at the gap position of the CSJs was induced by a torsion action during the fixation of the specimen in the tensile machine even prior to the testing, which caused, although locally, severe delamination of the CFRP of the aged CSJs. From the torsion test results, a decrease in the torsional capacity of the CFRP after aging revealed the degradation of the carbon fiber-to-matrix interface. Additional results reflected that a drop in the initial stiffness of the load vs. slip relationship can be observed, caused by a pre-crack with a length of 30 mm in the CSJs. © 2021 Elsevier Ltd

The use of optic measurements such as digital image correlation to take strain measurements of fibre-reinforced polymers bonded to a substrate has been on the increase recently. This technique has proven to be useful to fully characterize the bond behaviour between two materials. Although modern digital cameras can take high-definition photos, this task is far from simple due to the tiny displacements that need to be measured. Consequently, digital image correlation measurements lead to relative errors that, at an initial stage of the debonding process, are higher than those calculated close to the debonding of the fibre-reinforced polymer from the substrate. This study aims to evaluate and analyse the use of the digital image correlation technique on the bond between carbon fibre-reinforced polymer laminates and timber when subjected to a pull-out load consistent with fracture Mode II. To allow the quantification of the relative errors obtained from the digital image correlation measurements during the full debonding process, several strain gauges were used to measure the strains in the carbon fibre-reinforced polymer composite. The accuracy of the digital image correlation measurements is analysed by comparing it with those obtained from the strain gauges, which is a very well-established measuring technique. Another contribution of this study is to check the versatility of the digital image correlation measurements on a broader range of situations. To that end, several timber prisms were bonded with seven different bonding techniques with and without the installation of a mechanical anchorage at the carbon fibre-reinforced polymer unpulled end. The results showed that the digital image correlation technique was able to track the slips calculated from the strain gauge measurements until the debonding load, but after that, some difficulties to measure the displacements of the anchored carbon fibre-reinforced polymer-to-timber joints were detected. The digital image correlation technique also over predicted bond stresses when compared with those taken from the strain gauges, which led to bond–slip relationships with higher bond stresses. © The Author(s) 2021.

Phys. Rev. C 105, 014611 (2022). doi:10.1103/PhysRevC.105.014611

Mechanical anchorage devices have the potential to efficiently improve the bond behavior of Carbon Fiber-Reinforced Polymers (CFRP) Externally Bonded (EB) onto steel with an adhesive. Existing relevant studies, however, have been very limited. Against this background, experimental and numerical studies on the double overlapped CFRP-to-steel bonded joints with an end mechanical anchorage were carried out in the present study. Two types of CFRP laminates (i.e., SIKA CFRP and the other type made in Harbin Institute of Technology – HIT) were used in the bond tests, with or without end mechanical anchorage devices. The test results showed that the end mechanical anchorage had marginal effect on the bond-slip relationship between EB CFRP and steel as well as debonding load, but could increase the ultimate load. It was also found that CFRP laminate from HIT had a better bond performance than that from SIKA, in terms of both debonding load and ultimate load. Using ABAQUS, Finite Element (FE) model was established on such bonded joints and the accuracy was verified with test results. The verified FE model was adopted in a parametric study to further clarify the effect of key parameters on the bond behavior of such bonded joints. © 2021 Elsevier Ltd

Nowadays, the use of the Digital Image Correlation (DIC) technique has spread and it is being used in several engineering areas to measure displacements. The available data obtained from the DIC measurement to evaluate the bond performance between a Carbon fibre Reinforced Polymer (CFRP) externally bonded to a timber substrate is scarce. From the existing data obtained with other materials, this contactless technique revealed to be quite useful but its accuracy with other well-established techniques, such as the use of electric strain gauges is not well understood yet. Therefore, the current work aims to study the accuracy of 2D DIC measurements with the measurements obtained from the use of strain gauges within a low-cost perspective. To that end, several CFRP-to-timber bonded joints were tested under the single-lap shear test and different bonding techniques were considered as well. Some flaws intrinsically derived from the DIC measurements that complicate the bond assessment, such as the fluctuations in the generated displacements field, are identified, and to bypass this problem a new methodology is proposed. This new methodology is based on two different closed-form solutions that, after defining the local and global bond behaviours of different CFRP-to-timber bonded joints, allowed to eliminate the fluctuations found from the DIC measurements, facilitating the estimation and the comprehension of the full debonding process of the CFRP-to-timber joints, which was achieved with a good proximity to the homologous debonding process derived from the strain gauge measurements. © 2020

Nuclear Inst. and Methods in Physics Research, A, 1014 (2021) 165701. doi:10.1016/j.nima.2021.165701

Physics Letters B, 809 (2020) 135748. 10.1016/j.physletb.2020.135748

Warm mix asphalt (WMA) is produced by a variety of technologies at lower temperatures that enable to gain important environmental and social benefits and, in consequence, to contribute to a more sustainable transportation infrastructure. The producer usually defines the temperatures used in WMA production. However, some references suggest the increase of temperature in order to allow a longer time to transport or to compact in cases of unfavourable weather conditions, mainly under low temperatures. The objective of this paper is to analyse the feasibility of producing WMA at the same temperatures of hot mix asphalt (HMA) guaranteeing an adequate compaction, and final performance in service. The paper describes a laboratory study to investigate the properties of a WMA using different additives and varying the mixing and compaction temperatures. The effect of production temperatures on the performance of the WMA was evaluated through binder drainage (production phase), volumetric properties (compaction phase), and resistance to permanent deformation (service phase). The paper also presents a numerical study on the time available for paving WMA under unfavourable climatic conditions. Results demonstrated that it is possible to produce WMA at high temperatures without problems of binder drainage, during transport, and of performance in service if adequate compaction is achieved. In fact, the production temperatures influenced the compaction phase. However, it is possible to increase the temperature without negatively affecting the required volumetric properties. The rut depth of the permanent deformation test was mostly influenced by the air-voids of the compacted WMA and the binder. From the numerical study, it was concluded that the time available for in situ compaction increased substantially when WMA was paved at higher temperature. However, in cases of low air temperature and thin layer, the increase of temperature may not be sufficient to obtain the desired level of density or air-voids.

We report on measurements of the Kβ diagram, valence-to-core (VtC), and hypersatellite X-ray spectra induced in metallic Cr by photon single and double K-shell ionization. The experiment was carried out at the Stanford Synchrotron Radiation Lightsource using the seven-crystal Johann-type hard X-ray spectrometer of the beamline 6-2. For the Kβ diagram and VtC transitions, the present study confirms the line shape features observed in previous works, whereas the K h β hypersatellite transition was found to exhibit a complex spectral line shape and a characteristic low-energy shoulder. The energy shift of the hypersatellite relative to the parent diagram line was deduced from the measurements and compared with the result of extensive multiconfiguration Dirac–Fock (MCDF) calculations. A very good agreement between experiment and theory was found. The MCDF calculations were also used to compute the theoretical line shape of the hypersatellite. A satisfactory agreement was obtained between the overall shapes of the experimental and theoretical spectra, but deviations were observed on the low- and high-energy flanks of the hypersatellite line. The discrepancies were explained by chemical effects, which were not considered in the MCDF calculations performed for isolated atoms.