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Submitted
Simon, Levente L., Hajnalka Pataki, Gyoergy Marosi, Fabian Meemken, Konrad Hungerbuehler, Alfons Baiker, Srinivas Tummala, Brian Glennon, Martin Kuentz, Gerry Steele, Herman J. M. Kramer, James W. Rydzak, Zengping Chen, Julian Morris, Francois Kjell, Ravendra Singh, Rafiqul Gani, Krist V. Gernaey, Marjatta Louhi-Kultanen, John O'Reilly, Niklas Sandler, Osmo Antikainen, Jouko Yliruusi, Patrick Frohberg, Joachim Ulrich, Richard D. Braatz, Tom Leyssens, Moritz von Stosch, Rui Oliveira, Reginald B. H. Tan, Huiquan Wu, Mansoor Khan, Des O'Grady, Anjan Pandey, Remko Westra, Emmanuel Delle-Case, Detlef Pape, Daniele Angelosante, Yannick Maret, Olivier Steiger, Miklos Lenner, Kaoutar Abbou-Oucherif, Zoltan K. Nagy, James D. Litster, Vamsi Krishna Kamaraju, and Min-Sen Chiu. "{Assessment of Recent Process Analytical Technology (PAT) Trends: A Multiauthor Review}." {ORGANIC PROCESS RESEARCH & DEVELOPMENT}. {19} (Submitted): {3-62}. Abstract
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Carinhas, Nuno, Vicente Bernal, Adriana Y. Yokomizo, Manuel J. T. Carrondo, Rui Oliveira, and Paula M. Alves. "{Baculovirus production for gene therapy: the role of cell density, multiplicity of infection and medium exchange}." {APPLIED MICROBIOLOGY AND BIOTECHNOLOGY}. {81} (Submitted): {1041-1049}. Abstract
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Da Silva, Ferreira F., S. Jaksch, G. Martins, H. M. Dang, M. Dampc, S. Denifl, T. D. Maerk, P. Limao-Vieira, J. Liu, S. Yang, A. M. Ellis, and P. Scheier. "{Electron attachment and electron ionization of acetic acid clusters embedded in helium nanodroplets}." {PHYSICAL CHEMISTRY CHEMICAL PHYSICS}. {11} (Submitted): {11631-11637}. Abstract
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2024
Ning, Li, Chen Guozhong, Octávio Mateus, Jiang Tao, Xie Yan, Li Daqing, You Hailu, and Peng Guangzhao. "A new stegosaur (Dinosauria: Ornithischia) from the Upper Jurassic Qigu Formation of Xinjiang, China and a revision on Chinese stegosaurs phylogeny." bioRxiv (2024). Abstractli_ning_et_al_2024_2024.09.29.615678v1.full_.pdfWebsite

Stegosaurs are a small but iconic clade of ornithischian dinosaurs. They and their sister taxa, the ankylosaurs, formed the clade Eurypoda which means ‘broad-footed’. Here, we describe a stegosaur from the Upper Jurassic Qigu Formation of Xinjiang, China, based on an associated partial skeleton that includes axial, pectoral girdle, pelvic girdle, limb and armor elements. It can be diagnosed as a new taxon, Angustungui, based on numerous autapomorphies. Some morphologies of Angustungui are more similar to the taxa from Europe, Africa and North America than to those from Asia. Our phylogenetic analysis recovers it as the sister taxon of Loricatosaurus. More importantly, the narrow and claw-shaped ungual of Angustungui proves that Eurypoda, at least stegosaur, has claw-shaped unguals. Besides, we revised the character scores for Chinese stegosaurs based on observations of the specimens.Competing Interest StatementThe authors have declared no competing interest.

Haque, S., M. Alexandre, A. T. Vicente, K. Li, C. S. Schuster, S. Yang, H. Águas, R. Martins, R. A. S. Ferreira, and MJ Mendes. "Photon shifting and trapping in perovskite solar cells for improved efficiency and stability." Light: Science and Applications. 13 (2024). AbstractWebsite
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Akalin, S. A., M. Erol, B. Uzunbayir, S. Oguzlar, S. Yildirim, F. P. Gokdemir Choi, S. Gunes, U. D. Yilmazer Menda, and MJ Mendes. "Physically-Deposited Hole Transporters in Perovskite PV: NiOx Improved with Li/Mg Doping." Advanced Materials Technologies. 9 (2024). AbstractWebsite
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Akalin, S. A., T. Mateus, G. Ribeiro, J. Deuermeier, T. Calmeiro, H. Águas, R. Martins, A. T. Vicente, MJ Mendes, and U. D. Yilmazer Menda. "Ultra-flexible, high-performing NAN transparent electrodes for bendable optoelectronic applications." Journal of Materials Science: Materials in Electronics. 35 (2024). AbstractWebsite
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2023
Ito, Yoshiaki, Tatsunori Tochio, Michiru Yamashita, Sei Fukushima, Takashi Shoji, Katarzyna Słabkowska, Łukasz Syrocki, Marek Polasik, Jana Padežnik Gomilsek, José Pires Marques, Jorge Miguel Sampaio, Mauro Guerra, Jorge Machado, José Paulo Santos, Assala Hamidani, Abdelhalim Kahoul, Paul Indelicato, and Fernando Parente. "Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds." International Journal of Molecular Sciences. 24 (2023): 5570. Abstract

K$_{\alpha , \beta}$ X-ray lines from photon excitation were measured in selected elements from Mg to Cu using a high-resolution double-crystal X-ray spectrometer with a proportional counter, and the K$_beta$/K$_\alpha$ intensity ratio for each element was obtained, after correcting for self-absorption, detection efficiency, and crystal reflectance. This intensity ratio increases rapidly from Mg to Ca but, in the 3d elements region, the increase becomes slower. This is related to the intensity of the Kβ line involving valence electrons. The slow increase of this ratio in the 3d elements region is thought to be due to the correlation between 3d and 4s electrons. Moreover, the chemical shifts, FWHM, asymmetry indices, and Kβ/Kα intensity ratios of the Cr compounds, due to different valences, were also investigated using the same double-crystal X-ray spectrometer. The chemical effects were clearly observed, and the Kβ/Kα intensity ratio was found to be compound-dependent for Cr.

2022
Amaro, P., A. Adamczak, Abdou M. Ahmed, L. Affolter, F. D. Amaro, P. Carvalho, T. L. Chen, L. M. P. Fernandes, M. Ferro, D. Goeldi, T. Graf, M. Guerra, T. W. Hänsch, C. A. O. Henriques, Y. C. Huang, P. Indelicato, O. Kara, K. Kirch, A. Knecht, F. Kottmann, Y. W. Liu, J. Machado, M. Marszalek, R. D. P. Mano, C. M. B. Monteiro, F. Nez, J. Nuber, A. Ouf, N. Paul, R. Pohl, E. Rapisarda, J. M. F. dos Santos, J. P. Santos, P. A. O. C. Silva, L. Sinkunaite, J. T. Shy, K. Schuhmann, S. Rajamohanan, A. Soter, L. Sustelo, D. Taqqu, L. B. Wang, F. Wauters, P. Yzombard, M. Zeyen, and A. Antognini. "Laser excitation of the 1s-hyperfine transition in muonic hydrogen." SciPost Physics. 13 (2022). Abstract

The CREMA collaboration is pursuing a measurement of the ground-state hyperfine splitting (HFS) in muonic hydrogen (μp) with 1 ppm accuracy by means of pulsed laser spectroscopy to determine the two-photon-exchange contribution with 2×10-4 relative accuracy. In the proposed experiment, the μp atom undergoes a laser excitation from the singlet hyperfine state to the triplet hyperfine state, then is quenched back to the singlet state by an inelastic collision with a H2 molecule. The resulting increase of kinetic energy after the collisional deexcitation is used as a signature of a successful laser transition between hyperfine states. In this paper, we calculate the combined probability that a μp atom initially in the singlet hyperfine state undergoes a laser excitation to the triplet state followed by a collisional-induced deexcitation back to the singlet state. This combined probability has been computed using the optical Bloch equations including the inelastic and elastic collisions. Omitting the decoherence effects caused by the laser bandwidth and collisions would overestimate the transition probability by more than a factor of two in the experimental conditions. Moreover, we also account for Doppler effects and provide the matrix element, the saturation fluence, the elastic and inelastic collision rates for the singlet and triplet states, and the resonance linewidth. This calculation thus quantifies one of the key unknowns of the HFS experiment, leading to a precise definition of the requirements for the laser system and to an optimization of the hydrogen gas target where μp is formed and the laser spectroscopy will occur.

Yang, Y., J. Zhao, S. Zhang, Z. Yang, and H. Biscaia. "Influence of salt fog and ambient condition exposure on CFRP-to-steel bonded joints." Composite Structures. 280 (2022). AbstractWebsite

In this paper, the influence of salt fog and ambient condition exposure on CFRP-to-steel bonded joints (CSJs) with a near end mechanical anchorage was studied. The tests of the CSJs were carried out with a monotonic loading history respectively with and without a near end mechanical anchorage both unaged and after being exposed to the ageing conditions. The results revealed failures in the adhesive for some CSJs with a near end mechanical anchorage, among which also exhibited the best bond performance both in aged and unaged specimens. Due to the high state of degradation after ageing exposure, local damage of the CFRP located at the gap position of the CSJs was induced by a torsion action during the fixation of the specimen in the tensile machine even prior to the testing, which caused, although locally, severe delamination of the CFRP of the aged CSJs. From the torsion test results, a decrease in the torsional capacity of the CFRP after aging revealed the degradation of the carbon fiber-to-matrix interface. Additional results reflected that a drop in the initial stiffness of the load vs. slip relationship can be observed, caused by a pre-crack with a length of 30 mm in the CSJs. © 2021 Elsevier Ltd

Boillos, J. M., D. Cortina-Gil, J. Benlliure, J. L. Rodr{\'ıguez-Sánchez, H. Alvarez-Pol, L. Atar, T. Aumann, V. V. Avdeichikov, S. Beceiro-Novo, D. Bemmerer, C. A. Bertulani, K. Boretzky, M. J. G. Borge, M. Caamano, C. Caesar, E. Casarejos, W. Catford, J. Cederkäll, M. Chartier, L. Chulkov, E. Cravo, R. N. P. Crespo, I. Dillmann, Diaz P. Fernandez, Z. Elekes, J. Enders, O. Ershova, A. Estrade, F. Farinon, L. M. Fraile, M. Freer, Galaviz D. Redondo, H. Geissel, R. Gernhäuser, P. Golubev, K. Göbel, J. Hagdahl, T. Heftrich, M. Heil, M. Heine, A. Heinz, A. Henriques, M. Holl, A. Hufnagel, A. Ignatov, H. T. Johansson, B. Jonson, J. Kahlbow, N. Kalantar-Nayestanaki, R. Kanungo, A. Kelic-Heil, A. Knyazev, T. Kröll, N. Kurz, M. Labiche, C. Langer, T. Le Bleis, R. Lemmon, S. Lindberg, J. F. D. C. Machado, J. Marganiec, A. Movsesyan, E. Nacher, M. A. Najafi, T. Nilsson, C. Nociforo, V. Panin, S. Paschalis, A. Perea, M. Petri, S. Pietri, R. Plag, R. Reifarth, G. Ribeiro, C. Rigollet, D. M. Rossi, M. Röder, D. Savran, H. Scheit, H. Simon, O. Sorlin, I. J. Syndikus, J. T. Taylor, O. Tengblad, R. Thies, Y. Togano, M. Vandebrouck, P. J. F. Velho, V. Volkov, A. Wagner, F. Wamers, H. Weick, C. Wheldon, G. L. Wilson, J. S. Winfield, P. Woods, D. Yakorev, M. Zhukov, A. Zilges, and K. Zuber. "{Isotopic cross sections of fragmentation residues produced by light projectiles on carbon near $400A$ MeV}." (2022): 1-13. Abstract

Phys. Rev. C 105, 014611 (2022). doi:10.1103/PhysRevC.105.014611

Ménesguen, Y., M. - C. Lépy, Y. Ito, M. Yamashita, S. Fukushima, T. Tochio, M. Polasik, K. Słabkowska, Ł. Syrocki, P. Indelicato, J. P. Gomilsek, J. P. Marques, J. M. Sampaio, J. Machado, P. Amaro, M. Guerra, J. P. Santos, and F. Parente. "{Structure of single KL$^0$-, double KL$^1$-, and triple KL$^2$- ionization in Mg, Al, and Si targets induced by photons, and their absorption spectra}." Radiation Physics and Chemistry. 194 (2022): 110048. AbstractWebsite

Radiation Physics and Chemistry, 194 (2022) 110048. doi:10.1016/j.radphyschem.2022.110048

2021
G., Correia Viviana, Trovão Filipa, Pinheiro Benedita A., Brás Joana L. A., Silva Lisete M., Nunes Cláudia, Coimbra Manuel A., Liu Yan, Feizi Ten, Fontes Carlos M. G. A., Mulloy Barbara, Chai Wengang, Carvalho Ana Luísa, and Palma Angelina S. "Mapping Molecular Recognition of β1,3-1,4-Glucans by a Surface Glycan-Binding Protein from the Human Gut Symbiont Bacteroides ovatus." Microbiology SpectrumMicrobiology Spectrum (2021): e01826-21. AbstractWebsite

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Yazan, Abdurrahman, and António Brandão Moniz. "Technology Assessment of eVTOL Air Transportation System; the Positive Impacts." International journal of advanced research. 9.1 (2021): 171-180. AbstractWebsite

This paper intended to provide a vision on the potential consequences of the introduction of emerging air transportation system which was based on a section of the thesis to contribute to the forming of public and policy opinion.Especially this paper tried to understand whether there were enough positive social and environmental impacts in terms of potential benefits to continue the efforts.The negative impacts are beyond the scope of this paper. Limitations of the current ground and airline transportation systems, increasing congestion, poor block speed, combined with expanding population and demand for affordable on-demand mobility are driving the development of future transportation technology and policy. The third wave of aeronautic,e VTOL (Vertical Takeoff and landing) Air Transportation System, is envisioned as the next logical step in the natural progression and could bring about great new capabilities for society that would bring aviation into a new age of being relevant in daily lives. Considering door to door block time, e VTOL Air Transportation System has the potential to achieve anotherfive-fold increase over the auto today as the auto provided ten-fold increase over the horse, and a daily mobility reach of 125 to 250 miles.The main benefits will be on-demand, point-to-point,safe travel, further and anywhere in less travel time with almost zero environmental impact for general people. Besides, a successful implementation and sustainable transition will depend on overcoming technological hurdles, regulatory frameworks, operational safety, cost competitiveness, and sensibilities of the affected communities.

Yang, Y., J. Zhao, S. Zhang, C. Chastre, and H. Biscaia. "Effect of mechanical anchorage on the bond performance of double overlapped CFRP-to-steel joints." Composite Structures. 267 (2021). AbstractWebsite

Mechanical anchorage devices have the potential to efficiently improve the bond behavior of Carbon Fiber-Reinforced Polymers (CFRP) Externally Bonded (EB) onto steel with an adhesive. Existing relevant studies, however, have been very limited. Against this background, experimental and numerical studies on the double overlapped CFRP-to-steel bonded joints with an end mechanical anchorage were carried out in the present study. Two types of CFRP laminates (i.e., SIKA CFRP and the other type made in Harbin Institute of Technology – HIT) were used in the bond tests, with or without end mechanical anchorage devices. The test results showed that the end mechanical anchorage had marginal effect on the bond-slip relationship between EB CFRP and steel as well as debonding load, but could increase the ultimate load. It was also found that CFRP laminate from HIT had a better bond performance than that from SIKA, in terms of both debonding load and ultimate load. Using ABAQUS, Finite Element (FE) model was established on such bonded joints and the accuracy was verified with test results. The verified FE model was adopted in a parametric study to further clarify the effect of key parameters on the bond behavior of such bonded joints. © 2021 Elsevier Ltd

Boretzky, K., I. Gasparic, M. Heil, J. Mayer, A. Heinz, C. Caesar, D. Kresan, H. Simon, H. T. Törnqvist, D. Körper, G. Alkhazov, L. Atar, T. Aumann, D. Bemmerer, S. V. Bondarev, L. T. Bott, S. Chakraborty, M. I. Cherciu, L. V. Chulkov, M. Ciobanu, U. Datta, E. De Filippo, C. A. Douma, J. Dreyer, Z. Elekes, J. Enders, D. Galaviz, E. Geraci, B. Gnoffo, K. Göbel, V. L. Golovtsov, Gonzalez D. Diaz, N. Gruzinsky, T. Heftrich, H. Heggen, J. Hehner, T. Hensel, E. Hoemann, M. Holl, A. Horvat, Á. Horváth, G. Ickert, Jelavić D. Malenica, H. T. Johansson, B. Jonson, J. Kahlbow, N. Kalantar-Nayestanaki, A. Kelic-Heil, M. Kempe, K. Koch, N. G. Kozlenko, A. G. Krivshich, N. Kurz, V. Kuznetsov, C. Langer, Y. Leifels, I. Lihtar, B. Löher, J. Machado, N. S. Martorana, K. Miki, T. Nilsson, E. M. Orischin, E. V. Pagano, S. Pirrone, G. Politi, P. M. Potlog, A. Rahaman, R. Reifarth, C. Rigollet, M. Röder, D. M. Rossi, P. Russotto, D. Savran, H. Scheit, F. Schindler, D. Stach, E. Stan, Stomvall J. Gill, P. Teubig, M. Trimarchi, L. Uvarov, M. Volknandt, S. Volkov, A. Wagner, V. Wagner, S. Wranne, D. Yakorev, L. Zanetti, A. Zilges, K. Zuber, and R. 3B. collaboration. "{NeuLAND: The high-resolution neutron time-of-flight spectrometer for R3B at FAIR}." Nuclear Inst. and Methods in Physics Research, A. 1014 (2021): 165701. AbstractWebsite

Nuclear Inst. and Methods in Physics Research, A, 1014 (2021) 165701. doi:10.1016/j.nima.2021.165701

2020
Syndikus, I., M. Petri, A. O. Macchiavelli, S. Paschalis, C. A. Bertulani, T. Aumann, H. Alvarez-Pol, L. Atar, S. Beceiro-Novo, J. Benlliure, J. M. Boillos, K. Boretzky, M. J. G. Borge, B. A. Brown, M. Caamano, C. Caesar, E. Casarejos, W. Catford, J. Cederkäll, S. Chakraborty, L. V. Chulkov, D. Cortina-Gil, E. Cravo, R. Crespo, Datta U. Pramanik, I. Dillmann, Diaz P. Fernandez, Z. Elekes, J. Enders, F. Farinon, L. M. Fraile, D. Galaviz, H. Geissel, R. Gernhäuser, P. Golubev, K. Göbel, M. Heil, M. Heine, A. Heinz, A. Henriques, M. Holl, H. T. Johansson, B. Jonson, N. Kalantar-Nayestanaki, R. Kanungo, A. Kelic-Heil, T. Kröll, N. Kurz, C. Langer, T. Le Bleis, J. Machado, J. Marganiec-Gałązka, E. Nacher, T. Nilsson, C. Nociforo, V. Panin, A. Perea, S. B. Pietri, R. Plag, A. Rahaman, R. Reifarth, A. Revel, G. Ribeiro, C. Rigollet, D. M. Rossi, D. Savran, H. Scheit, H. Simon, O. Sorlin, O. Tengblad, Y. Togano, M. Vandebrouck, V. Volkov, F. Wamers, C. Wheldon, G. L. Wilson, J. S. Winfield, H. Weick, P. Woods, D. Yakorev, M. Zhukov, A. Zilges, K. Zuber, and R. 3B. collaboration. "{Probing the Z=6 spin-orbit shell gap with (p,2p) quasi-free scattering reactions}." Physics Letters B. 809 (2020): 135748. AbstractWebsite

Physics Letters B, 809 (2020) 135748. 10.1016/j.physletb.2020.135748

Ito, Y., T. Tochio, M. Yamashita, S. Fukushima, A. M. Vlaicu, J. P. Marques, J. M. Sampaio, M. Guerra, J. P. Santos, Ł. Syrocki, K. Słabkowska, E. WÈ©der, M. Polasik, J. Rzadkiewicz, P. Indelicato, Y. Ménesguen, M.-Ch. Lépy, and F. Parente. "Structure of K$\upalpha$1,2- and K$\upbeta$1,3-emission x-ray spectra for Se, Y, and Zr." Physical Review A. 102 (2020). AbstractWebsite
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2019
Gao, Tian, Jingyu Yan, Chang-Cheng Liu, Angelina S. Palma, Zhimou Guo, Min Xiao, Xi Chen, Xinmiao Liang, Wengang Chai, and Hongzhi Cao. "{Chemoenzymatic Synthesis of O-Mannose Glycans Containing Sulfated or Nonsulfated HNK-1 Epitope.}." Journal of the American Chemical Society. 141 (2019): 19351-19359. Abstract

The human natural killer-1 (HNK-1) epitope is a unique sulfated trisaccharide sequence presented on O- and N-glycans of various glycoproteins and on glycolipids. It is overexpressed in the nervous system and plays crucial roles in nerve regeneration, synaptic plasticity, and neuronal diseases. However, the investigation of functional roles of HNK-1 in a more complex glycan context at the molecular level remains a big challenge due to lack of access to related structurally well-defined complex glycans. Herein, we describe a highly efficient chemoenzymatic approach for the first collective synthesis of HNK-1-bearing O-mannose glycans with different branching patterns, and for their nonsulfated counterparts. The successful strategy relies on both chemical glycosylation of a trisaccharide lactone donor for the introduction of sulfated HNK-1 branch and substrate promiscuities of bacterial glycosyltransferases that can tolerate sulfated substrates for enzymatic diversification. Glycan microarray analysis with the resulting complex synthetic glycans demonstrated their recognition by two HNK-1-specific antibodies including anti-HNK-1/N-CAM (CD57) and Cat-315, which provided further evidence for the recognition epitopes of these antibodies and the essential roles of the sulfate group for HNK-1 glycan-antibody recognition.

Yang, Yongming, Hugo Biscaia, Manuel A. G. Silva, and Carlos Chastre. "Monotonic and quasi-static cyclic bond response of CFRP-to-steel joints after salt fog exposure." Composites Part B: Engineering. 168 (2019): 532-549. AbstractWebsite

Deterioration of adhesively bonded CFRP/steel systems in salt fog environment, i.e., deicing salts and ocean environments, has to be taken into account in the design of steel strengthened structures. In the present work, monotonic and quasi-static cyclic loading were applied to CFRP-to-steel double strap joints for two kinds of CFRP laminates after being aged for a period of 5000 h to evaluate the bond behavior. The bonded joints exposed to salt fog had a different failure mode than that observed in the control specimens (0 h of exposure). The severe reduction of the maximum bond stress resulted from damage initiation that occurred in the corrosion region of the steel substrate, associated with final partial rupture on the corroded steel substrate around the edge of the bonded area: it was also correlated with reduced load carrying capacity. Results of pseudo-cyclic tests showed that the relationship between a local damage parameter (D) and normalized local dissipated energy (Wd/Gf) and the normalized slip increment (ΔS/ΔSult) exhibited almost the same trend in the un-aged and aged bonded joints. The normalized slip increment can be seen as a direct indicator for the local and global damage for the un-aged and aged bonded joints. However, monotonic and quasi-static cyclic tests results revealed that the stress concentration due to local corrosion of steel substrate could lead to brittle rupture or accelerated cumulative damage once the aged bonded interface had become weaker. The bonded joints have exhibited also a smaller relative deformation capacity between CFRP and steel.

Yang, Yongming, Manuel A. G. Silva, Hugo Biscaia, and Carlos Chastre. "Bond durability of CFRP laminates-to-steel joints subjected to freeze-thaw." Composite Structures. 212 (2019): 243-258. AbstractWebsite

The degradation mechanisms of bonded joints between CFRP laminates and steel substrates under severe environmental conditions require more durability data and studies to increase the database and better understand their causes. Studies on bond properties of double-strap CFRP-to-steel bonded joints with two different composite materials as well as adhesive coupons subjected to freeze-thaw cycles for 10,000 h were conducted to reduce that gap. In addition, the equivalent to the number of thermal cycles and their slips induced in the CFRP laminates was replicated by an equivalent (mechanical) loading-unloading history condition imposed by a static tensile machine. The mechanical properties of the adhesive coupons and the strength capacity of the bonded joints were only slightly changed by the artificial aging. It was confirmed that the interfacial bond strength between CFRP and adhesive is critically related to the maximum shear stress and failure mode. The interfacial bond strength between adhesive and steel degraded with the aging. However, the equivalent thermal cyclic bond stress caused no detectable damage on the bond because only the interfacial elastic regime was actually mobilized, which confirmed that pure thermal cycles aging, per se, at the level imposed, have a low impact on the degradation of CFRP-to-steel bonded joints.

Yang, Y., M. A. G. Silva, H. Biscaia, and C. Chastre. "Bond durability of CFRP laminates-to-steel joints subjected to freeze-thaw." Composite Structures. 212 (2019): 243-258. AbstractWebsite

The degradation mechanisms of bonded joints between CFRP laminates and steel substrates under severe environmental conditions require more durability data and studies to increase the database and better understand their causes. Studies on bond properties of double-strap CFRP-to-steel bonded joints with two different composite materials as well as adhesive coupons subjected to freeze-thaw cycles for 10,000 h were conducted to reduce that gap. In addition, the equivalent to the number of thermal cycles and their slips induced in the CFRP laminates was replicated by an equivalent (mechanical) loading-unloading history condition imposed by a static tensile machine. The mechanical properties of the adhesive coupons and the strength capacity of the bonded joints were only slightly changed by the artificial aging. It was confirmed that the interfacial bond strength between CFRP and adhesive is critically related to the maximum shear stress and failure mode. The interfacial bond strength between adhesive and steel degraded with the aging. However, the equivalent thermal cyclic bond stress caused no detectable damage on the bond because only the interfacial elastic regime was actually mobilized, which confirmed that pure thermal cycles aging, per se, at the level imposed, have a low impact on the degradation of CFRP-to-steel bonded joints. © 2019 Elsevier Ltd

Yang, Y., H. Biscaia, M. A. G. Silva, and C. Chastre. "Monotonic and quasi-static cyclic bond response of CFRP-to-steel joints after salt fog exposure." Composites Part B: Engineering. 168 (2019): 532-549. AbstractWebsite

Deterioration of adhesively bonded CFRP/steel systems in salt fog environment, i.e., deicing salts and ocean environments, has to be taken into account in the design of steel strengthened structures. In the present work, monotonic and quasi-static cyclic loading were applied to CFRP-to-steel double strap joints for two kinds of CFRP laminates after being aged for a period of 5000 h to evaluate the bond behavior. The bonded joints exposed to salt fog had a different failure mode than that observed in the control specimens (0 h of exposure). The severe reduction of the maximum bond stress resulted from damage initiation that occurred in the corrosion region of the steel substrate, associated with final partial rupture on the corroded steel substrate around the edge of the bonded area: it was also correlated with reduced load carrying capacity. Results of pseudo-cyclic tests showed that the relationship between a local damage parameter (D) and normalized local dissipated energy (W d /G f ) and the normalized slip increment (ΔS/ΔS ult ) exhibited almost the same trend in the un-aged and aged bonded joints. The normalized slip increment can be seen as a direct indicator for the local and global damage for the un-aged and aged bonded joints. However, monotonic and quasi-static cyclic tests results revealed that the stress concentration due to local corrosion of steel substrate could lead to brittle rupture or accelerated cumulative damage once the aged bonded interface had become weaker. The bonded joints have exhibited also a smaller relative deformation capacity between CFRP and steel. © 2019 Elsevier Ltd

Ménesguen, Y., {M. C. } Lépy, Y. Ito, M. Yamashita, S. Fukushima, M. Polasik, K. Słabkowska, Syrocki, E. Wȩder, P. Indelicato, {J. P. } Marques, {J. M. } Sampaio, M. Guerra, F. Parente, and {J. P. } Santos. "Precise x-ray energies of gadolinium determined by a combined experimental and theoretical approach." Journal Of Quantitative Spectroscopy & Radiative Transfer. 236 (2019). Abstract

We combined different experimental techniques with a theoretical approach to determine a consistent set of diagram lines energies and binding energies. We propose an original approach consisting in determining the mass attenuation coefficients in an energy range covering the L-, M- and N- absorption edges, including a detailed evaluation of the associated uncertainties, to derive precisely the binding energies. We investigated the Lα, Lβ and M spectra of Gd with an independantly calibrated high-resolution anti-parallel double-crystal x-ray spectrometer. All the lines were identified and found in excellent agreement with the binding energies previously derived. Morever, we identified for the first time M5−O2, M4−O2,3 and M4−N2,3 diagram lines.