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This thesis deals with the analysis of the behaviour of retrofitting reinforced concrete circular columns with FRP materials which were subjected either to axial cyclic compression or axial compression and alternated cyclic horizontal loads. The choice of this topic derived from the need to investigate the behaviour of the strengthening of reinforced concrete columns to seismic actions, especially with new materials such as carbon and glass fibres or polymeric mortars. Another reason for such choice is linked to the strong seismicity of the Portuguese territory.
It has been verified that confined concrete columns with FRP jackets have their resistance and ductility highly increased as these considerably reduce the columns transversal deformation, thus preventing the buckling of longitudinal reinforcement. There has been an increasing use of FRP composites in the strengthening of structures, mainly with GFRP (Glass Fibre Reinforced Plastics) or CFRP (Carbon Fibre Reinforced Plastics). This is due to their attractive characteristics such as high resistance to corrosion, lowratio for weight/strength, moldability, easy application and the fact that there is no need of support structures.
Forty-five experimental tests were carried out, dealing with retrofitting reinforced concrete columns with axial monotonic or cyclic compression reinforced with FRP composites. The column height of 750 mm was maintained in order to evaluate the influence of several parameters in its behaviour: the column geometry (change in its diameter), the type of column (plain or reinforced concrete), transversal reinforcement ratio of concrete columns, the type of external confinement with FRP (C or GFRP), the number of FRP layers and the type of axial loading (monotonic or cyclic).
Twelve additional experimental tests were conducted in order to analyse the behaviour of reinforced concrete columns jacketed with FRP composites and subjected to axial cyclic compression and alternated cyclic horizontal loads. The columns’ dimension was maintained (1500 mm height by 250 mm diameter) and the models were subjected to a series of cyclic and alternated loadings. This enabled the study of the various parameters’ influence in their behaviour such as the type of FRP confinement, the number of FRP layers, the level of axial loading, the jacket’s height or the strengthening of the plastic hinge by replacing the cover concrete with polymeric mortar.
Based on the numerical models presented and experimental analysis carried out, models were proposed and developed to simulate the behaviour of columns jacketed with FRP composites.

If H is a family of graphs, then an H-decomposition of a graph G is a partition of the edges of G each element of which induces a copy of a graph in G.
This paper addresses the problem of finding the number φ(n,H), the smallest number k such that every graph on n vertices has an H-decomposition with at most k elements. φ(n,H) is found in the cases when H={K2,C5}; when H={K2,C5+e}, where e is a chord of the C5; when H={K2,K4−e}; and when H={K2,K3+e}, where e is a pendant edge added to one vertex in the K3.

A multi-product model for the design of global supply chains with reverse flows is proposed. Two levels of decisions are considered, one strategic and one tactical. The first is modelled through a macro perspective of time where the determination of the network structure and flows is accomplished. At tactical level, a micro perspective of time is considered, where production planning and inventory management are addressed in detail. A mixed integer linear programming formulation is developed which is solved with standard Branch and Bound techniques. The model accuracy and suitability are studied using a case study.

Much attention is currently given to the study of supply chains. Most studies are, however, only concerned with forward chains, rendering reverse chains a field insufficiently covered. Few optimization models addressing either the design of reverse networks or the simultaneous design of forward and reverse networks have been presented. We propose a MILP model for the design and planning of an integrated forward and reverse chain. While minimizing cost, the network structure is defined simultaneously with production and storage planning. Dynamic aspects are accounted for using a two-time scale, fully interconnected structure, where at a macro time the network design is performed and at a micro time the planning is optimised. The deterministic model is extended and a scenario approach is applied to account for uncertainties in demand and return of products. A case study is solved and a common structure to all scenarios is obtained, while scenario dependent policies are defined for distribution, production and storage. The model generality is corroborated with good performance results.

This paper is mainly focused on the characterisation of a glass material (GM) obtained from the thermal treatment of a bottom ash (BA) produced at the Municipal Solid Waste (MSW) incineration plant of Valorsul. By melting the BA at 1400ºC during 2 hours, and without using any chemical additives, a homogeneous black-coloured glass was obtained. The thermal and mechanical properties of this glass were characterised. The thermal expansion coefficient, measured by dilatometry, was 9-10 x 10-6 per ºC and the modulus of rupture, determined by four-point bending test, was 75±6 MPa, which are similar values to those exhibited by commercial soda-lime-silica glasses used in structural applications. The chemical and the ecotoxicological leaching behaviour of the GM were also analysed. The GM was submitted to a leaching procedure composed of 15 sequential extraction cycles. A liquid/solid (L/S) ratio of 2 l/kg was applied in each cycle. The leachates were filtered through a membrane of PTFE (porosity: 0.45 µm). The filtered leachates were characterised for different chemical parameters and for an ecotoxicological indicator (bacterium Vibrio fischeri). The GM was also submitted to a microwave acidic digestion for the assessment of the total metal content. The crude BA was also submitted to the same experimental procedures. The GM showed levels of chemical emission and ecotoxicity for V. fischeri much lower than those determined for the crude BA. Similar characterisation studies will be pursued with the glass-ceramics produced by adequate thermal treatment of the glass, in order to investigate the effect of the crystallization on the final properties.

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We prove Szegö's strong limit theorem for Toeplitz determinants with a symbol having a nonstandard smoothness. We assume that the symbol belongs to the Wiener algebra and, moreover, the sequences of Fourier coefficients of the symbol with negative and nonnegative indices belong to weighted Orlicz classes generated by complementary \(N\)-functions both satisfying the \(\Delta_2^0\)-condition and by weight sequences satisfying some regularity, and compatibility conditions.

In recent years much attention has been given to global supply chains. However, the emphasis has been on forward chains, with reverse flows been insufficiently studied. In this work, we study closed loop supply chains and analyse the impact caused by the introduction of new facility sites into an already existing supply chain. The model considers both strategic and tactical decisions allowing for the design of a global supply chain with reverse flows. The impact of the network redesign is analysed and the associated costs calculated. The obtained MILP is solved using a standard Branch and Bound solver. The results obtained prove that the proposed model handles satisfactorily the network redesign problem.

GaN films were deposited by cyclic pulsed laser deposition (cyclic-PLD) at different substrate temperatures between 400 and 600◦C. Alignment of the films along the c-axis, grain size, roughness and conductivity increased with temperature. Surface elemental ratio N/Ga was determined by X-ray photoelectron spectroscopy (XPS) and was smaller for films deposited at higher temperature. A decrease of the resistivity of the films agreed with higher metallic (Ga) surface concentration. Bulk elemental ratio N/Ga, determined by Rutherford backscattering spectroscopy (RBS), was higher than the XPS ratio and showed a very small tendency to decrease with deposition temperature. At 600 ◦C, there was evidence of contamination of the films by oxygen probably resulting from diffusion from the sapphire (Al2O3) substrate. These results suggest that adjustments in the deposition conditions are needed in order to have high crystal alignment, large grain size and good N/Ga ratio.

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The thermal decompositions of methyl azidoformate (N3COOMe), ethyl azidoformate (N3COOEt) and 2-azido-N,N-dimethylacetamide (N3CH2CONMe2) have been studied by matrix isolation infrared spectroscopy and real-time ultraviolet photoelectron spectroscopy. N2 appears as an initial pyrolysis product in all systems, and the principal interest lies in the fate of the accompanying organic fragment. For methyl azidoformate, four accompanying products were observed: HNCO, H2CO, CH2NH and CO2, and these are believed to arise as a result of two competing decomposition routes of a four-membered cyclic intermediate. Ethyl azidoformate pyrolysis yields four corresponding products: HNCO, MeCHO, MeCHNH and CO2, together with the five-membered-ring compound 2-oxazolidone. In contrast, the initial pyrolysis of 2-azido-N,N-dimethyl acetamide, yields the novel imine intermediate Me2NCOCHNH, which subsequently decomposes into dimethyl formamide (HCONMe2), CO, Me2NH and HCN. This intermediate was detected by matrix isolation IR spectroscopy, and its identity confirmed both by a molecular orbital calculation of its IR spectrum, and by the temperature dependence and distribution of products in the PES and IR studies. Mechanisms are proposed for the formation and decomposition of all the products observed in these three systems, based on the experimental evidence and the results of supporting molecular orbital calculations.